Materials Literature
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Abstract Scintillation in cerium‐doped gadolinium‐based crystals results from the energy transfer of excited host matrix Gd 3+ ions ( 6 I 7/2,11/2 ; 6 P 7/2,5/2) to the Ce 3+ ions {5d 1 ( 2 T 2 )} which radiatively relax to the ground state.
Abstract A novel biodegradable polyester having pendant amine functional groups was snythesized from N ‐(benzyloxycarbonyl)‐ L ‐aspartic anhydride ( 2 ) and 1,4‐cyclohexanedimethanol ( 3 ) by polycondensation reaction using p‐toluenesulfonic acid as a catalyst. The synthesized polymer 4 shows the characteristic ester…
Abstract Weathering performance of rigid PVC pigmented with iron oxide or some complex inorganic pigments (CIP) containing iron can be poor. Consideration of iron‐containing CIP's for use in exterior PVC leads to the common question: “How much ‘free iron’ is present in the pigment?” It has been unclear what “free iron…
Abstract The effective second harmonic generation coefficient of monomethyl urea has been determined relatively to urea by phase matched interaction. Both Type I and Type II phase matching have been achieved by propagating the pump beam at small angles to natural faces of solution grown crystals. The conversion effici…
Three-dimensional images of the near-surface atom arrangement were calculated from two-dimensional photoelectron diffraction data by several imaging algorithms: (i) a basic method with a Fourier transformation at one kinetic energy over k space, considering the phase factor due to the path-length difference; (ii) ener…
Corrosive exposure and subsequent deterioration of weathering steel structures cause strength loss due to cross-section thinning as well as crack susceptibility due to formation of notches that concentrate stresses. Key issues include rapidly drying versus extended wet time surfaces, the relationship of clean versus d…
Les evolutions microstructurales de l’alliage de titane β-Cez au cours de son forgeage β ont ete suivies par des essais de compression uniaxiale sur une large gamme de vitesse [10-3 -10 s-1 ] et de deformation [0,25,1,5]. L’examen des textures (RX), des structures, des microtextures (EBSD) ainsi que le trace de cartes…
Abstract The oxidative degradation of benzo nuclei of various higher contropolyindanes with ruthenium (VIII) oxide or ozone was studied to further explore the chemistry of partially benzoanellated centrohexaquinanes. Besides the two tribenzotri‐quinacenes 12 and 15 which were used as model substrates for oxidation wit…
We study the time-dependent orientational response of a nematic liquid crystal doped with single-domain ferromagnetic particles. A set of coupled macroscopic equations describing evolution of the director texture, magnetization distribution and concentration of the particles under the change of the external field is d…
A detailed study of electronic and thermal transport properties and linear thermal expansion of ${\mathrm{La}}_{2}$${\mathrm{CuO}}_{4+\mathrm{\ensuremath{\delta}}}$ single crystals with both high oxygen pressure oxidation and electrochemical oxidation were carried out. A series of anomalies of resistivity, thermoelect…
Abstract Mineralogical and chemical heterogeneity within three standard clay mineral samples have been identified by X-ray diffraction and chemical analysis of various size-fractions. This heterogeneity is partly attributed to accessory minerals, but mostly to structural and compositional variations in the 2:1 layer m…
The levels of soluble sugars, starch, pectin and insoluble fibre in blanched green beans, green beans and Padrón peppers were monitored during 12 months' deep-freezing. Blanching did not alter the pectin content of the beans, but reduced their soluble sugar and starch contents by 10 and 8%, respectively. Nonetheless,…
The morphology and optical properties of polymer stabilized liquid crystals formed in a more highly ordered low molecular weight liquid crystal solvent were studied. Tetrafunctional, mesogenic monomers (with and without flexible spacers) were polymerized in isotropic, nematic and smectic phases of the LC solvent (4′-o…
Abstract 11B- and 13C-solid state NMR of boron carbide with different isotope ratios, B4C(11B/10B = 80.42/19.58; natural abundance isotope) and 11B4C(11B/10B = 99.5/0.5; 11B enriched sample), has been investigated. The linewidth of the icosahedral B (6h1and 6h2) in 11B-static NMR signal in 11B4C was greater in 11B4C t…
Powder X-ray diffraction data are reported for La 0.6 Sr 0.4 Co 1− y Fe y O 3 ( y =0.1, 0.25, 0.4, 0.6, 0.8, 1.0). The powders were prepared by thermal decomposition of metal-containing complex solutions. All compositions have rhombohedral unit cells. In hexagonal setting, the cell parameters are a =5.4388 Å, c =13.23…
Abstract Ca 2 P 2 S 6 und Sr 2 P 2 S 6 wurden aus Metall und einem Gemenge von rotem Phosphor und Schwefel (Molverhältnis M:P:S = 1:1:3) in 2 Korundinnentiegeln in Quarzampullen unter Vakuum (20 d 900°C) als farblose, grobkristalline Pulver, die Einkristalle enthalten, rein dargestellt. Beide sind mit der Hochtemperat…
Abstract The thermal and light‐induced spin transitions in [Fe(bpen)(NCS) 2 ] and [Fe(bpen)(NCSe) 2 ] have been investigated by means of magnetic susceptibility and Mössbauer measurements. The HS → LS transition in [Fe(bpen)(NCS) 2 ] is detected at temperatures below 120 K ( T 1/2 [when the fraction of high‐spin speci…
IR depth profiling of propane‐stabilized calcia‐alumina fibers showed that carbon deposited on the fibers during melt‐spinning induced tetrahedral coordination of aluminum atoms near the fiber surface. It is proposed that this effect increases melt surface viscosity and stabilizes calcia‐alumina fibers. Ethers, esters…
This article points to the importance of penetrating micropores through the graft wall to minimize thrombosis and to enhance endothelialization in small diameter polymer skin coated vascular grafts. Four types of spongy polyurethane-polydimethylsiloxane vascular grafts (PUG) fabricated by a spray, phase-inversion tech…
Abstract Crystallization behavior of deproteinized natural rubber at −25°C was investigated by dilatometry in connection with the effect of long-chain fatty acid groups, esterified to the rubber chain, as well as free fatty acids and their esters. The overall crystallization rate decreased after removal of the acetone…