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On the temperature dependence of the order parameter of liquid crystals over a wide nematic range

Matthew L. Magnuson、B. M. Fung、J. P. Bayle1995-12-01Liquid Crystals

Based on the ideas of Landau-de Gennes theory applied to nematic liquid crystals, several forms for the variation of the order parameter as a function of temperature are investigated over a wide nematic range. These functional forms are used to fit the experimental order parameters, determined through the use of C-13…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Effects of mixing porcedures on properties of compatibilized polypropylene/nylon 6 blends

Jae‐Dong Lee、Seung‐Man Yang1995-12-01Polymer Engineering and Science

Abstract The paper consides the effects of compatibilization with maleic anhydride grafted polypropylene (PP‐g‐MAH) on the propertie of immiscible blends of polypropylene (PP) and nylon 6 (N6). We prepared the blends by three different mixing processes; single‐step blending, two‐step blending with reactive premixing,…

Polymer crystallization and propertiesNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Reduced electronic density matrices, effective Hamiltonians, and nonlinear susceptibilities of conjugated polyenes

GuanHua Chen、Shaul Mukamel1995-12-01The Journal of Chemical Physics

The ground state single-electron reduced density matrix is shown to contain the essential chemical bonding information relevant for calculating the nonlinear optical response of conjugated polymers. Applications to a series donor-acceptor substituted Hexatrienes demonstrate the interplay of electronic structure and dy…

Porphyrin and Phthalocyanine ChemistryNonlinear Optical Materials ResearchPhotochemistry and Electron Transfer Studies

Migration of Cu Ions in Cu Montmorillonite Heated with and without Alkali Halides

L. Heller‐Kallai、C. Mosser1995-12-01Clays and Clay Minerals

Abstract Cu montmorillonite heated with or without potassium halide was studied by IR and ESR spectroscopy, supplemented by XRD measurements, microprobe and chemical analyses. It appears that on heating Cu montmorillonite, most of the Cu ions migrate into hexagonal cavities and eventually, when dehydroxylation occurs,…

Concrete and Cement Materials ResearchZeolite Catalysis and SynthesisClay minerals and soil interactions

EFFECT OF CURRENT VELOCITY ON THE DETACHMENT OF THALLI OF ULVA LACTUCA (CHLOROPHYTA) IN A NEW ZEALAND ESTUARY

Ian Hawes、Rob Smith1995-12-01Journal of Phycology

ABSTRACT Experiments were undertaken in a recirculating flume to determine the relationships among water velocity, thallus area, drag, and the probability of thallus breakage or detachment in the foliose green alga Ulva lactuca L. In all specimens tested to breaking point, thalli detached from their bivalve substrates…

Marine and coastal plant biologyDiatoms and Algae Research

Kink switching in ferroelectric free-standing films with high spontaneous polarization

Е. И. Демихов、S. A. Pikin、E. S. Pikina1995-12-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

The dynamics of a Sm-${\mathit{C}}^{\mathrm{*}}$ director field in an ac electric field has been studied by means of light scattering. Scattering of resonance type has been observed by variation of field frequency at fixed temperatures. The resonance scattering is suppressed in high electric fields, at low temperature…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesTheoretical and Computational Physics

In situ 31P nuclear magnetic resonance for observation of polyphosphate and catabolite responses of chemostat-cultivated Saccharomyces cerevisiae after alkalinization

Cristina De Castro、A. J. Meehan、Alan P. Koretsky 等 4 位作者1995-12-01Applied and Environmental Microbiology

The proposed pH buffering and phosphagenic functions of polyphosphate were investigated by subjecting chemostat-cultivated Saccharomyces cerevisiae to alkalinization (NaOH addition) and anaerobiosis. The subsequent changes in intracellular phosphate-containing species were observed in situ by nuclear magnetic resonanc…

Fungal and yeast genetics researchbiodegradable polymer synthesis and propertiesPhosphorus and nutrient management

