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Negative Magneto-Resistance in Pyrolytic Carbons

Kazuhiko Yazawa1969-06-01Journal of the Physical Society of Japan

Negative magneto-resistance is observed in poorly graphitized carbons at liquid nitrogen temperature or even higher. This peculiar phenomenon has been studied on pyrolytic graphite, as a model material. It is concluded that the negative magneto-resistance is a quantum phenomenon caused by a change of the carrier conce…

Graphite, nuclear technology, radiation studiesGraphene research and applicationsCarbon Nanotubes in Composites

Electrocaloric effect in potassium dihydrogen phosphate

G. G. Wiseman1969-06-01IEEE Transactions on Electron Devices

Measurements of the electrocaloric effect from 78 to 130 K were made on crystalline KH2PO4and are discussed in terms of the phenomenological theory of Devonshire and others. The predicted quadratic dependence of the electrocaloric effect upon applied field (and polarization) in the paraelectric phase was shown to occu…

Acoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallographyFerroelectric and Piezoelectric Materials

Photoreversible Photographic Systems. VI. Reverse Photochromism of 1,3,3-Trimethylspiro[indoline-2,2′-benzopyran]-8′-carboxylic Acid

Isamu Shimizu、Hiroshi Kokado、Eiichi Inoue1969-06-01Bulletin of the Chemical Society of Japan

Abstract Many derivatives of 1,3,3-trimethylspiro[indoline-2,2′-benzopyran] (1) exhibit photoreversible color changes in organic solvents. One of the derivatives 1,3,3-trimethylspiro[indoline-2,2′-benzopyran]-8′-carboxylic acid (2) shows “reverse photochromism” in polar solvents. The compound 2 exhibits a deep color i…

bioluminescence and chemiluminescence researchPhotochromic and Fluorescence ChemistryPolydiacetylene-based materials and applications

PREDICTION OF PITTING RATES IN FERROUS METALS FROM SOIL PARAMETERS

John R. Rossum1969-06-01American Water Works Association

From a consideration of pit formation chemistry, equations have been derived that correspond to empirical equations developed by the NBS corrosion group. The theoretical equations' derivations show how soil resistivity and pH affect corrosion rates.

Corrosion Behavior and Inhibition

The influence of strain rate on the mechanical properties and dislocation substructure in deformed copper single crystals

J. W. Edington1969-06-01Philosophical magazine

The mechanical properties, dislocation configurations and densities have been investigated in single crystals of copper deformed in the strain-rate range 10−4 to 104 sec−1. It was found that the flow stress of copper exhibits two regions of strain-rate sensitivity. Below strain rates of 103 sec−1 the flow stress was r…

Ion-surface interactions and analysisHigh-Velocity Impact and Material BehaviorMicrostructure and mechanical properties

Regulation of Glyoxylate Metabolism in Escherichia coli K-12

L. Nicholas Ornston、M. K. Ornston1969-06-01Journal of Bacteriology

The relative contributions of the dicarboxylic acid and the tricarboxylic acid cycles to the oxidative catabolism of glyoxylate in Escherichia coli K-12 were deduced by analysis of mutant strains that were blocked in the formation of glyoxylate carboligase and of malate synthase G (the "glycolate form" of malate synth…

Enzyme function and inhibitionEnzyme Structure and FunctionBiochemical and Molecular Research

New Nonlinear Optical Materials: Metal Oxides with Nonbonded Electrons

J. G. Bergman、G. D. Boyd、A. Ashkin 等 4 位作者1969-06-01Journal of Applied Physics

Molecules or ions of the form BOx−n lack a center of symmetry whenever the B atom has a nonbonded pair of electrons. The problem of generating an acentric crystal can be approached by using these acentric oxygen polyhedrons as building blocks. A very high incidence of acentricity is found in compounds based on distort…

Photorefractive and Nonlinear OpticsNonlinear Optical Materials ResearchCrystal Structures and Properties

