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Migration of Small Pores in Potassium Chloride Due to a Temperature Gradient

P. J. Lemaire、H. Kent Bowen1982-01-01Journal of the American Ceramic Society

Pore migration in KCl crystals subjected to a temperature gradient occurs by a vaporization‐condensation mechanism. The behavior of small (<100 μm) pores was observed using hot‐stage microscopy. A size‐dependent probability of pore motion was noted in which the fraction of mobile pores in a given size range steadily i…

Crystallography and molecular interactionsCrystallization and Solubility Studiesnanoparticles nucleation surface interactions

Microstructure and Mechanical Properties of Nonequilibrium Austenite in Fe-C-(Mo, W) Systems Rapidly Quenched from Melts

Tetsuroh Minemura、Akihisa Inoue、Yoshitaka Kojima 等 4 位作者1982-01-01Transactions of the Iron and Steel Institute of Japan

By melt-quenching technique, nonequilibrium austenitic alloys possessing high strength and hardness combined with good ductility have been found in Fe-C-Mo and Fe-C-W ternary systems. This formation region is limited to about 1.0 to 2.4wt% C and 3 to 22wt% Mo for Fe-C-Mo system and 1.0 to 2.4wt% C and 3 to 24wt% W for…

Advanced materials and compositesMetal Alloys Wear and PropertiesMetallurgical and Alloy Processes

High-Strength, Creep-Resistant Excel Pressure Tubes

B.A. Cheadle、RA Holt、V. Fidleris 等 5 位作者1982-01-01OpenAlex

Pressure tubes for CANada Deuterium Uranium Pressurized Heavy Water reactors are made from Zr-2.5Nb by extruding preheated hollow billets into tubes that are cold-worked 30 percent to size. The fabrication process produces fine elongated α-grains with a high dislocation density which makes a large contribution to the…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Materials and Properties

Preliminary results on dosimetric properties op MgB4O7:Dy

V. Barbina、Giorgio Contento、C. Furetta 等 5 位作者1982-01-01Radiation Effects

The thermoluminescent properties of magnesium borate, a new tissue equivalent material, have been stu died.

Luminescence Properties of Advanced MaterialsLanthanide and Transition Metal Complexes

Statics and dynamics near the nematic-columnar phase transition in liquid crystals

J. B. Swift、Barbara S. Andereck1982-01-01Journal de Physique Lettres

A Landau-Ginzburg Hamiltonian describing a liquid crystal in the nematic phase near the nematic-columnar phase transition is used to find the renormalized nematic elastic constants and viscosities. The elastic constants, with the exception of the bend elastic constant, are found to be enhanced by order parameter fluct…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesNonlinear Dynamics and Pattern Formation

Intermediates in thermal decomposition of nickel(II) complexes: The crystal structures of Ni(SCN)2(NH3)2and Ni(SCN)2

E. Dubler、Armin Reller、H. R. Oswald1982-01-01Zeitschrift für Kristallographie

Ni(SCN) 2 (NH 3 ) 2 and Ni(SCN) 2 are stable intermediates in the course of the thermal decomposition reaction Ni(SCN) 2 (NH 3 ) 4 → NiS 2 . Ni(SCN) 2 (NH 3 ) 2 crystallizes in the monoclinic space group C 2/ m with a = 8.698(5), b = 7.991(4), c = 5.619(3) Å, β = 105.91(9)°, Z = 2, D x = 1.85g cm −3 . The crystal data…

Corrosion Behavior and InhibitionOrganic and Molecular Conductors ResearchCO2 Reduction Techniques and Catalysts

Texture Control of Zircaloy Tubing During Tube Reduction

Nobuyuki Nagai、Tsutomu Kakuma、Katsuhide Fujita1982-01-01OpenAlex

Seven batches of Zircaloy-2 tubing with widely different textures were processed from tube shells of the same size, by different reduction routes using pilger and 3-roll mills. Based on the texture data of these tubes, the texture control of Zircaloy tubing, the texture gradient across the wall, and the texture change…

