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Determination of the OH- Content in the aqueous phase of hardened cementitious materials by an empirical Leaching method

M. Castellote、M. C. Alonso、C. Andrade2002-03-01Materiales de Construccion

The most reliable method to determine the concentration of hydroxyl ions in the aqueous phase of hardened cementitious materials is the squeezing of concrete at high pressures. However, this method needs special equipment as well as a relatively high amount of sample to be carried out. In present research, the determi…

Surface Modification of Polymeric Materials by Plasma Treatment

Elza F. Castro Vidaurre、Carlos A. Achete、Flávia da Cruz Gallo 等 6 位作者2002-03-01Materials Research

Low-temperature plasma treatment has been used in the last years as a useful tool to modify the surface properties of different materials, in special of polymers. In the present work low temperature plasma was used to treat the surface of asymmetric porous substrates of polysulfone (PSf) membranes. The main purpose of…

Diamond and Carbon-based Materials ResearchAdvanced Sensor and Energy Harvesting MaterialsSurface Modification and Superhydrophobicity

Electrochromic Properties of Sol-gel Coating of Nb2O5 and Nb2O5:Li+

L. Melo、C.O. Avellaneda、R. Caram 等 5 位作者2002-03-01Materials Research

Thin solid films of Nb2O5 and Nb2O5:Li+ were prepared by the sol-gel process using the sonocatalytic method. The films reported here were prepared from a NbCl5 as precursor and butanol as solvent. Through the addition of lithium salt LiCF3SO3 to the precursor solution, films with different electrochemical performance…

Structural Evaluation and Performance of Portland Cement Concretes After Exposure to High Temperatures

Evandro Tolentino、Fernando S. Lameiras、Abdias M. Gomes 等 5 位作者2002-03-01Materials Research

We evaluated the "residual" thermal conductivity of Portland cement concretes (with characteristic compressive strength at 28 days, f ck, of 20 MPa and 50 MPa) at room temperature after heat-treating at 180 °C, 300 °C and 600 °C. The description of the geometry of the structure was carried out using mercury intrusion…

Ultrasonic Measurements In Brazilian Hardwood

Fabiana Goia R. de Oliveira、Janaína Anadia O. de Campos、Almir Sales2002-03-01Materials Research

This paper reports on a study of the application of ultrasound waves in wood with the purpose of evaluating the latter's mechanical properties. The evaluation is based on the correlation between the speed of sound, modulus of elasticity and density. The speed of transmission is sensitive to the material's quality-dete…

Synchrotron SAXS Studies of Nanostructured Materials and Colloidal Solutions: A Review

A. F. Craievich2002-03-01Materials Research

Structural characterisations using the SAXS technique in a number of nanoheterogeneous materials and liquid solutions are reviewed. The studied systems are protein (lysozyme)/water solutions, colloidal ZnO particles/water sols, nanoporous NiO-based xerogels, hybrid organic-inorganic siloxane-PEG and PPG nanocomposites…

Iron oxide chemistry and applicationsX-ray Diffraction in CrystallographyEnzyme Structure and Function

Evolution and quantification of the main Sensitisers in commercial portland cements

M. Frías、M. I. Sánchez Rojas2002-03-01Materiales de Construccion

The commercial Portland cements contain minor elements in their chemical compositions. The presence of these elements has a direct incidence in different aspects: rheological behaviour, reaction kinetics, environmental, etc. Some of them also have a negative effect on the human health; so, chromium (Cr), nickel (Ni) a…

Hydrous Tantalum Phosphates for Ion Exchange Purposes: A Systematic Study

M.L.C.P.da Silva、G.L.J.P. da Silva、D.N. Villela Filho2002-03-01Materials Research

This work describes two methods of preparation of hydrous tantalum phosphates and their characterization as ion exchangers. The hydrous metallic phosphate compounds were chemically and physically characterized by thermal gravimetric analysis, X-ray diffractometry and surface area measurements. By the first method, tan…

Transição de Fase Difusa e Propriedades Dielétricas de Cerâmicas Ferroelétricas de (Pb, Ba)Nb2O6

I.A. Santos、V.L. Arantes、D. Garcia 等 4 位作者2002-03-01Materials Research

Tungsten bonze structured lead barium niobate (Pb1-xBa xNb2O6) ferroelectric ceramics were prepared by the conventional mixed oxide method and their dielectric properties were carefully investigated. All studied samples presented elevated values of maximum dielectric constant (epsilon'm) and its corresponding temperat…

Influence of Fiber Length Distribution on Strength Efficiency of Fibers in Yarn

Mishu I. Zeidman、Paul Sawhney2002-03-01Textile Research Journal

The tensile and tear strengths and hence the durability of a cotton fabric are greatly influenced by the length and strength of cotton fibers in addition to the fabric structure. This is so because fiber length to a large extent determines yam strength, which ultimately contributes to fabric strength. Also, fiber leng…

Structural Analysis and OptimizationTextile materials and evaluations

The Coordination of CuII in Zeolites − Structure and Spectroscopic Properties

Annelies Delabie、Kristine Pierloot、Marijke H. Groothaert 等 5 位作者2002-03-01European Journal of Inorganic Chemistry

