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Synthesis and hydrogenation application of Pt–Pd bimetallic nanocatalysts stabilized by macrocycle-modified dendrimer

Zhijun Jin、Haiyan Xiao、Wei Zhou 等 5 位作者2017-12-01Royal Society Open Science

Different generations of poly(propylene imine) (G n -PPI) terminated with N-containing 15-membered triolefinic macrocycle (G n M) ( n = 2, 3, 4, 5) were prepared. The bimetallic nanoparticle catalysts G n M-(Pt x /Pd 10− x ) ( x = 0, 3, 5, 7, 10) were prepared by the synchronous ligand-exchange reaction between G n M…

Catalysis and Hydrodesulfurization StudiesDendrimers and Hyperbranched PolymersNanomaterials for catalytic reactions

Compressive response ofPMMAmicrocellular foams at low and high strain rates

Ruizhi Zhang、Lianmeng Zhang、Jian Zhang 等 9 位作者2017-12-01Journal of Applied Polymer Science

ABSTRACT Microcellular foams are widely applied in various applications in both civil and military applications for barriers and energy absorption materials. Poly(methyl methacrylate) microcellular foams were fabricated via supercritical foaming method. Field emission scanning electron microscopy, differential scannin…

Polymer crystallization and propertiesCellular and Composite StructuresPolymer Foaming and Composites

TiO2 Crystal Structure Dependence of Low-temperature CO Oxidation Catalyzed by Au/TiO2

Kohei Tada、Yasushi Maeda、Hiroaki Koga 等 4 位作者2017-12-01Chemistry Letters

The effect of TiO2 crystal structures (rutile, anatase, and brookite) on low-temperature CO oxidation catalyzed by Au/TiO2 was determined. The catalytic activities of Au/TiO2 with different TiO2 crystal structures are identical when the Au loadings and mean diameters are equal. Additionally, the present work confirmed…

Catalytic Processes in Materials ScienceGas Sensing Nanomaterials and SensorsCatalysis and Oxidation Reactions

Influence of grain boundaries on the distribution of components in binary alloys

П. Е. Львов、В. В. Светухин2017-12-01Physics of the Solid State

Based on the free-energy density functional method (the Cahn–Hilliard equation), a phenomenological model that describes the influence of grain boundaries on the distribution of components in binary alloys has been developed. The model is built on the assumption of the difference between the interaction parameters of…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomena

Impact of silver ions and silver nanoparticles on the plant growth and soil microorganisms

Daiane Tomacheski、Michele Pittol、Douglas Naue Simões 等 5 位作者2017-12-01DOAJ (DOAJ: Directory of Open Access Journals)

There is a growing consumer market for products that proclaim to decrease microorganism counts to prevent infections. Most of these products are loaded with silver in its ionic or nanoparticle form. Through use or during production, these particles can find their way into the soil and cause an impact in microbial and…

Nanoparticles: synthesis and applicationsHeavy metals in environmentWastewater Treatment and Reuse

Error correction method based on multiple neural networks for UHF partial discharge localization

Nan Zhou、Lingen Luo、Jingde Chen 等 5 位作者2017-12-01IEEE Transactions on Dielectrics and Electrical Insulation

The time difference method based ultra-high-frequency (UHF) partial discharge (PD) localization has not been extensively applied in substations due to its excessive localization error. A novel and effective PD localization error correction method, consisting of two multiple radial basis function (RBF) networks, RBFtfo…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationMagneto-Optical Properties and Applications

Optical properties of the plasma hydrogenated ZnO thin films

Yu-Ying Chang、Jiří Stuchlík、Neda Neyková 等 5 位作者2017-12-01Journal of Electrical Engineering

Abstract We have optimized the deposition of the highly electrically resistive undoped (intrinsic) polycrystalline ZnO thin layers on fused silica substrates by the DC reactive magnetron sputtering of metallic zinc target in argonne/oxide atmosphere and we introduced the post-deposition hydrogen plasma doping. The thi…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Carbon nanotube: A review on its mechanical properties and application in aerospace industry

