Mixed Valency Chemistry: A Survey of 10 Years Progress
(1981). Mixed Valency Chemistry: A Survey of 10 Years Progress. International Reviews in Physical Chemistry: Vol. 1, No. 2, pp. 149-193.
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Structure of Glasses of the TeO2 – MoO3 System
Abstract Structural models for glasses of the TeO 2 –MoO 3 system are suggested. On the basis of X‐ray and infrared spectral investigations, by comparing with known crystalline structures of TeO 2 , MoO 3 and Te 2 MoO 7 (T 2 M), it is shown that the glasses from TeO 2 to Te 2 MoO 7 possess [TeO 4 ] and [MoO 5 ] groups…
Correlation functions of the hard-sphere Lorentz model
Quantitative results for the correlation functions for the Lorentz model of overlapping hard spheres are worked out and discussed within the recently proposed theory of diffusion and localization of a classical particle moving in a random static field. The applicability of the theory to the diffusion phase is establis…
Promoter sequence of fibroin gene assigned by in vitro transcription system.
We have shown that the silk fibroin gene from Bombyx mori is faithfully transcribed in an in vitro transcription system of the HeLa cell extract prepared by the method of Manley et al. [Manley, J. L., Fire, A., Cano, A., Sharp, P. A. & Gefter, M. L. (1980) Proc. Natl. Acad. Sci. USA 77, 3855-3859]. Using this system a…
Multinuclear nuclear magnetic resonance study of three aqueous lanthanide shift reagents: complexes with EDTA and axially symmetric macrocyclic polyamino polyacetate ligands
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMultinuclear nuclear magnetic resonance study of three aqueous lanthanide shift reagents: complexes with EDTA and axially symmetric macrocyclic polyamino polyacetate ligandsCharles C. Bryden, Charles N. Reilley, and Jean F. DesreuxCite this: Anal. Chem. 1981, 53, 9, 1418–142…
Thermal and mechanical properties of linear segmented polyurethanes with butadiene soft segments
Abstract A series of segmented polyurethanes based on a hydroxyl terminated polybutadiene soft segment (HTPBD) have been prepared with varying hard segment content between 20 and 60 weight percent. These materials are linear and amorphous and have no potential for hydrogen bonding between the “hard” and “soft” segment…
Solubility of TiO 2 in BaTiO 3
Scanning electron microscopy and electron probe micro‐analysis were used to investigate the microstructure of both slow‐cooled and quenched polycrystalline BaTiO 3 specimens with a small excess of TiO 2 (Ba/Ti=0.995 to 0.999) or of BaO (Ba/Ti=1.002 and 1.005). The electron micrographs of polished and etched TiO 2 ‐exc…
Liquid crystal polymers. IV. Thermotropic polyesters with flexible spacers in the main chain
Abstract Two closely related series of polyesters that contain mesogenic units interconnected by flexible spacers along the main chain were prepared and characterized for their liquid crystal properties. All of these polymers showed theotropic behavior, which was examined by DSC, hot‐stage microscopy on a polarizing m…
Cu2+ in trigonal‐bipyramidaler Koordination: Die Struktur des CuGaInO4
Abstract Die Kristallstruktur von CuGaInO 4 wurde bestimmt. Die Substanz kristallisiert in der Raumgruppe R 3 m mit den hexagonalen Gitterkonstanten a = 335,4(3) und c = 2481(5) pm (Z = 3). Die Anionen bilden eine 12 L‐Struktur mit der Stapelfolge (31) 3 . Indium liegt zwischen kubisch gestapelten Sauerstoffschichten…
Electrochemical Characteristics of TiS2, ZrSe2 and VSe2 in Secondary Lithium Battery
The layered transition metal dichalcogenides of TiS 2 , ZrSe 2 and VSe 2 were found to react reversibly with lithium in electrochemical cells. The energy densities of these cathode materials were determined to be 500, 240 and 250 W·h/kg for one lithium intercalation per unit cell, respectively and 420 W·h/kg for two l…
Kristall-und Molekülstrukturen von Benzoato-pyridin-iod(I) und Phthalato-bis(pyridin-iod(I))/ Crystal and Molecular Structures of Benzoato-pyridine-iodine(I) and Phthalato-bis(pyridine-iodine(I))
Abstract Benzoato-pyridine-iodine(I) and phthalato-bis(pyridine-iodine(I)) crystallize in the monoclinic spacegroup P2 1 /c. In both cases iodine(I) shows an almost linear coordination towards the pyridine-N and one carboxylate-O donor atom. The I -N distances range from 228 to 232 pm, the I - O distances from 213 to…
The Mechanics of Carpet Wear
An analysis of the various mechanisms involved in carpet wear has provided the general form of a relationship between carpet thickness and the number of treads on the carpet. The possible applications of this approach in wear testing are discussed.