Neutron Reflectometry Study of Surface Segregation in an Isotopic Poly(ethylenepropylene) Blend: Deviation from Mean-Field Theory

Laura J. Norton、Edward J. Krämer、Frank S. Bates 等 8 位作者1995-12-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNeutron Reflectometry Study of Surface Segregation in an Isotopic Poly(ethylenepropylene) Blend: Deviation from Mean-Field TheoryL. J. Norton, E. J. Kramer, F. S. Bates, M. D. Gehlsen, R. A. L. Jones, A. Karim, G. P. Felcher, and R. KlebCite this: Macromolecules 1995, 28, 25…

Polymer crystallization and propertiesPhase Equilibria and ThermodynamicsMaterial Dynamics and Properties

Sb-rich titanite in the manganese concentrations at St. Marcel-Praborna, Aosta Valley, Italy: petrography and crystal-chemistry

E.A. Perseil、David C. Smith1995-12-01Mineralogical Magazine

Abstract Titanites rich in antimony (up to 12.59 wt.% Sb 2 O 5 ; equal to 0.165 Sb 5+ per Si 4+ = 1.000) arc described for the first time. They coexist with various greenschist-facies minerals in three different petrographical environments in the manganese concentrations at St. Marcel-Praborna in the Aosta Valley, Ita…

Crystal Structures and PropertiesNuclear materials and radiation effectsCrystallography and Radiation Phenomena

Interpretation of 3‐D permeability measurements for RTM modeling

Dara L. Woerdeman、Frederick R. Phelan、Richard S. Parnas1995-12-01Polymer Composites

Abstract The resin transfer molding (RTM) technique often utilizes reinforcement with a complex fiber architecture. Several parameters, including the permeability tensor, are necessary to characterize the flow behavior in these intricate fibrous porous media. In this paper, a general procedure for extracting three‐dim…

High voltage insulation and dielectric phenomenaEpoxy Resin Curing ProcessesAerosol Filtration and Electrostatic Precipitation

Formation and Stability of Ni(I) Ions in MCM-41 Mesoporous Molecular Sieves

Martin Hartmann、Andreas Pöppl、Larry Kevan1995-12-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFormation and Stability of Ni(I) Ions in MCM-41 Mesoporous Molecular SievesMartin Hartmann, Andreas Poppl, and Larry KevanCite this: J. Phys. Chem. 1995, 99, 49, 17494–17496Publication Date (Print):December 1, 1995Publication History Published online1 May 2002Published iniss…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisElectrochemical Analysis and Applications

Estimation of time-to-flashover characteristics of contaminated electrolytic surfaces using a neural netlwork

P.S. Ghosh、S. Chlakravorti、N. Chatterjee1995-12-01IEEE Transactions on Dielectrics and Electrical Insulation

A major field of neural networks (NN) application is function estimation, because the useful properties of NN such as adaptivity and nonlinearity are well suited to function estimation tasks where the equation describing the function is unknown. In this paper the prerequisite trainiing data are obtained from experimen…

High voltage insulation and dielectric phenomenaImage and Signal Denoising MethodsEnergy Load and Power Forecasting

Self-Organization of Polymethine Dyes in Thin Solid Layers

Lars Daehne1995-12-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSelf-Organization of Polymethine Dyes in Thin Solid LayersLars DaehneCite this: J. Am. Chem. Soc. 1995, 117, 51, 12855–12860Publication Date (Print):December 1, 1995Publication History Published online1 May 2002Published inissue 1 December 1995https://doi.org/10.1021/ja00156…

Gold and Silver Nanoparticles Synthesis and ApplicationsMolecular Junctions and NanostructuresElectrochemical Analysis and Applications

Non-Symmetric Tension-Compression Behaviour of NiTi Alloy

Laurent Orgéas、Denis Favier1995-12-01Journal de Physique IV (Proceedings)

