Materials Literature
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The Ag content in Ag–As–S glasses can be spatially modified by illumination of visible light. Optical and thermal studies demonstrate that the Ag-content modification is caused by Ag+ ionic migration from the dark to the illuminated region in a sample. The migration can be reversed by changing the illuminated region.…
This paper reports the details of a high-pressure and -temperature in situ transmission infrared reactor cell and experimental approaches for investigation of the nature of adsorbates in CO hydrogenation and NO-CO reaction on Rh/SiO 2 catalyst. The infrared cell used in this study allows easy assembling and reliable o…
Abstract The molecular weight (MW) and the molecular weight distribution (MWD) of polyethylene (PE) prepared with various metallocene catalysts were investigated. The weight‐average molecular weight ( M w ) of PE prepared with dicyclopentadienyltitanium dichloride/aluminoxane (Cp 2 TiCl 2 /MAO) was about 4,0 · 10 5 ,…
We derive an expression for the inverse longitudinal dielectric function ${\mathrm{\ensuremath{\varepsilon}}}^{\mathrm{\ensuremath{-}}1}$(k,\ensuremath{\omega}) of a random system of identical spherical particles with dielectric function ${\mathrm{\ensuremath{\varepsilon}}}_{1}$(\ensuremath{\omega}) in a host with die…
Palladium acetate vapor was sublimed at a reduced pressure and was evacuated through the porous wall of an α-alumina support tube of 1.8 mm i.d. and 2.4 mm o.d. Due to chemical vapor deposition (CVD), a thin palladium membrane was formed in macropores of the support. The membrane part was about 50 mm in length and was…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNature of the Relaxation Processes in the Supercooled Liquid and Glassy States of Some CarbohydratesGangasharan and S. S. N. MurthyCite this: J. Phys. Chem. 1995, 99, 32, 12349–12354Publication Date (Print):August 1, 1995Publication History Published online1 May 2002Publishe…
The stability range at room temperature of the orthorhombic phase of ${\mathrm{KNbO}}_{3}$ was investigated under pressure using optical observation and Raman scattering techniques. It was observed that the ferroelectric orthorhombic solid is stable up to the 9--10 GPa pressure range, where it transforms to the parael…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDithiadiazafulvalenes-New Strong Electron Donors. Synthesis, Isolation, Properties, and EPR StudiesGregory V. Tormos, Martin G. Bakker, Ping Wang, M. V. Lakshmikantham, Michael P. Cava, and Robert M. MetzgerCite this: J. Am. Chem. Soc. 1995, 117, 33, 8528–8535Publication Dat…
Abstract Poly(trimethylene terephthalate) was synthesized on a semi‐technical scale following the trans‐esterification route. Ester exchange as well as polycondensation were catalyzed by titanium tetrabutylate. The polymer formed shows a remarkable degree of whiteness, contrary to poly(ethylene terephthalate) when syn…
info:eu-repo/semantics/published
Abstract A new model for the description of the structural disorder in natural kaolinite materials is proposed, based on the stacking of two 1:1 layers and their enantiomorphs, and encompassing previously proposed models. The layers, where randomly stacked along the c axis (using probabilistic functions nested in recu…
Sonodynamic therapy is a promising new modality for cancer treatment based on the synergistic effect on tumor cell killing by combination of a drug (typically a photosensitizer) and ultrasound. The mechanism of sonodynamic action was suggested to involve photoexcitation of the sensitizer by sonoluminescent light, with…
The results of photoluminescence (PL) and electroluminescence (EL) studies from partially oxidized porous silicon (POPS) layers are presented. The PL from POPS is stable, peaks at 600-570 nm and its temperature dependence can be fitted by an exponential law with an activation energy Ea ≈ 10 meV. The current-voltage ch…
Differential scanning calorimetry has been used to make direct measurements of the excess enthalpy of TiO 2 (rutile) with an initial grain size of 30–70 nm. When the heat released during grain growth is normalized to the change in grain boundary area, the specific excess enthalpy at low temperatures and fine grain siz…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynchrotron-Based Method for the Study of Crystallization: Templated Formation of CoALPO-5 CatalystFernando Rey, Gopinathan Sankar, John Meurig Thomas, Phillip A. Barrett, Dewi W. Lewis, C. Richard A. Catlow, Simon M. Clark, and G. Neville GreavesCite this: Chem. Mater. 1995…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAlternating Lamellar Structure of Triblock Copolymers of the ABA TypeY. Matsushita, M. Nomura, J. Watanabe, Y. Mogi, I. Noda, and M. ImaiCite this: Macromolecules 1995, 28, 18, 6007–6013Publication Date (Print):August 1, 1995Publication History Published online1 May 2002Publ…
Polycrystalline yttrium aluminum garnet (YAG) fibers were prepared from commercially available colloidal sols of Y 2 O 3 and AlOOH and water‐soluble polymers. The fibers were dry spun and all processing was performed in air. Transformation to YAG was complete by ≅1300°C, and the fibers were mostly dense by 1600°C with…
The synthesis, solid-state structure and magnetic characterization of KFe3(OMe)7(dbm)3·4MeOH (I; Hdbm = dibenzoylmethane) are reported. I readily assembles in methanolic solns. of Fe(III) chloride and Hdbm in the presence of an excess of K methoxide; it crystallizes in the triclinic space group P-1 with a = 13.044(1),…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectron-transfer boat-vibration mechanism for superconductivity in organic molecules based on BEDT-TTFErsan Demiralp, Siddharth Dasgupta, and William A. Goddard IIICite this: J. Am. Chem. Soc. 1995, 117, 31, 8154–8158Publication Date (Print):August 1, 1995Publication Histor…
Optical reflectivity of free-standing films at the smectic-A--nematic (Sm-A--N) phase transition has been studied. The Sm-A films thin in a stepwise manner in the nematic temperature interval. The film thickness can be described by a power function of maximal temperature at which this thickness is stable. The value of…