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Hydrothermal processings to produce magnetic particulates

Cheng‐Hsiung Lin、Zong‐Whie Shih、T.S. Chin 等 5 位作者1990-01-01IEEE Transactions on Magnetics

alpha -Fe/sub 2/O/sub 3/, gamma -Fe/sub 2/O/sub 3/, and alpha -FeOOH powders were used as starting materials to prepare barium hexaferrite hydrothermally. Since strontium hexaferrite and lanthanum-doped calcium hexaferrite have coercivities similar to that of barium ferrite, the hydrothermal synthesis of strontium hex…

Magnetic Properties and Synthesis of FerritesMinerals Flotation and Separation TechniquesIron oxide chemistry and applications

Transition mechanism from elastic deformation to plastic flow in poly(methyl methacrylate)

Yukuo Nanzai1990-01-01Polymer Engineering and Science

Abstract Sudden changes of compressive strain‐rate on glassy poly(methyl methacrylate) lead to the conclusion that the post‐yield state under a constant stress is a state of steady flow in the polymer. Non‐linearity between the stress divided by temperature and the logarithm of strain rate for this steady plastic flow…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

The first structurally characterized alkali metal porphyrin: 7Li NMR behaviour and X-ray crystal structure of the dilithium salt of octaethylporphyrin(2?)

John Arnold1990-01-01Journal of the Chemical Society Chemical Communications

Reaction of H2oep (oep = dianion of octaethylporphyrin) with two equivalents of LiN(SiMe3)2 in tetrahydrofuran (thf) yields the dilithium salt [Li(thf)4][Li(oep)], characterized in the solid state by X-ray crystallography; in solution, 7Li NMR and conductivity measurements show a more complex, solvent-dependent struct…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesOrganic and Molecular Conductors Research

Synthesis, structures, and electrochemistry of palladium and platinum macrocyclic complexes of [18]aneN 2 S 4 (1,4,10,13-tetrathia-7,16-diazacyclo-octadecane) and Me 2 [18]aneN 2 S 4 (7,16-dimethyl-1,4,10,13-tetrathia-7,16-diazacyclo-octadecane). Single crystal X-ray structures of [Pd(Me 2 [18]aneN 2 S 4 )][PF 6 ] 2 ·Me 2 CO, [Pd([18]aneN 2 S 4 )][BPh 4 ] 2 , and [Pd 2 Cl 2 ([18]aneN 2 S 4 )][PF 6 ] 2 ·2MeCN

Alexander J. Blake、Gillian Reid、Martin Schröder1990-01-01Journal of the Chemical Society Dalton Transactions

Reaction of PdCl2 with the N2S4 donor macrocycles [18]aneN2S4(1,4,10,13-tetrathia-7,16-diazacyclo-octadecane) and Me2[18]aneN2S4(7,16-dimethyl-1,4,10,13-tetrathia-7,16-diazacyclo-octadecane) affords the 1 : 1 complex cations [Pd([18]aneN2S4)]2+ and [Pd(Me2[18]aneN2S4)]2+ respectively in high yield. The yellow complex…

Magnetism in coordination complexesPolyoxometalates: Synthesis and ApplicationsInorganic Chemistry and Materials

Effect of corona discharge treatment on cellulose prepared from beech wood

Tohru Uehara、Isao Sakata1990-01-01Journal of Applied Polymer Science

Abstract Cellulose prepared from beech wood ( Fagus crenata Blume) was treated in a corona discharge. The chemical changes produced by the treatment were investigated by use of infrared spectrum, Schiff's reaction, adsorption of methylene blue and Orange II, and intrinsic viscosity. Infrared absorption bands at 1382 a…

Surface Modification and SuperhydrophobicityAdvanced Cellulose Research StudiesElectrohydrodynamics and Fluid Dynamics

Studies of the UV/Ozone oxidation of GaAs using angle‐resolved x‐ray photoelectron spectroscopy

B.J. Flinn、N. S. McIntyre1990-01-01Surface and Interface Analysis

Abstract Angle‐resolved x‐ray photoelectron spectroscopy (ARXPS) has been used to study the composition of oxides grown on 〈110〉 and 〈100〉 GaAs during exposure to UV/ozone. The effects of substrate treatments on oxide growth were compared on 〈100〉 surfaces exposed to an HF treatment and thermal desorption of the oxide…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy TechniquesGa2O3 and related materials

Solvent regeneration of spent activated carbon in wastewater treatment.

Hajime Tamon、Takashi Saito、Masaaki Kishimura 等 5 位作者1990-01-01JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

Ethanol regeneration was applied to spent activated carbon which had adsorbed an organic compound in aqueous solutions, including an industrial wastewater. High regeneration efficiency was achieved except for aromatic compounds substituted by electron-donating groups. In the case where ethanol regeneration was not eff…

Catalytic Processes in Materials Science

Characterization of pulp refiners by a C-factor

Richard J. Kerekes1990-01-01Nordic Pulp & Paper Research Journal

Keywords Disk refiners, Conical refiners, Cellulose fibers, Refining, Process variables, Energy, Fineness, Fiber length, Grooves, Bars, Impact, Equations

Advanced Cellulose Research StudiesMaterial Properties and Processing

Surface modified polysulfone hollow fibers. III. Fibers having a hydroxide group

Akon Higuchi、Tsutomu Nakagawa1990-01-01Journal of Applied Polymer Science

Abstract Polysulfone ultrafiltration hollow fibers were chemically modified on the surfaces with propylene oxide and Friedel‐Crafts catalysts. A peak at 1.6 ppm was observed in H 1 ‐NMR spectrum of the modified fibers at 45°C, while the peak was not observed at 27°C measurements. The peak was attributed to a hydroxide…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Elastic Properties of Three-dimensional Angle-interlock Fabric Preforms