A Raunika、S. Aravind Raj、K Jayakrishna 等 4 位作者2017-12-01IOP Conference Series Materials Science and Engineering

Carbon nanotube (CNT) is a prominent material that has good potential to be used in numerous aerospace applications. This paper presents a review about CNT on its various aspects such as fabrication methods, mechanical properties and applications in aerospace. The evolution of CNT is discussed to its recent applicatio…

Carbon Nanotubes in CompositesGraphene research and applicationsPolymer Nanocomposite Synthesis and Irradiation

Facial synthesis of nanostructured ZnCo2O4 on carbon cloth for supercapacitor application

Swati J. Patil、Jungsung Park、Dong‐Weon Lee2017-12-01IOP Conference Series Materials Science and Engineering

In this work, we have synthesized the ZnCo 2 O 4 electrode by a facial one-step hydrothermal method on a carbon cloth for the supercapacitor application. The structural and phase purity of the prepared electrode material was confirmed by X-ray diffraction (XRD) technique. The surface morphology and elemental stoichiom…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAerogels and thermal insulation

Formulation and characterization of in situ generated copper nanoparticles reinforced cellulose composite films for potential antimicrobial applications

P. Sivaranjana、E.R. Nagarajan、N. Rajini 等 5 位作者2017-12-01Journal of Macromolecular Science Part A

Cellulose was dissolved in aq.(LiOH + urea) solution pre-cooled to –12.5°C and the wet films were prepared using ethyl alcohol coagulation bath. The gel cellulose films were dipped in 10 wt.% Cassia alata leaf extract solution and allowed the extract to diffuse into them. The leaf extract infused wet cellulose films w…

Nanoparticles: synthesis and applicationsNanocomposite Films for Food PackagingAdvanced Cellulose Research Studies

Strong up-conversion luminescence of rare-earth doped oxide films enhanced by gap modes on ZnO nanowires

Jinlei Wu、Baosheng Cao、L. Rino 等 8 位作者2017-12-01Nanoscale

films. This UCL enhancement is attributed to the formation of a very strong electric field in the tips of the nw-ZnO creating a highly effective electric field at the composite films, combined with reflection at the silver layer. Furthermore, we use the UCL properties of these novel Ag/nw-ZnO/RE composite films to dem…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsGa2O3 and related materials

Inorganic, Hybridized and Living Macrocellular Foams: “Out of the Box” Heterogeneous Catalysis

Armand Roucher、Martin Depardieu、Deniz Pekin 等 5 位作者2017-12-01The Chemical Record

With this personal account we show how the Integrative Chemistry, when combining the sol-gel process and concentrated emulsions, allows to trigger inorganic, hybrid or living materials when dedicated toward heterogeneous catalysis applications. In here we focus on 3D-macrocellular monolithic foams bearing hierarchical…

Mesoporous Materials and CatalysisSupramolecular Self-Assembly in MaterialsPickering emulsions and particle stabilization

Treatment of the Rust Layer by Different Pyridine Derivatives and Its Effect on the Epoxy-Polyvinylbutyral Coating Directly Painted onto the Rust Mild Steel

Yinze Zuo、Zhaolei Li、Liang Chen 等 5 位作者2017-12-01International Journal of Electrochemical Science

In this work, 2-picolinicacid, 2-hydroxypyridine and 2-aminopyridine were used as rust converters to pre-process a metal surface. The results showed that the rust layers of A3 steel treated by pyridine derivatives are more compact and homogeneous than the untreated rust layer. The corrosion rate of the mild steel trea…

Corrosion Behavior and InhibitionElectrospun Nanofibers in Biomedical ApplicationsAnodic Oxide Films and Nanostructures

Study on charge de-trapping and dipolar relaxation properties of epoxy resin from discharging current measurements

Nasirul Haque、Sovan Dalai、Biswendu Chatterjee 等 4 位作者2017-12-01IEEE Transactions on Dielectrics and Electrical Insulation

