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Polytype Diversity of the Hydrotalcite-Like Minerals I. Possible Polytypes and their Diffraction Features

A. S. Bookin、V. A. Drits1993-10-01Clays and Clay Minerals

Abstract All possible polytypes of hydrotalcite-like minerals with a periodicity along the c axis of one-, two- and three-layers, as well as the simplest six-layer polytypes, were derived on the basis of the concept of closely packed brucite-like layers. Multilayer structures were found to be possible in several polyt…

Layered Double Hydroxides Synthesis and ApplicationsClay minerals and soil interactionsMesoporous Materials and Catalysis

Facile elaboration of porphyrins via metal-mediated cross-coupling

Stephen G. DiMagno、Victor S.‐Y. Lin、Michael J. Therien1993-10-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFacile elaboration of porphyrins via metal-mediated cross-couplingStephen G. DiMagno, Victor S. Y. Lin, and Michael J. TherienCite this: J. Org. Chem. 1993, 58, 22, 5983–5993Publication Date (Print):October 1, 1993Publication History Published online1 May 2002Published iniss…

Photosynthetic Processes and MechanismsSurface Chemistry and CatalysisPorphyrin and Phthalocyanine Chemistry

Linear and Nonlinear Optical Properties of TeO 2 Glass

Sae‐Hoon Kim、Toshinobu Yoko、Sumio Sakka1993-10-01Journal of the American Ceramic Society

A thin plate of TeO 2 glass of 5.0 × 4.0 × 0.25 mm 3 size, which was large enough for various optical measurements, was obtained by a rapid quenching method. The linear refractive index was measured as a function of wavelength from 486.1 to 1000 nm. The refractive index at 486.1 nm was as high as 2.239. The optical en…

Photorefractive and Nonlinear OpticsCrystal Structures and PropertiesGlass properties and applications

X-ray-absorption studies of zirconia polymorphs. I. Characteristic local structures

Ping Li、I‐Wei Chen、James E. Penner‐Hahn1993-10-01OpenAlex

Characteristic extended x-ray-absorption fine structure and x-ray-absorption near-edge structure spectra of zirconia polymorphs (monoclinic, orthorhombic, tetragonal, and cubic) have been identified at 10 K. For the host cations, these spectra are phase dependent but dopant independent because the dopant perturbation…

X-ray Diffraction in CrystallographyCrystal Structures and PropertiesNuclear materials and radiation effects

Strain hardening of thermoplastics

R. N. Haward1993-10-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStrain hardening of thermoplasticsR. N. HawardCite this: Macromolecules 1993, 26, 22, 5860–5869Publication Date (Print):October 1, 1993Publication History Published online1 May 2002Published inissue 1 October 1993https://pubs.acs.org/doi/10.1021/ma00074a006https://doi.org/10…

Polymer Science and ApplicationsTribology and Wear AnalysisMaterial Properties and Applications

Bragg gratings in an acrylate polymer consisting of periodic polymer-dispersed liquid-crystal planes

Richard L. Sutherland、L. V. Natarajan、Vincent P. Tondiglia 等 4 位作者1993-10-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTBragg gratings in an acrylate polymer consisting of periodic polymer-dispersed liquid-crystal planesR. L. Sutherland, L. V. Natarajan, V. P. Tondiglia, and T. J. BunningCite this: Chem. Mater. 1993, 5, 10, 1533–1538Publication Date (Print):October 1, 1993Publication History…

Photonic Crystals and ApplicationsLiquid Crystal Research Advancements

Microbial degradation of poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) in soils

Joris Mergaert、Antonio R. Webb、C. S. Anderson 等 5 位作者1993-10-01OpenAlex

The microbial degradation of tensile test pieces made of poly(3-hydroxybutyrate) [P(3HB)] or a copolymer of 90% 3-hydroxybutyric acid and 10% 3-hydroxyvaleric acid was studied in soils incubated at a constant temperature of 15, 28, or 40 degrees C for up to 200 days. In addition, hydrolytic degradation in sterile buff…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisMicroplastics and Plastic Pollution

Porphyrin sponges: conservative of host structure in over 200 porphyrin-based lattice clathrates

Marianne P. Byrn、Carol J. Curtis、Y. Hsiou 等 8 位作者1993-10-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPorphyrin sponges: conservative of host structure in over 200 porphyrin-based lattice clathratesMarianne P. Byrn, Carol J. Curtis, Yu Hsiou, Saeed I. Khan, Philip A. Sawin, S. Kathleen Tendick, Aris Terzis, and Charles E. StrouseCite this: J. Am. Chem. Soc. 1993, 115, 21, 94…

Marine Sponges and Natural ProductsPorphyrin and Phthalocyanine ChemistryCoral and Marine Ecosystems Studies

Quantitative mineralogical analysis using the Rietveld full-pattern fitting method

D. L. Bish、Jeffrey E. Post1993-10-01OpenAlex

Ansrnlcr Quantitative phase analysis of a number of multicomponent standard and natural mineral mixtures has been done using an adaptation of the Rietveld method. Binary mixtures (most 50:50 by weight) of corundum with quartz, hematite, ilmenite, magnetite, biotite, analcime, mordenite, or clinoptilolite were analyzed…

X-ray Diffraction in CrystallographyHigh-pressure geophysics and materialsGeochemistry and Geologic Mapping

