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Mechanistic insights into heterogeneous methane activation

Allegra A. Latimer、Hassan Aljama、Arvin Kakekhani 等 9 位作者2017-01-01Physical Chemistry Chemical Physics

While natural gas is an abundant chemical fuel, its low volumetric energy density has prompted a search for catalysts able to transform methane into more useful chemicals. This search has often been aided through the use of transition state (TS) scaling relationships, which estimate methane activation TS energies as a…

Catalytic Processes in Materials ScienceCO2 Reduction Techniques and CatalystsCatalysis and Oxidation Reactions

Green synthesis of silver nanoparticles using a Melissa officinalis leaf extract with antibacterial properties

Álvaro de Jesús Ruíz-Baltazar、Simón Yobanny Reyes‐López、Daniel Larrañaga Ordaz 等 5 位作者2017-01-01Results in Physics

The exceptional properties of the silver nanoparticles offer several applications in the biomedicine field. The development of antibiotics which are clinically useful against bacteria and drug resistant microorganisms, it is one of the main approaches of silver nanoparticles. However, it is necessary to develop enviro…

Nanoparticles: synthesis and applicationsMedicinal Plants and NeuroprotectionMedicinal Plant Extracts Effects

A highly-distorted octahedron with a C 2v group symmetry inducing an ultra-intense zero phonon line in Mn 4+ -activated oxyfluoride Na 2 WO 2 F 4

Tao Hu、Hang Lin、Yao Cheng 等 8 位作者2017-01-01Journal of Materials Chemistry C

A novel Na <sub>2</sub> WO <sub>2</sub> F <sub>4</sub> :Mn <sup>4+</sup> red-emitting phosphor, exhibiting an ultra-intense zero phonon line at 620 nm, is demonstrated to be promising for LED lightings and displays.

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsInorganic Fluorides and Related Compounds

Recent advances in nanomedicines for the treatment of rheumatoid arthritis

Qin Wang、Xun Sun2017-01-01Biomaterials Science

Rheumatoid arthritis (RA) is a severe systemic inflammatory disease. It is often associated with serious cartilage destruction and massive inflammatory infiltration, which might ultimately cause disability, wide complications and reduced life quality. Current clinical treatments of RA show several drawbacks such as hi…

Nanoparticle-Based Drug DeliveryImmunotherapy and Immune ResponsesMonoclonal and Polyclonal Antibodies Research

Smart candle soot coated membranes for on-demand immiscible oil/water mixture and emulsion switchable separation

Jian Li、Zhihong Zhao、Dianming Li 等 7 位作者2017-01-01Nanoscale

Oil/water separation is of great importance for the treatment of oily wastewater, including immiscible light/heavy oil-water mixtures, oil-in-water or water-in-oil emulsions. Smart surfaces with responsive wettability have received extensive attention especially for controllable oil/water separation. However, traditio…

Catalytic Processes in Materials ScienceSurface Modification and SuperhydrophobicityMembrane Separation and Gas Transport

Characterizations of multilayer ZnO thin films deposited by sol-gel spin coating technique

M.I. Khan、K.A. Bhatti、Rabia Qindeel 等 5 位作者2017-01-01Results in Physics

In this work, zinc oxide (ZnO) multilayer thin films are deposited on glass substrate using sol-gel spin coating technique and the effect of these multilayer films on optical, electrical and structural properties are investigated. It is observed that these multilayer films have great impact on the properties of ZnO. X…

ZnO doping and propertiesCopper-based nanomaterials and applicationsGa2O3 and related materials

Mitochondria-targetable carbon quantum dots for differentiating cancerous cells from normal cells

Ge Gao、Yao‐Wen Jiang、Jingjing Yang 等 4 位作者2017-01-01Nanoscale

In this study, a series of fluorescent carbon quantum dots (or carbon dots, CDs) with inherent mitochondrial targeting/imaging and cancerous/normal cell differentiation capabilities were prepared by a one-pot solvothermal treatment of glycerol and a silane molecule. Glycerol acted as a solvent and carbon source, and t…

Advanced biosensing and bioanalysis techniquesCarbon and Quantum Dots ApplicationsGraphene and Nanomaterials Applications

Suitability of Biodegradable Plastic Mulches for Organic and Sustainable Agricultural Production Systems

Carol Miles、Lisa W. DeVetter、Shuresh Ghimire 等 4 位作者2017-01-01HortScience

Biodegradable plastic mulch has the potential to be a sustainable technology in agricultural production systems if the mulch performs equally to polyethylene (PE) mulch and biodegrades completely into constituents that do not harm the soil ecology or environment. Reduced labor costs for removal and disposal, and reduc…

biodegradable polymer synthesis and propertiesPesticide and Herbicide Environmental StudiesComposting and Vermicomposting Techniques