Joon‐Hyung Byun、Tsu-Wei Chou1990-01-01Journal of the Textile Institute

An Investigation is reported in which a model based upon fabric geometry was developed to predict the thread-volume fraction and elastic constants of three-dimensional angle-interlock fabric composites. The architecture of this model was investigated by identifying the structural and geometric parameters. The structur…

Mechanical Behavior of CompositesTextile materials and evaluationsStructural Analysis and Optimization

Effects of Chromate and Vanadate Anions on the Hot Corrosion of Preoxidized Ni by a Thin Fused Na2 SO 4 Film at 900°C

N. Ōtsuka、Robert A. Rapp1990-01-01Journal of The Electrochemical Society

The effects of chromate and vanadate anions on the hot corrosion of preoxidized Ni by a thin fused film in an gas atmosphere at 900°C were investigated by use of a sodium sensor and an oxygen probe. The chromate anion suppressed the sulfidation of Ni probably by precipitating solid from the melt. However, the corrosio…

Corrosion Behavior and InhibitionHigh-Temperature Coating BehaviorsAnodic Oxide Films and Nanostructures

Effect of Grain Size and Poling on the Fracture Mode of Lead Zirconate Titanate Ceramics

Jong‐Min Kim、Doh‐Yeon Kim、Jeong‐Joo Kim 等 4 位作者1990-01-01Journal of the American Ceramic Society

The fracture mode of lead zirconate titanate (PZT) ceramics at room temperature is investigated as a function of grain size. The fracture mode is almost intergranular at small grain size and changes to predominantly transgranular at large grain size. Application of an electric field (poling) causes a change in the fra…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisAcoustic Wave Resonator Technologies

Advanced electronic packaging materials

A.T. Barfknecht、Julian P. Partridge、C.J. Chen 等 4 位作者1990-01-01OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)

This proceeding contains papers on advanced electronic packaging materials. Included are the following topics: Optoelectronics, Polymers, Composites, Aluminum Nitride, and Metallization.

Synthesis and properties of polymers

Electrochemical Codeposition of Gallium and Arsenic from a Room Temperature Chlorogallate Melt

Michael K. Carpenter、Mark W. Verbrugge1990-01-01Journal of The Electrochemical Society

An electrodeposition process by which gallium arsenide can be formed at room temperatures is reported. Gallium and arsenic can be codeposited from a room temperature melt comprised of and ImCl (1‐methyl‐3‐ethylimidazolium chloride) and an solute. Codeposition is studied over a potential range of 0 to −2V relative to a…

Silicon Nanostructures and PhotoluminescenceSemiconductor materials and interfacesAnodic Oxide Films and Nanostructures

Detection of Joule heating before dielectric breakdown in polyethylene films

M. Nagao、Takayuki Kimura、Yukio Mizuno 等 5 位作者1990-01-01IEEE Transactions on Electrical Insulation

Local Joule heating in polyethylene films was detected at room temperature before dielectric breakdown under DC field. When a high-temperature point appeared in a film, the conduction current increased with time. The final breakdown occurred at the point of the highest temperature. This concurrence of the breakdown po…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and Insulation

Recent advances in the one- and two-dimensional magnetic measurement technique for electrical sheet steel

J. Sievert1990-01-01IEEE Transactions on Magnetics

The problems connected with measuring the magnetic properties of electrical sheet steel under the condition of one-dimensional (alternating) and two-dimensional excitation (circular, elliptic, and alternating with rotation of the direction) are surveyed. Regarding the classical case of one-dimensional excitation, the…

Magnetic Properties and ApplicationsNon-Destructive Testing TechniquesMagnetic Field Sensors Techniques

Time-resolved observation of isothermal phase transition of liquid crystals triggered by photochemical reaction of dopant

Seiji Kurihara、Tomiki Ikeda、Takeo Sasaki 等 5 位作者1990-01-01Journal of the Chemical Society Chemical Communications

A mixture of 4-butyl-4′-methoxyazobenzene (BMAB) and 4-n-pentyl-4′-cyanobiphenyl (5CB)([BMAB]/[5CB]= 0.03) undergoes an isothermal phase transition on pulse irradiation at 355 nm (10 ns fwhm), in which the relaxation from the nematic to the isotropic phase was completed within ∼ 100 ms as shown by time-resolved birefr…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesSpectroscopy and Quantum Chemical Studies

Molecular-beam studies of methanol partial oxidation on Cu(110)

Colin Barnes、Paul D. A. Pudney、Quanmin Guo 等 4 位作者1990-01-01Journal of the Chemical Society Faraday Transactions

A thermal molecular-beam system has been used to examine the oxidative dehydrogenation of methanol on the Cu(110) surface. The initial sticking probability for oxygen is 0.21 (±0.01) at room temperature and shows a near linear dependence of sticking coefficient on atomic coverage due to an island growth mechanism with…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Rheology of weakly interacting colloidal particles at high concentration

Richard Buscall、Ian J. McGowan、Colin A. Mumme-Young1990-01-01Faraday Discussions of the Chemical Society

The paper describes an experimental study of the rheology of concentrated latex under conditions where a secondary miminum in the interparticle pair potential is expected. Particular attention is given to the Bingham stress σB derived from steady-shear-flow data, which is taken as a measure of the additional or extra…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsRheology and Fluid Dynamics Studies