Metallurgy and Material FormingNuclear Materials and PropertiesTitanium Alloys Microstructure and Properties

Development and Application of the Rolling Contact Fatigue Test Rig

EN Bamberger、JC Clark1982-01-01OpenAlex

The rolling contact (RC) fatigue test rig was developed specifically for rapid and inexpensive evaluation of materials and processes for rolling element bearing applications. The simple geometry of the test specimen, a cylindrical bar, makes it ideal for evaluating new materials where only limited quantities of the ma…

Gear and Bearing Dynamics AnalysisMechanical stress and fatigue analysisMetal Alloys Wear and Properties

Unusual Michael reaction of acyclic 1,3-dicarbonyl compounds with nitre-olefins. A novel pyrrole synthesis

Antonio Gómez-Sánchez、Berta Marco Stiefel、Rosario Fernández 等 5 位作者1982-01-01Journal of the Chemical Society Perkin Transactions 1

Acetoacetic esters and pentane-2,4-dione undergo unusual Michael reactions with β-nitrostyrene in methanolsodium methoxide to formthe (2R,3R,2′S,3′S)-bis-(4-acy1-2,3-dihydro-5-methyl-3-phenyl-2)-furylhydroxylamines (5) in high yields. The normal adducts (6) are intermediates in these reactions. Acetylation of compound…

Porphyrin and Phthalocyanine ChemistryChemical Reaction MechanismsSynthesis and Characterization of Pyrroles

Influence of Temperature on Corrosion Product Film Formation on CuNi10Fe in the Low Temperature Range: I. Corrosion rate as a function of temperature in well aerated sea water

F. P. Ijsseling、L. J. P. Drolenga、B. H. Kolstert1982-01-01British Corrosion Journal

It was found that the corrosion rate of CuNi10Fel·4 in aerated sea water at 40 and 50°c was lower than that at the lower sea water temperatures of 10–30°c. This was mainly due to the quick formation of a protective layer of corrosion products at the higher temperatures. Moreover, the protectiveness of these layers app…

Corrosion Behavior and InhibitionHigh-Temperature Coating BehaviorsAnodic Oxide Films and Nanostructures

Partial Discharge Testing under Direct Voltage Conditions

R. S. Bever、J. L. Westrom1982-01-01IEEE Transactions on Aerospace and Electronic Systems

DC partial discharge (PD) (corona) testing is performed using a multichannel analyzer for pulse storing, and data is collected during increase of voltage and at quiescent voltage levels. Thus high voltage ceramic disk capacitors were evaluated by obtaining PD data interspersed during an accelarated life test. Increase…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectrostatic Discharge in Electronics

Corrosion Characteristics of High Purity Iron

Katsuhisa Sugimoto、Shiro Matsuda、Minoru Isshiki 等 5 位作者1982-01-01Journal of the Japan Institute of Metals and Materials

The corrosion resistance of iron in acid and neutral chloride solutions has been investigated as a function of the purity of iron. Five kinds of iron having residual resistivity ratios, RRRH,4.2K, of 80, 150, 800, 1500 and 6000 were used as specimens. The former three with RRRH,4.2K 80, 150 and 800 were commercially a…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Origin of the coloration of yellow fluorites: The O3− center structure and dynamical aspects

H. Bill1982-01-01The Journal of Chemical Physics

This paper demonstrates that the color of natural yellow fluorites is due to an O−3 molecule ion incorporated into the lattice. The center has several equilibrium positions. A detailed EPR and ENDOR study of this center is presented and the motional effects observed in the EPR spectrum are analyzed.

Crystal Structures and PropertiesSolid-state spectroscopy and crystallography

Suzukiite, Ba2V24+(O2|Si4O12), a new mineral from the Mogurazawa mine, Gumma Prefecture, Japan.