Biocompatible, degradable thermoplastic polyurethane based on polycaprolactone-block-polytetrahydrofuran-block-polycaprolactone copolymers for soft tissue engineering

Hao‐Yang Mi、Xin Jing、Brett N. Napiwocki 等 6 位作者2017-01-01Journal of Materials Chemistry B

Biodegradable synthetic polymers have been widely used as tissue engineering scaffold materials. Even though they have shown excellent biocompatibility, they have failed to resemble the low stiffness and high elasticity of soft tissues because of the presence of massive rigid ester bonds. Herein, we synthesized a new…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsPolymer composites and self-healing

An acidic pH independent piperazine–TPE AIEgen as a unique bioprobe for lysosome tracing

Yuanjing Cai、Gui Chen、Kerim Samedov 等 13 位作者2017-01-01Chemical Science

Lysosomes are involved in a multitude of cellular processes and their dysfunction is associated with various diseases. They are the most acidic organelles (pH 3.8-6.6, size 0.1-1.2 μm) with the highest viscosity (47-190 cP at 25 °C) in the cell. Because of their acidity, pH dependent non-AIE active fluorescent lysosom…

DNA and Nucleic Acid ChemistryLuminescence and Fluorescent MaterialsCalcium signaling and nucleotide metabolism

Halloysite nanotubes as support for metal-based catalysts

Marina Massaro、Carmelo Giuseppe Colletti、Giuseppe Lazzara 等 6 位作者2017-01-01Journal of Materials Chemistry A

Halloysite nanotubes (HNTs) are clay minerals with a hollow nanotubular structure. Due to their peculiar chemical characteristics, HNTs constitute valuable supports for metal nanoparticles, promoting catalytic applications with tunable properties.

Clay minerals and soil interactionsIron oxide chemistry and applicationsLayered Double Hydroxides Synthesis and Applications

Thermal decomposition and recovery properties of ZnAl–CO 3 layered double hydroxide for anionic dye adsorption: insight into the aggregative nucleation and growth mechanism of the LDH memory effect.

Rodrigo Morais Menezes dos Santos、Jairo Tronto、Valérie Briois 等 4 位作者2017-01-01Journal of Materials Chemistry A

The LDH memory effect is driven by an aggregative nucleation and growth mechanism limited by the adsorption of the anionic dye in on the external surface.

Polyoxometalates: Synthesis and ApplicationsLayered Double Hydroxides Synthesis and ApplicationsMagnesium Oxide Properties and Applications

Nickel–iron alloy catalysts for reforming of hydrocarbons: preparation, structure, and catalytic properties

Keiichi Tomishige、Dalin Li、Masazumi Tamura 等 4 位作者2017-01-01Catalysis Science & Technology

Among various methods for preparation of supported Ni–Fe alloy catalysts, reduction of oxides containing both Ni <sup>2+</sup> and Fe <sup>3+</sup> can give uniform alloy particles with high catalytic performance for reforming of hydrocarbons.

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

High-detectivity ultraviolet photodetectors based on laterally mesoporous GaN

Lei Liu、Chao Yang、A. Patanè 等 9 位作者2017-01-01Nanoscale

Photodetectors for the ultraviolet (UV) range of the electromagnetic spectrum are in great demand for several technologies, but require the development of novel device structures and materials. Here we report on the high detectivity of UV photodetectors based on well-ordered laterally mesoporous GaN. The specific dete…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

Thickness-dependent Schottky barrier height of MoS 2 field-effect transistors

Junyoung Kwon、Jong‐Young Lee、Young‐Jun Yu 等 7 位作者2017-01-01Nanoscale

2D semiconductors, including transition metal dichalcogenides (TMDs), have been widely studied recently. However, the device performance is deteriorated due to the significant contact resistance. The contact resistance of MoS2-metal contacts decreases with the thickness of MoS2. We obtained a Schottky barrier height a…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

High thermoelectric performances of monolayer SnSe allotropes

Ziyu Hu、Kaiyue Li、Yong Lu 等 5 位作者2017-01-01Nanoscale

orbitals. The thermoelectric transport properties and coefficients are obtained from the electronic structure using semi-classical Boltzmann theory, and the results indicate that the four new phases of SnSe (β, γ, δ and ε) all have better thermoelectric properties compared with the reported α phase. The predicted ZT v…

2D Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin Films