Finite compressibility in shaped charge jet and long rod penetration—the effect of shocks
The classical theory of high speed jet and long rod penetration assumes incompressibility of both projectile and target. We extend here previous analyses of the implications of finite compressibility by including the effect of stationary shocks. For uniform projectile velocities V≲6×103 ms−1, depending on the type of…
The Behavior of Na ‐ TiS2 and Na ‐ TiS3 as Solid Solution Electrodes
We have investigated the behavior of and electrodes in a sodium cell at temperatures between 230° and 280°C using the solid electrolyte β''‐alumina. The electrochemical reaction of with sodium was found to be reversible, while was found to decompose.
Crystal and molecular structure of tetrakis(trifluoroacetato)bis(dimethyl sulfone)dirhodium(II). A compound with axially coordinated sulfone ligands
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal and molecular structure of tetrakis(trifluoroacetato)bis(dimethyl sulfone)dirhodium(II). A compound with axially coordinated sulfone ligandsF. Albert Cotton and Timothy R. FelthouseCite this: Inorg. Chem. 1981, 20, 8, 2703–2708Publication Date (Print):August 1, 1981P…
Raman study of hydrogen bonding in α and β‐oxalic acid dihydrate
Abstract The effects of different hydrogen bonding configurations upon the Raman spectrum of α‐(COOH) 2 ·2H 2 O, α‐(COOD) 2 ·2D 2 O, β‐(COOD) 2 ·2D 2 O and (COOK) 2 ·H 2 O and the temperature stability of β‐ (COOD) 2 ·2D 2 O are reported. The OH stretch frequencies correlate well to the changes in the hydrogen bond l…
A Tree Growth Inhibiting Insulation for Power Cable
This paper describes a power cable insulation with a tree growth inhibiting additive that is nowommer commercially available for use by the electric utilities. The new insulating resin inhibits the growth of both electrical and water trees. A major cause of insulation failure is the progressive ive degradation process…
Intracellular transport and secretion of fibroin in the posterior silk gland of the silkworm Bombyx mori
Intracellular transport and secretion of fibroin in the posterior silk gland cells of the silkworm, Bombyx mori, were investigated in relation to the radial microtubule and circular microtubule-microfilament systems of the cells. The silk glands were pulse-labelled for 3 min with [3H]glycine in vitro and then chased i…
Anomalous small angle scattering
Isomorphous replacement methods have been revolutionary in macromolecular structure research. This has been most clearly demonstrated in protein crystallography. Specific binding of heavy atoms to protein molecules in the crystalline state provides the necessary reference for the phase determination of each Bragg refl…
Structural, EPR and magnetic studies of a nonplanar copper(II) maleonitriledithiolate complex
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructural, EPR and magnetic studies of a nonplanar copper(II) maleonitriledithiolate complexD. Snaathorst, H. M. Doesburg, J. A. A. J. Perenboom, and C. P. KeijzersCite this: Inorg. Chem. 1981, 20, 8, 2526–2532Publication Date (Print):August 1, 1981Publication History Publi…