METALLURGICAL ASPECTS OF THE STRESS CORROSION CRACKING OF TITANIUM ALLOYS.
Titanium alloys stress corrosion cracking /SCC/ from metallurgical-mechanical viewpoint, discussing phase transformations, dislocation arrangements, crack propagation, etc
Materials Literature
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Divalent silicon intermediates in the pyrolysis of alkoxypolysilanes
Abstract
NEW UNIT LAYERS FOR MICAS
A new choice of unit layer proposed by Sadanaga & Takeda (1968) has been found useful for explaining the two characteristic features of the X-ray diffraction pattern of the mica, namely, the periodic intensity distribution and the partial enhancement of symmetry. The recognition of the fact that the symmetry of the ne…
Recrystallization of the Cellulose I Lattice in Mercerized and Regenerated Cellulose Fibers
Cotton cellulose has been subjected to swelling and stretching treatments under various conditions. It has been found that the cellulose I lattice is highly resistant to alkali attack and difficult to disrupt completely during a single swelling treatment. The residual cellulose 1 “nuclei” grow upon stretching the swol…
The Mechanism of Void Growth and Factors Affecting the Onset of Intergranular Failure during Creep of a Mg–0·8% Al Alloy
Tensile tests on a Mg–0·8% Al alloy have been conducted at a strain rate of 10−2h−1 between 25 and 400° C with grain sizes ranging from 0·009 to 0·300 in. It is shown that the growth of voids occurs by a grain-boundary sliding mechanism and the variation of ductility in the intergranular-failure range is interpreted b…
Benzoquinone imines. Part VI. Mechanism and kinetics of the reaction of p-benzoquinone di-imines with m-phenylenediamines
Oxidation of mixtures of a p-phenylenediamine and a m-phenylenediamine is shown to give aminoindamine dyes by a reaction between the p-benzoquinonedi-imine and the m-diamine. At pH > 7 the latter reaction involves electrophilic attack by the conjugate acid of the di-imine on the electron-rich carbon [C(4)] of the m-di…
Pyrolysis of diallyl oxalate vapour. Part 1.—Kinetics of the unsensitized decomposition
The unsensitized thermal decomposition of the vapour of diallyl oxalate has been studied in a fused quartz cell between 130 and 190°C. The products are consistent with the formation of allyl radicals in the primary dissociation: (COOC3H5)2→ 2CO2+ 2C3H5·; k1= 1014 ± 1 exp(–40 ± 3) 103/RT sec–1 This system is well suite…
18- and 22-π-Electron macrocycles containing furan, pyrrole, and thiophen rings
The preparation of a number of novel aromatic macrocycles related to porphins, but containing furan and thiophen rings in addition to pyrrole rings, is described, together with deuterium exchange studies on some of the macrocycles.
Processes Involved in Reattainment of Steady-State Conditions for the Anodizing of Aluminum Following Formation Voltage Changes
The dissolution processes involved in the formation of porous films in sulfuric acid have been studied by suddenly lowering the formation voltage and observing changes in the current flowing and the barrier layer capacitance as steady‐state conditions are re‐established. It was found that current changes always follow…
The Properties of Photochromic Materials
The types of systems available are briefly mentioned, together with the mechanisms involved in the photochromic changes. The behaviour of the materials under irradiation, both for activation (colouring) and reversal (erasure), the effect of temperature, and reversibility and resolution are discussed. The optimum perfo…
Catalytic oxidation of methane on zeolites containing rhodium, iridium, palladium and platinum
The complete oxidation of methane over zeolites containing palladium, platinum, rhodium and iridium has been studied using a microcalorimetric technique. The results show that isolated ions of these metals are able to adsorb both methane and oxygen but only with platinum do methane and oxygen adsorb competitively. The…
Fatigue Fundamentals for Composite Materials
As composites are a combination of many organic and inorganic materials already studied, we draw on this information to guide us in strength evaluations, interpretation of results, and design aspects of the new materials. Basically, many micro- and macrostructural differences exist between the materials made of metals…
Polycondensation rate of poly(ethylene terephthalate). II. Antimony trioxide–catalyzed polycondensation in static thin films on metal surfaces
Abstract In the catalyzed polycondensation reaction of poly(ethylene terephthalate), defined by equation image rates of polymerization in thin films under vacuum are orders of magnitude greater than those observed in an equilibrating system. Such behavior is consistent with a mechanism in which a volatile component of…
The stress‐strain‐birefringence properties of styrene‐butadiene block copolymers
Abstract The stress‐strain‐optical properties of three elastomeric styrene‐butadiene block copolymers containing 31, 40, and 49 wt‐% styrene were studied as a function of temperature. The mechanical and the optical properties indicate that these materials are two‐phase systems in which the polybutadiene chains form an…
The Science of Engineering Materials
Abstract not Available.
Dendrite Morphology and Arm Spacing of Steels
An experimental study has been carried out to investigate the effect of growth variables on dendrite morphology and dendrite arm spacing in 25Cr-20Ni stainless steel and 1Cr-0.25Mo steel, solidified vertically under semi-steady state conditions.The condition for cell formation and the cell to dendrite transition has b…
Quantentheorie der Strahlung
ZusammenfassungBevor man Wechselwirkungen zwischen Elektronen und Lichtquanten diskutieren kann, sind zunächst die beiden Einzelsysteme zu untersuchen. Die Quantentheorie der Einelektronensysteme wurde bereits behandelt, damit muß man sich nun der Quantentheorie der Strahlung zuwenden. Dazu sind lediglich die bisher e…
Gas-phase Raman spectroscopy of phosphorus, arsenic, and saturated sulphur vapours
The gas-phase Raman spectra of P4, As4, P2, and As2 are recorded and compared with literature values for P2 and As2 derived from electronic spectroscopy, and for sulphur, the gas-phase Raman spectra of S8 and S6 are obtained, together with a polarized band at 237 cm.–1 which is probably due to S7.
Electronic Displacement in Tellurium by Mechanical Strain
Abstract The piezoelectric constants e 11 and e 14 of tellurium have been found by measurement to be 0.42 C m −2 and 0.17 C m −2 . They are described by strain‐induced displacement of the electron distribution relative to the Te cores.
Structures magnétiques des orthoferrites de terres rares
On précise les structures magnétiques des sous-réseaux de fer et de terre rare dans quelques orthoferrites de terres rares. L'hypothèse d'une très forte anisotropie de la terre rare permet d'interpréter la polarisation non colinéaire du sous-réseau de terre rare dans l'état paramagnétique par le champ dû à l'ordre du…