Satοshi Matsubara、Akira Kato、Shunzo Yui1982-01-01Mineralogical Journal

Suzukiite, Ba2V4+2[O2|Si4O12], orthorhombic, Amam or Amam2, a=7.089(2), b=15.261(2), c=5.364(1)Å, Z=2, is a new mineral corresponding to the barium analogue of haradaite, Sr2V4+2[O2|Si4O12].The electron microprobe analysis gave : BaO 38.38, SrO 3.21, VO2 23.56, TiO2 0.20, SiO2 33.59, total 98.94%, yielding the empiric…

Geological and Geochemical AnalysisCrystal Structures and PropertiesGeochemistry and Geologic Mapping

The physics and display applications of liquid crystals

I.A. Shanks1982-01-01Contemporary Physics

After a short introduction, the general characteristics of liquid crystals are reviewed, the three main classes of thermotropic liquid crystals are described and the concept of order parameters introduced. The phase behaviour of thermotropic liquid crystals is considered in some detail and the continuum theory, descri…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPlant Reproductive Biology

Grain Boundary Sliding with and without Matrix Slip Deformation in Cadmium Bicrystals

Hiroshi Fukutomi、Hideo Takatori、Ryo Horiuchi1982-01-01Transactions of the Japan Institute of Metals

Differences between grain boundary sliding with crystal slip and that without it are investigated by the use of orientation controlled cadmium bicrystals.Without crystal slip, the rate of grain boundary sliding varied in proportion to applied stress and was controlled by grain boundary diffusion. With crystal slip, th…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Embrittlement of zircaloy-4 due to oxidation in environment of stagnant steam.

Hiroshi Uetsuka、Teruo FURUTA、Satoru Kawasaki1982-01-01Journal of Nuclear Science and Technology

With a view to examining the embrittlement behavior of Zircaloy due to inner surface oxidation occurring in an LWR loss-of-coolant accident, ring-like Zircaloy-4 cladding specimens were heated at the isothermal oxidation temperature ranging 890~1,194°C in an environment of stagnant steam, which simulated the atmospher…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear Engineering Thermal-Hydraulics

The influence of homeotropic and planar boundary conditions on the field induced cholesteric-nematic transition

W. J. A. Goossens1982-01-01Journal de physique

The field induced cholesteric-nematic transition is discussed for the case where the helical axis is parallel to the plane of the sample. Approximate solutions for the critical field are presented for both homeotropic and planar boundary conditions.

Liquid Crystal Research AdvancementsForce Microscopy Techniques and ApplicationsOptical Polarization and Ellipsometry

Effect of a Magnetic Field on the Rate of Diffusion-Controlled Corrosion of Metals

M. E. Ghabashy、G.H. Sedahmed、I.A.S. Mansour1982-01-01British Corrosion Journal

Experiments with copper in acidified dichromate solutions have shown that a magnetic field can enhance the rate of diffusion-controlled corrosion. Care should be taken in chemical and electrochemical industries to keep hardware susceptible to corrosion away from the domain of magnetic fields.

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsMetallurgical Processes and Thermodynamics

Studies on the constituents of asclepiadaceae plants. LI. Oxidation at the 18-methyl group of C/D-cis-pregnane type steroids and 13C-nuclear magnetic resonance spectra of 18-oxygenated pregnanes and related compounds.

MASAHIKO KIMURA、Kôji Hayashi、Hiroshi Narita 等 4 位作者1982-01-01Chemical and Pharmaceutical Bulletin

Four 18-oxygenated pregnane-type steroids ; 18, 20-epoxypregn-5-en-3β-ol acetate (III), 18, 20-epoxy-isolineolon cyclic sulfite (VIII), 18, 20-epoxy-deacyl condurangogenin C (XVIII), and 18, 20-epoxy-20-epideacyl condurangogenin C (XXI) were synthesized, and their structures were established by chemical and spectral s…

Natural product bioactivities and synthesisPhytochemistry and Biological ActivitiesPhytochemistry and Bioactive Compounds