Materials Literature
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The infrared spectra of lithium isocyanide and of sodium and potassium cyanides in the solid phase were examined over the range 4000 to 140 cm −1 at room temperature. A study of the effect of cooling the solids to liquid nitrogen temperature has been carried out.
On the basis of polarization arguments, the equality τd=τl is proposed as the critical condition for the threshold point of chalcogenide glass switches, τd being the dielectric relaxation time and τl the carrier lifetime. It is shown that this switching criterion is in good agreement with measurements and that it expl…
Abstract Das Mössbauer‐Spektrum von 119 Sn in Sn 2 O 3 zeigt, daß in dieser Verbindung zwei‐ und vierwertiges Zinn vorliegen. Die verhältnismäßig große Quadrupolaufspaltung des Zinn(II) weist auf eine niedrige Symmetrie der ersten Koordinationssphäre hin, während sich Zinn(IV) in ähnlicher Umgebung wie im SnO 2 befind…
It is shown that the electric-field-induced cholesteric-nematic phase transition of mixed liquid crystal possesses two important properties; (i) a sharp threshold in the scattering- vs. -voltage characteristic and (ii) an electrically controllable relaxation time. The mixed liquid crystal is composed of p- n -butoxybe…
The general problem of which insulator configuration is best for gas-insulated systems is considered. A smooth disc is compared with both a corrugated disc and a cone and the cone is seen to have considerable potential. Impulse and switching surge voltages are more severe than 60 Hz when contamination is present on th…
The shear moduli, C44 and C55, and the temperature dependence have been computed for the orthorhombic unit cell of paraffinic hydrocarbons. The computations were conducted by expressing the shear moduli in terms of intermolecular interactions formulated for infinitely long rows of H…H force centers. The interaction pa…
A dislocation distribution is initially in equilibrium, piled up against a block by a uniform applied stress. The block is removed and the subsequent motion of the distribution, for a linear stress—velocity law, is analysed by the complex representation introduced in Parts I to V of this study of dislocation group dyn…
The $4{f}^{14}\ensuremath{\rightarrow}4{f}^{13}5d$ absorption spectrum of an ${\mathrm{Yb}}^{2+}$ ion in cubic crystals is demonstrated to have four peaks, which correspond to the four $5d ({e}_{g} or {t}_{2g}) 4{f}^{13}(^{2}F_{\frac{7}{2}} or ^{2}F_{\frac{5}{2}})$ final states.
Abstract In order critically to evaluate the previous morphological interpretations of stress relaxation during oriented crystallization, a reexamination was made of the relaxation behavior of the same oriented natural rubber material used for the x‐ray investigation in Part II of this series. Our results were found t…
Air oxidation of (U, Pu)O 2 solid solutions having Pu/(U+Pu) ratios of 0.2 and 0.25 was studied using a recording thermal balance. For Pu/(U+Pu)=0.2, the original fluorite MO 2 phase oxidized first to tetragonal M 3 O 7 ; further oxidation at 450°C< T <600°C gave a two‐phase mixture of M' 3 O 8 and a cubic phase…
The absorption spectrum of thin films of CfCl3 was measured at 298, 77, and 4°K in the range 6000–46 000 cm−1. Interpretation of the results was based on systematic variation of energy level parameters over the actinide series. Electrostatic, spin-orbit, and configuration interaction terms were calculated by diagonali…
Abstract A method for determining long‐chain branching frequency and molecular weight averages for unfractionated low‐density polyethylene (LDPE) by the combined use of gel‐permeation chromatography (GPC) and intrinsic viscosity data has been reported (GPC–IV method). The method assumes that the number of long branche…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLaser emission spectrography of rare earth elementsToshio. IshizukaCite this: Anal. Chem. 1973, 45, 3, 538–541Publication Date (Print):March 1, 1973Publication History Published online1 May 2002Published inissue 1 March 1973https://pubs.acs.org/doi/10.1021/ac60325a024https:/…
Calcium carbonate structure in mollusc shells can be determined by infrared spectroscopy. Infrared analysis is easier and less expensive than most other current methods for macroscopic analysis of the structures in gross calcium carbonate. Shell specimens from 22 river species were shown to be entirely aragonite; the…
The effects of wash-water temperature, cold-water or regular detergent, wash-cycle design, drying, and drying temperature on survival of four microorganisms on polyester-cotton sheeting were examined. Escherichia coli T3 bacteriophage survived washing at 24, 35, 46, and 57 C, but not at 68 C. Serratia marcescens survi…
In‐reactor creep tests were performed on stoichiometric UO 2 helices enriched with 1.82% 235 U at fission rates of 2×10 12 to 1.5×10 13 fissions/cm 3 ‐s and outer‐fiber shear stresses of 2890 and 2090 psi. Depending on the test procedure, the initial creep transient either decelerated continuously or was of the sigmoi…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotochemistry of polyenes. III. Preparation of 7-cis-ionyl and ionylidene derivatives and other sterically hindered olefins by one-way sensitized geometric isomerizationV. Ramamurthy, Y. Butt, C. Yang, P. Yang, and R. S. H. LiuCite this: J. Org. Chem. 1973, 38, 6, 1247–1249…
Cu and Cu—Al alloys were pre-stressed to produce strains of the order of 10−4 and then reverse strained to study the Bauschinger effect. Under these conditions of pre-stressing cross slip will not occur to any significant degree and variations in the mechanical properties of the alloys reflect differences in the type…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal structure and single-crystal electron paramagnetic resonance data for bis[dihydrobis(1-pyrazolyl)borato]cobalt(II)L. J. Guggenberger, C. T. Prewitt, P. Meakin, S. Trofimenko, and J. P. JessonCite this: Inorg. Chem. 1973, 12, 3, 508–515Publication Date (Print):March 1…
Abstract A differential conductimetric apparatus allowing the continuous titration of HCl carried by a stream of gas with a limit sensitivity of 40 nanograms is described and applied to study the initial steps of poly(vinyl chloride) thermal degradation. The powdered sample is placed in a quartz cell which may be clos…