The behavior of polar polymeric dielectrics at high electric fields is controlled by several factors. Among them, dipolar polarization and trapping and de-trapping of space charge are very important, as they are related to the microstructural properties of the material. From the point of insulation diagnostics, it wil…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaPower Transformer Diagnostics and Insulation

Adsorption and Inhibition Behavior of Avicennia Marina for Zn Metal in Hydrochloric Acid Solution

A. S. Fouda、S.M. Rashwan、Medhat M. Kamel 等 4 位作者2017-12-01International Journal of Electrochemical Science

The protection of the dissolution of Zn in 1/2 M HCl by aqueous Avicennia marina extract (AME) has been examined utilized hydrogen liberation (HL), weight loss (WL), Tafel polarization (TP), electrochemical frequency modulation (EFM) and AC impedance (EIS) tests. The outcome data of studied extract is excellent except…

Corrosion Behavior and InhibitionMetal Extraction and BioleachingCalcium Carbonate Crystallization and Inhibition

The mechanical and thermal characteristics of phenolic foam reinforced with kaolin powder and glass fiber fabric

Wenya Xiao、Zhixiong Huang、Jie Ding2017-12-01IOP Conference Series Materials Science and Engineering

In this work, kaolin powder and glass fiber fabric were added to PF in order to improve its thermal stability and mechanical property. Micro-structures of carbonized PF with kaolin powder were inspected by scanning electron microscopy (SEM) to demonstrate the filler's pinning effect. SEM results illustrated modified P…

Polymer Nanocomposites and PropertiesFlame retardant materials and propertiesPolymer Foaming and Composites

Contact-induced doping in aluminum-contacted molybdenum disulfide

Yoshihiro Shimazu、Kensuke Arai、Tatsuya Iwabuchi2017-12-01Japanese Journal of Applied Physics

Abstract The interface between two-dimensional semiconductors and metal contacts is an important topic of research of nanoelectronic devices based on two-dimensional semiconducting materials such as molybdenum disulfide (MoS 2 ). We report transport properties of thin MoS 2 flakes in a field-effect transistor geometry…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Experimental and Theoretical Study of Ketoconazole as Corrosion Inhibitor for Bronze in NaCl+Na2SO4 Solution

Daysi Elusaí Millán-Ocampo、J.A. Hernández、J. Porcayo-Calderón 等 8 位作者2017-12-01International Journal of Electrochemical Science

An antifungal, Ketoconazole, 1-[4-[4-[[(2R,4S)-2-(2,4-dichlorophenil)-2-(imidazol-1- ilmetil)-1,3-dioxolan-4-yl]metoxi]phenil]piperazin-1-yl]ethanol, has been evaluated as corrosion inhibitor for bronze in 3.5% M NaCl + 0.1M Na 2 SO 4 solution with electrochemical techniques, including potentiodynamic polarization cur…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Edge-spin-derived magnetism in few-layer MoS2 nanomeshes

G. Kondo、Naoaki Yokoyama、Shôji Yamada 等 7 位作者2017-12-01AIP Advances

Magnetism arising from edge spins is highly interesting, particularly in 2D atomically thin materials in which the influence of edges becomes more significant. Among such materials, molybdenum disulfide (MoS2; one of the transition metal dichalcogenide (TMD) family) is attracting significant attention. The causes for…

Graphene research and applicationsZnO doping and properties2D Materials and Applications

Octahedral Distortions at High‐Temperature Superconducting La2CuO4 Interfaces: Visualizing Jahn–Teller Effects

Y. Eren Suyolcu、Yi Wang、Wilfried Sigle 等 8 位作者2017-12-01Advanced Materials Interfaces

Abstract Tuning the octahedral network represents a promising route for achieving new properties and functionalities in perovskite‐based oxide heterostructures. One of the interface‐mediated phenomena occurring in complex oxides is the Jahn—Teller (JT) effect. With the purpose of investigating octahedral distortions a…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides