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Nanomaterials design for super-degenerate electronic state beyond the limit of geometrical symmetry

Naoki Haruta、Takamasa Tsukamoto、Akiyoshi Kuzume 等 5 位作者2018-09-10Nature Communications

Spherical atoms have the highest geometrical symmetry. Due to this symmetry, atomic orbitals are highly degenerate, leading to closed-shell stability and magnetism. No substances with greater degrees of degeneracy are known, due to geometrical limitations. We now propose that realistic magnesium, zinc, and cadmium clu…

Graphene research and applications2D Materials and ApplicationsNanocluster Synthesis and Applications

Effects of Soot Deposition on NOx Purification Reaction and Mass Transfer in a SCR/DPF Catalyst

Yoshihisa Tsukamoto、Shun Utaki、Wencong Zhang 等 5 位作者2018-09-10SAE technical papers on CD-ROM/SAE technical paper series

<div class="section abstract"><div class="htmlview paragraph">Experimental studies were carried out to investigate the effect of soot deposition on NOx purification phenomena in an ammonia selective catalytic reduction coated diesel particulate filter (SCR/DPF) catalyst. To study soot deposition effects on…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsIndustrial Gas Emission Control

Electrochemical reduction and re‐oxidation behavior of α, β, and γ‐iron oxy‐hydroxide films on electrodes

Kiyonobu Sugae、Takayuki Kamimura、Ryo Asakura 等 6 位作者2018-09-10Materials and Corrosion

To clarify the effect of rust on the corrosion of steel exposed to an atmosphere containing chloride, the electrochemical reduction and re‐oxidation behavior of α, β, and γ‐FeOOH is studied. Films are formed on gold electrodes and are electrochemically reduced at several potentials, thus simulating the corrosion poten…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Removal of silver nanoparticles coated with different stabilizers from aqueous medium by electrocoagulation

Larissa Desordi Bortoli、Soraya Moreno Palácio、Eliane Hermes 等 6 位作者2018-09-10Environmental Technology

This study evaluated the removal of silver nanoparticles (AgNPs), coated with different stabilizers, from aqueous media using the electrocoagulation technique. The AgNPs dispersions were synthesized by chemical reduction with silver nitrate as precursor, sodium borohydride as reducing agent and sodium carboxymethylcel…

Nanoparticles: synthesis and applications

Dielectric breakdown at sub-critical fields

Zhou Zuo、L. A. Dissado、N. M. Chalashkanov 等 5 位作者2018-09-10Applied Physics Letters

We present a quantitative physical model based on experimentally determined parameter values for the description of the way that dielectric breakdown occurs after a period of stressing at fields below the critical values required for deterministic theories. It is found that for most of the material lifetime isolated r…

Semiconductor materials and devicesHigh voltage insulation and dielectric phenomenaPower Transformer Diagnostics and Insulation

Bidirectional tunable ferrite-piezoelectric trilayer magnetoelectric inductors

Jitao Zhang、Dongyu Chen、Д. А. Филиппов 等 9 位作者2018-09-10Applied Physics Letters

A tunable magnetoelectric inductor composed of a symmetrical trilayer of Ga-doped NiZn ferrite and PZT in a solenoid has been developed. Under the influence of external electric/magnetic fields, the permeability variation arising from magnetostriction and piezoelectric strain in the composite results in a bidirectiona…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Weak Field Tuning of Transition-Metal Dopant Hybridization in Solid Hosts

Pragathi Darapaneni、Orhan Kizilkaya、Zhen Wang 等 4 位作者2018-09-10The Journal of Physical Chemistry C

Transition-metal (TM)-doped solids are one of the most extensively studied compounds in the fields of catalysis, magnetism, solar cells, etc., due to their tunable optoelectronic properties that stem from TM energy-level hybridization. In this work, the hybridization of the Ni–O bond in TiO 2:Ni films was controlled i…

Catalytic Processes in Materials ScienceQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Tailoring Highly Flexible Hybrid Supercapacitors Developed by Graphite Nanoplatelets-Based Film: Toward Integrated Wearable Energy Platform Building Blocks

Ziao Wang、Huatao Wang、Hao Zheng 等 15 位作者2018-09-10ACS Applied Energy Materials

We report a new type of highly flexible hybrid supercapacitors (SCs) developed by graphite nanoplatelets (GNPs)-based films with a practicable fabrication method for mass production. In this report, GNP/carbon black films are featured with excellent free-standing and conductivity characteristics, thus capable of worki…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Surface Reconstruction of Germanium: Hydrogen Intercalation and Graphene Protection

Dechun Zhou、Zhiqiang Niu、Tianchao Niu2018-09-10The Journal of Physical Chemistry C

Understanding the interfacial properties of functional nanomaterials on semiconductor surfaces is crucial for developing electronics, optoelectronics, and other devices. By using graphene on the germanium (110) surface as a model, we performed scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (X…

Graphene research and applicationsQuantum and electron transport phenomenaSurface and Thin Film Phenomena

Estimation of projected surface area of irregularly shaped fragments

Elvedin Kljuno、Alan Ćatović2018-09-10Defence Technology

The essence and the main contribution of this paper are consisted of the suggested novel method for estimation of a projected surface area of an irregularly shaped fragment, which represents a significant step toward a new method of an aerodynamic force estimation of a fragment motion through a resistive medium. The s…

High-Velocity Impact and Material BehaviorGuidance and Control SystemsElectromagnetic Launch and Propulsion Technology

A Strain-Deformation Nexus within Pincer Ligands: Application to the Spin States of Iron(II) Complexes

James N. McPherson、Timothy E. Elton、Stephen B. Colbran2018-09-10Inorganic Chemistry

The substitution of a pyrrolide ring for one (or more) pyridyl rings within the ubiquitous terpyridine (tpy, A ) scaffold results in more open geometries of the pyridine–pyrrolide chelate ligands. DFT calculations (B3LYP-GD3BJ/6-31G**) demonstrate that the more open geometries of the unbound ligands are mismatched wit…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Facile One‐Step Synthesis of Black Phosphorus via Microwave Irradiation with Excellent Photocatalytic Activity

Dongyang He、Zhaocheng Zhang、Jiao Qu 等 5 位作者2018-09-10Particle & Particle Systems Characterization

Abstract A rapid one‐step microwave‐assisted liquid‐phase synthesis (MLS) method of black phosphorus (BP) is reported for the first time in this work. Under microwave irradiation, BP is generated within 45 min. The lattice spaces of the as‐prepared BP are determined as 0.338 and 0.158 nm, belonging to the (021) and (2…

Advanced Photocatalysis Techniques2D Materials and ApplicationsMXene and MAX Phase Materials

Magnetic field-induced ferroelectricity in S = 1/2 kagome staircase compound PbCu3TeO7

Kyongjun Yoo、B. Koteswararao、Jeonghun Kang 等 11 位作者2018-09-10npj Quantum Materials

Abstract Ni 3 V 2 O 8 is an archetypical multiferroic material with a kagome staircase structure of S = 1 (Ni 2+ ) spins whose complex interplay between spin ordering and ferroelectricity has been studied for more than a decade. Here, we report a new kagome staircase compound PbCu 3 TeO 7 with Cu 2+ ( S = 1/2) spins t…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Light-Mediated Growth of Noble Metal Nanostructures (Au, Ag, Cu, Pt, Pd, Ru, Ir, Rh) From Micro- and Nanoscale ZnO Tetrapodal Backbones

Trevor B. Demille、Robert A. Hughes、Arin S. Preston 等 6 位作者2018-09-10Frontiers in Chemistry

Micro- and nanoscale ZnO tetrapods provide an attractive support for metallic nanostructures since they can be inexpensively produced using the flame transport method and nanoparticle synthesis schemes can take advantage of a coupled response facilitated by the formation of a semiconductor-metal interface. Here, we pr…

ZnO doping and propertiesCopper-based nanomaterials and applicationsNanomaterials for catalytic reactions

Facile Synthesis of a Terephthalic Acid-Based Organic Fluorophore with Strong and Color-Tunable Emission in Both Solution and Solid States for LED Applications

Yuan Zhan、Lifeng Lin、Min Chen 等 4 位作者2018-09-10ACS Applied Materials & Interfaces

Dual-state emission (DSE) fluorophores with strong photoluminescence in both solution and solid states have wide applications in fluorescent probes and photoelectric devices. However, most of the existing DSE fluorophores involve complex synthetic strategies or only one or two emission colors in the solid state, which…

Advanced biosensing and bioanalysis techniquesOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Hierarchical FeCo2S4 Nanotube Arrays Deposited on 3D Carbon Foam as Binder‐free Electrodes for High‐performance Asymmetric Pseudocapacitors

Yunpeng Huang、Fen Cui、Mingqing Hua 等 8 位作者2018-09-10Chemistry - An Asian Journal

Abstract The ever‐increasing global demand for green energy resources calls for more research attention on the development of cheap and efficient energy storage systems. Herein, we propose the rational design of a 3D carbon foam electrode deposited with perpendicularly oriented FeCo 2 S 4 nanotubes arrays (FeCo 2 S 4…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationAdvanced battery technologies research

Effect of pH on Size and Internal Structure of Poly(propylene imine) Dendrimers: A Molecular Dynamics Simulation Study

Shilpa Gupta、Parbati Biswas2018-09-10The Journal of Physical Chemistry B

The behavior of poly(propylene imine) dendrimers at three different solution pH is investigated through molecular dynamics (MD) simulations in explicit solvent. MD simulations provide an insight into the conformational properties of dendrimers via the evaluation of their size, shape, radial density distribution, stati…

Advanced Polymer Synthesis and CharacterizationRNA Interference and Gene DeliveryDendrimers and Hyperbranched Polymers

Influence of Mixing Intensity on Lysozyme Crystallization in a Meso Oscillatory Flow Reactor

Filipa Castro、António Ferreira、J. A. Teixeira 等 4 位作者2018-09-10Crystal Growth & Design

The influence of mixing intensity on protein crystallization has been investigated for the first time in a meso oscillatory flow reactor (meso-OFR). For this, lysozyme crystallization was studied in batch at different oscillation amplitudes and frequencies. Turbidity was monitored over time to measure induction time a…

Enzyme Structure and FunctionCrystallization and Solubility StudiesFreezing and Crystallization Processes

Effects of Decavanadate Salts with Organic and Inorganic Cations on Escherichia coli, Giardia intestinalis, and Vero Cells

Juliana Morais Missina、Bruno Gavinho、Kahoana Postal 等 10 位作者2018-09-10Inorganic Chemistry

Decavanadate salts with nicotinamide (3-pyridinecarboxamide, 3-pca) and isonicotinamide (4-pyridinecarboxamide, 4-pca) in both neutral and protonated forms, (3-Hpca) 4 [H 2 V 10 O 28 ]·2H 2 O·2(3-pca) (complex I ) and (4-Hpca) 4 [H 2 V 10 O 28 ]·2(4-pca) (complex II ), have been synthesized and characterized by vibrat…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation Chemistry

Comparison Between Chitosan Nanoparticles and Cellulose Nanofibers as Reinforcement Fillers in Papaya Puree Films: Effects on Mechanical, Water Vapor Barrier, and Thermal Properties

Taís Téo de Barros‐Alexandrino、Milena Martelli‐Tosi、O. B. G. Assis2018-09-10Polymer Engineering and Science

Chitosan nanoparticles (Np) were prepared by ionic gelation method, with particle size of 58.54 ± 16.99 nm. Cellulose nanofibers (Nf) were extracted from soybean straws by a combined process of mechanical grinding and enzymatic hydrolysis, with diameters between 40 and 120 nm and variable length. The puree was prepare…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced CompositesAdvanced Cellulose Research Studies