Zeolites loaded with transition metal ions are promising heterogeneous catalysts. Knowledge about the location and structure of the metal centers is of paramount importance for the understanding of the catalytic potential of these materials. In this work, the spectroscopic studies of the coordination of CuII in zeolit…

Advanced Chemical Physics StudiesX-ray Diffraction in CrystallographyCatalytic Processes in Materials Science

Clay Mineralogy of Phyllic and Intermediate Argillic Alteration at Bingham, Utah

William Parry、Mark D. Jasumback、Paula N. Wilson2002-03-01Economic Geology

The earliest alteration mineral zones in the porphyry Cu-Mo-Au ore deposit at Bingham, Utah, include the outermost propylitic and inner potassic alteration of igneous rocks. Innermost phyllic and intermediate argillic alteration is superimposed on propylitic and potassic alteration. Petrographic, X-ray diffraction, an…

Geochemistry and Geologic MappingGeological and Geochemical AnalysisClay minerals and soil interactions

Three-Dimensional Computer Modeling of Warp Knitted Structures

Özer Göktepe、S.C. Harlock2002-03-01Textile Research Journal

In this work, a 3D computer aided designing (CAD) system is developed for solid modeling and visual simulation of warp knitted structures on Silicon Graphics workstations. In the first part, a three-dimensional cylindrical and uniform solid yarn model is developed, such that its central axis is a space curve, using no…

Textile materials and evaluations

A VO2-Based Multifunctional Window with Highly Improved Luminous Transmittance

Ping Jin、Gang Xu、Masato Tazawa 等 4 位作者2002-03-01Japanese Journal of Applied Physics

A novel window structure composed of VO 2 thermochromic film with TiO 2 antireflection (AR) coating was proposed. TiO 2 was chosen as the best AR candidatefor reasons that it is an AR material superior to the reported SiO 2 , and that it is capable to make the window multifunctional with excellent photocatalytic prope…

Transition Metal Oxide NanomaterialsTiO2 Photocatalysis and Solar CellsOptical Wireless Communication Technologies

Electron inelastic mean free path for Ti, TiC, TiN and TiO 2 as determined by quantitative reflection electron energy‐loss spectroscopy

G.G. Fuentes、E. Elizalde、F. Yubero 等 4 位作者2002-03-01Surface and Interface Analysis

Abstract Electron inelastic mean free paths (IMFP) have been estimated for Ti, TiC, TiN and TiO 2 for energies between 250 and 2000 eV. The IMFP values have been derived from the respective energy‐loss function (i.e. Im{−1/ ϵ }) on the basis of the model developed by Yubero and Tougaard for quantitative analysis using…

Electron and X-Ray Spectroscopy TechniquesX-ray Spectroscopy and Fluorescence AnalysisCorrosion Behavior and Inhibition

Electronic polarizability, optical basicity, and interaction parameter of La2O3 and related glasses

Tsuyoshi Honma、Yasuhiko Benino、Takahiro Fujiwara 等 6 位作者2002-03-01Journal of Applied Physics

The electronic polarizability and optical basicity of La2O3 and related glasses have been determined from ultraviolet absorption spectra and calculations based on the Lorentz–Lorenz equation. The optical basicity for La2O3 oxide is found to be 1.07, being much larger compared with typical glass-forming oxides such as…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsMineralogy and Gemology Studies

Silica–Carbon Nanocomposites—A New Concept for the Design of Solar Absorbers

Yitzhak Mastai、Sebastian Polarz、Markus Antonietti2002-03-01Advanced Functional Materials

To create materials that are composites or hybrids structured on the nanometer scale or the meso-domain, respectively, is one of the major tasks in modern materials science. In this paper, we demonstrate general strategies on how to obtain these nanocomposites founded on the knowledge about ordered mesoporous material…

Aerogels and thermal insulationMesoporous Materials and CatalysisSupercapacitor Materials and Fabrication

Biomineralization of the Spicules of Sea Urchin Embryos

Fred H. Wilt2002-03-01ZOOLOGICAL SCIENCE

The formation of calcareous skeletal elements by various echinoderms, especially sea urchins, offers a splendid opportunity to learn more about some processes involved in the formation of biominerals. The spicules of larvae of euechinoids have been the focus of considerable work, including their developmental origins.…

Echinoderm biology and ecologyCalcium Carbonate Crystallization and InhibitionMarine Biology and Environmental Chemistry

Molecular Dynamics and Free Energy Analyses of Cathepsin D−Inhibitor Interactions: Insight into Structure-Based Ligand Design

Shuanghong Huo、Junmei Wang、Piotr Cieplak 等 5 位作者2002-03-01Journal of Medicinal Chemistry

In this study, we compare the calculated and experimental binding free energies for a combinatorial library of inhibitors of cathepsin D (CatD), an aspartyl protease. Using a molecular dynamics (MD)-based, continuum solvent method (MM-PBSA), we are able to reproduce the experimental binding affinity for a set of seven…

Protein Structure and DynamicsEnzyme Structure and FunctionComputational Drug Discovery Methods