Development of tensorial constitutive equations suitable to model the thermomechanical behaviour of shape memory alloys (SMA) would greatly help engineering design of sophisticated components. While a number of studies have focused on mechanical behaviour under tensile loading, only a few have been done to characteris…

Shape Memory Alloy Transformations

Metal Oxide Surfaces: Electronic Structure and Molecular Adsorption

Hans‐Joachim Freund1995-12-01physica status solidi (b)

Abstract The surface science of oxides has received considerably less attention than the study of metal surfaces. We review some of our work on structural characterization and electronic structure investigations on oxide surfaces which we prepare as thin oxide films on metallic substrates. This preparation method lead…

Advanced Chemical Physics StudiesElectron and X-Ray Spectroscopy TechniquesChemical and Physical Properties of Materials

On the Number of Statistically Independent Observations in a Powder Diffraction Pattern

Angela Altomare、G. Cascarano、Carmelo Giacovazzo 等 7 位作者1995-12-01Journal of Applied Crystallography

When in a powder diffraction pattern two or more peaks heavily overlap, the integrated intensities of the overlapping reflections are correlated. This paper describes a method, based on the study of the peak overlap, which estimates the number of statistically independent intensities associated with a powder diagram.…

Crystallography and molecular interactionsCrystallization and Solubility StudiesX-ray Diffraction in Crystallography

Surface molecular motion in thin films of poly(styrene‐block‐methyl methacrylate) diblock copolymer

Keiji Tanaka、Atsushi Takahara、T. Kajiyama1995-12-01Acta Polymerica

Abstract Thin films of poly(styrene‐ block ‐methyl methacrylate) diblock copolymer [P(St‐ b ‐MMA)] with thickness ca. 50 nm were prepared by a dip‐coating method. The surface T g for the P(St‐ b ‐MMA) thin film was evaluated on the basis of the temperature‐dependent X‐ray photoelectron spectroscopic (TDXPS) measuremen…

Block Copolymer Self-AssemblyCopper Interconnects and ReliabilitySynthesis and properties of polymers

Mediated Activation and Electroreduction of CO 2 on Modified Electrodes with Conducting Polymer and Inorganic Conductor Films

Kotaro Ogura、Nobutaka Endo、Masaharu Nakayama 等 4 位作者1995-12-01Journal of The Electrochemical Society

In order to diminish the overpotential required for the electrochemical reduction of CO 2 , a metal complex‐fixed polyaniline (PAn)/prussian blue (PB)‐modified electrode has been developed, and the roles of the two laminated films as well as a fixed metal complex are disclosed here. The onset potential for the reducti…

Electrochemical sensors and biosensorsConducting polymers and applicationsCO2 Reduction Techniques and Catalysts

Single Correction Function for Computing Retarded van der Waals Attraction

A. Anandarajah、J. Chen1995-12-01Journal of Colloid and Interface Science

Due to the inherent complexity of the general Lifshitz theory, the Hamaker–De Boer approach is still used in computing the van der Waals attractive force in systems with macrobodies of complex shapes. To account for the retardation of force computed by this approach, the London equation has in the past been modified b…

Material Dynamics and PropertiesSpectroscopy and Quantum Chemical StudiesElectrostatics and Colloid Interactions

Modeling Water Chemistry, Electrochemical Corrosion Potential, and Crack Growth Rate in the Boiling Water Reactor Heat Transport Circuits—I: The DAMAGE-PREDICTOR Algorithm

Tsung‐Kuang Yeh、Digby D. Macdonald、Arthur T. Motta1995-12-01Nuclear Science and Engineering

A computer code with the capability of simultaneously estimating the concentrations of radiolysis species, the electrochemical corrosion potential, and the kinetics of growth of a reference crack in sensitized Type 304 stainless steel is developed for the heat transport circuits of boiling water reactors (BWRs). The p…

Hydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and PropertiesNuclear Engineering Thermal-Hydraulics