Number of relevant independent points in x-ray-absorption fine-structure spectra

Edward A. Stern1993-10-01OpenAlex

A discussion is given of the amount of information present in x-ray-absorption fine-structure spectra. It is shown that the usual formulations underestimate the degrees of freedom by at least one.Received 1 June 1993DOI:https://doi.org/10.1103/PhysRevB.48.9825©1993 American Physical Society

Advanced X-ray Imaging TechniquesX-ray Diffraction in CrystallographyEnzyme Structure and Function

The Physics of Macropore Formation in Low Doped n‐Type Silicon

V. Lehmann1993-10-01OpenAlex

Macropore formation in n‐type silicon is a self‐adjusting phenomenon characterized by a specific current density at the pore tip. At this specific current density, the dissolution reaction changes from the charge‐transfer‐limited to the mass‐transfer‐limited regime. The passivation of the pore walls in hydrofluoric ac…

Advanced Surface Polishing TechniquesSilicon and Solar Cell TechnologiesSilicon Nanostructures and Photoluminescence

Changes in macromolecular organization in collagen assemblies during secretion in the nidamental gland and formation of the egg capsule wall in the dogfish Scyliorhinus canicula

David P. Knight、Dian Feng、Murray Stewart 等 4 位作者1993-09-29Philosophical Transactions of the Royal Society B Biological Sciences

Abstract The thickest layer (L2) of the egg capsule wall of the dogfish, Scyliorhinus Canicula, is constructed largely from highly ordered collagen fibrils (Knight & Hunt 1976). This collagen is stored and secreted by the nidamental gland and passes through an extraordinary series of ordered phases, m any of which…

Proteoglycans and glycosaminoglycans researchCollagen: Extraction and CharacterizationConnective tissue disorders research

A partial discharge monitor for the measurement of partial discharges in a high voltage plant by the transient earth voltage technique

E. Jennings、Amy Collinson1993-09-28OpenAlex

Several proprietary discharge detectors are available that are suitable for measuring the magnitudes of the partial discharges in plants such as high voltage metalclad switchgear. Their main disadvantages are the high capital cost of the test equipment and the complexity of the testing procedure. When performing such…

Magnetic Field Sensors TechniquesHigh voltage insulation and dielectric phenomenaPower Transformer Diagnostics and Insulation

Properties of interacting aspartic acid and lysine residues in the lactose permease of Escherichia coli

Miklós Sahin‐Tóth、H. Ronald Kaback1993-09-28Biochemistry

The side chains of the interacting pair Asp237(helix VII)-Lys358(helix XI) or Asp240(helix VII)-Lys319(helix X) in the lactose permease of Escherichia coli were extended by replacement with Glu and/or Arg or by site-specific derivatization of single-Cys replacement mutants. Iodoacetic acid was used to carboxymethylate…

DNA and Nucleic Acid ChemistryBacterial Genetics and BiotechnologyEnzyme Structure and Function

Developments in partial discharge plant-monitoring technology

I.J. Kemp1993-09-28OpenAlex

Partial discharge activity is both a symptom of degradation in the solid insulating systems of power plants-irrespective of the causative stresses-and a stress mechanism which causes degradation. It can therefore be readily appreciated why the detection, location and interpretation of pd activity is an attractive tech…

High voltage insulation and dielectric phenomena

The experimental conditions for Compton scattering in the electron microscope

Peter Jonas、P. Schattschneider1993-09-27Journal of Physics Condensed Matter

Electron Compton scattering from solids (ECOSS) is a technique for obtaining the momentum density distributions of charge carriers in a solid on a scale of mu m or less. The authors discuss the possibilities and the problems of this experimental technique, which uses a conventional transmission electron microscope (CT…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesAdvanced Chemical Physics Studies

Gamma-rays irradiation: An effective method for improving light emission stability of porous silicon

J. S. Fu、Jingshu Mao、E. Wu 等 9 位作者1993-09-27Applied Physics Letters

We report a study on gamma irradiated porous Si. The electron paramagnetic resonance study on porous Si irradiated by gamma rays shows that the observed signals come from an intrinsic defect, a Si dangling bond, at the interface of Si/SiOx in porous Si. The photoluminescence measurements show that the gamma irradiatio…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Absence of a sharp glass transition in mode coupling theory

Rudi Schmitz、James W. Dufty、Piali De1993-09-27Physical Review Letters

A self-consistent mode coupling model for supercooled fluids is derived from fluctuating nonlinear hydrodynamics (extended to short wavelengths) with attention to detailed balance constraints. The sharp glass transition predicted by mode coupling models based only on pressure nonlinearities does not occur here. Instea…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesTheoretical and Computational Physics

Noncritical behavior of density fluctuations in supercooled water

Yonglin Xie、Karl Ludwig、Guarionex Morales 等 5 位作者1993-09-27Physical Review Letters

We have measured the absolute structure factor of liquid water over the wave-number range 0.05k0.30 A${\mathrm{\r{}}}^{\mathrm{\ensuremath{-}}1}$ and temperature range -34T25 \ifmmode^\circ\else\textdegree\fi{}C with small-angle x-ray scattering. The correlation lengths of density fluctuations are small and change ver…

Spectroscopy and Quantum Chemical StudiesMaterial Dynamics and PropertiesPhase Equilibria and Thermodynamics