Continuum Theory of Liquid Crystals of Nematic Type

J. L. Ericksen1969-06-01Molecular Crystals

We describe continuum theory now being used to describe macroscopic behavior of liquid crystals of nematic type. Two types of predictions are discussed. The first concerns the propagation of orientation waves. The second area is viseometry, including effects of simple electromagnetic fields. We discuss some unusual si…

Advanced Materials and MechanicsNonlinear Dynamics and Pattern FormationLiquid Crystal Research Advancements

Digestibility as a Simple Function of a Molecule of Similar Size to a Cellulase Enzyme

Joseph E. Stone、A. M. Scallan、E. DONEFER 等 4 位作者1969-06-01Advances in chemistry series

Cotton linters were swollen to an increasing extent by means of phosphoric acid of increasing concentration. Using a number of simple sugars plus a series of dextran molecules ranging in M.W. from 180 to 2.4 X 10 7 and diameter from 8 to 1600 A. it was possible to measure the pore volume and calculate the surface area…

Textile materials and evaluationsAdvanced Cellulose Research Studies

Guest-Host Interactions in Nematic Liquid Crystals

George H. Heilmeier、Joseph A. Castellano、Louis A. Zanoni1969-06-01Molecular Crystals

new electro-optic effect based on guest-host interactions in nematic liquid crystals is described. The cooperative alignment of a nematic liquid crystal in an electric field is used to orient “guest” pleochroic dye molecules (molecules whose absorption spectrum is a function of the molecular orientation with respect t…

Nonlinear Dynamics and Pattern FormationMolecular spectroscopy and chiralityLiquid Crystal Research Advancements

Influence of Electric Fields on the Molecular Alignment in the Liquid Crystalp-(Anisalamino)-phenyl Acetate

E. F. Carr1969-06-01Molecular Crystals

The effects of electric fields on the molecular alignment in the liquid crystal p-(anisalamino)-phenyl acetate are discussed. The behavior of this material is similar to that of p-azoxyanisole in that the ordering which is normally observed shows an alignment with the molecular axis preferring a direction parallel to…

Molecular spectroscopy and chiralityLiquid Crystal Research AdvancementsAdvanced NMR Techniques and Applications

Nuclear Magnetic Resonance Powder Patterns in the Presence of Completely Asymmetric Quadrupole and Chemical Shift Effects: Application to Metavanadates

J. F. Baugher、P. Craig Taylor、T. Oja 等 4 位作者1969-06-01The Journal of Chemical Physics

A procedure was developed for the determination of the locations of shoulders and singularities of polycrystalline nuclear magnetic resonance (NMR) powder patterns in the presence of both nuclear quadrupole and anisotropic magnetic shift interactions. This determination was performed for both the satellites and the ce…

Advanced NMR Techniques and ApplicationsMolecular spectroscopy and chiralitySolid-state spectroscopy and crystallography

X-ray investigations concerning the physical structure of cross-linking in urethane elastomers. II. Butanediol as chain extender

R. Bonart、L. Morbitzer、G. Hentze1969-06-01Journal of Macromolecular Science Part B

The elastomers investigated are cross-linked partly by primary and partly by secondary valencies, i.e., by allophanate, biuret, and cyanurate bonds, on the one hand, and by hydrogen bridges and other intermoiecular interactions, on the other. The so-called physical cross-linking effected by secondary valencies is asso…

Polymer Nanocomposites and PropertiesPolymer crystallization and propertiesPolymer composites and self-healing

On Molecular Structure and Physical Properties of Thermotropic Liquid Crystals

A. Saupe1969-06-01Molecular Crystals

Some models for the molecular structures of liquid crystals including a ferroelectric liquid are discussed. It is shown that a smectic liquid with a layered structure, in which the preferred orientation of the molecular axis is inclined against the layers, has some similarities with a nematic liquid. Such a tilted sme…

Nonlinear Dynamics and Pattern FormationLiquid Crystal Research AdvancementsMaterial Dynamics and Properties

Editorial

Equipo Editorial1969-06-01Materiales de Construccion