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Refinement of the Structure of Mg3(VO4)2

N. Krishnamachari、C. Calvo1971-05-15Canadian Journal of Chemistry

Magnesium orthovanadate crystallizes in the orthorhombic space group Cmca with a = 6.053(3), b = 11.442(6), c = 8.330(3) Å, and Z = 4. The structure was refined by full matrix least square methods to a final R value of 0.047 using 1697 reflections measured by a quarter circle General Electric automatic diffractometer.…

Crystal Structures and PropertiesPolyoxometalates: Synthesis and ApplicationsCatalysis and Oxidation Reactions

Observability of Charge-Density Waves by Neutron Diffraction

A. W. Overhauser1971-05-15Physical review. B, Solid state

It is shown that atomic displacements $\stackrel{\ensuremath{\rightarrow}}{\mathrm{A}}sin\stackrel{\ensuremath{\rightarrow}}{\mathrm{Q}}\ifmmode\cdot\else\textperiodcentered\fi{}\stackrel{\ensuremath{\rightarrow}}{\mathrm{L}}$ associated with a charge-density wave (CDW) modulation of a metal crystal cause several chan…

High-pressure geophysics and materialsAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Lattice Dynamics of Rutile

J. G. Traylor、H. G. Smith、R. M. Nicklow 等 4 位作者1971-05-15OpenAlex

The phonon dispersion relation for rutile (Ti${\mathrm{O}}_{2}$) has been measured by the coherent inelastic scattering of thermal neutrons along principal symmetry directions of the Brillouin zone. Theoretical models based on rigid-ion and shell models, with either axially symmetric or tensor first- and second-neighb…

High-pressure geophysics and materialsGlass properties and applicationsSolid-state spectroscopy and crystallography

Quadratic Elongation: A Quantitative Measure of Distortion in Coordination Polyhedra

Keith Robinson、G. V. Gibbs、P. H. Ribbe1971-05-07OpenAlex

Quadratic elongation and the variance of bond angles are linearly correlated for distorted octahedral and tetrachedral corrdination complexes, both of which show variations in bond length and bond angle. The quadratic elongation is dimensionless, giving a quantitative measure of polyhedral disortion which is independe…

Crystal Structures and PropertiesX-ray Diffraction in CrystallographyCrystallography and Radiation Phenomena

Dielectric Properties of SrTiO3at Low Temperatures

T. Sakudo、H. Unoki1971-05-03Physical Review Letters

Report No. HE-70-4, 1970 (unpublished}.In Fig. 1 the data from the latter reference are used.They are not corrected for secondary productions, which are accounted for in the former reference, but unfortunately in a model- dependent calculation.The general energy dependences of o"and (n) are not affected.4A comparison…

Ferroelectric and Piezoelectric MaterialsInorganic Chemistry and MaterialsElectronic and Structural Properties of Oxides

In-Pile Fission Gas Release from UC at Temperature around 2,000°C

Hirotaka Furuya、Junji Komatsu、Tadashi Muto 等 5 位作者1971-05-01Journal of Nuclear Science and Technology

In-pile fission gas release from nearly stoichiometric sintered uranium monocarbide was measured in the temperature range from 1,650° to 2,030°C. The result was analyzed on the basis of the diffusion model, from which the diffusion coefficient of krypton in uranium monocarbide was derived as D=1.6×10−7 exp(–56,400/RT)…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Materials and Properties

Effect of uniaxial compression on the thermomagnetic effects in bismuth

Michael Ertl、Ijaz ur Rahman1971-05-01physica status solidi (b)

Abstract Thermomagnetic transport parameters have been measured in bismuth at 80 °K and found to be strongly pressure‐dependent. Results indicate that in addition to a decrease in the energy overlap, E 0 , there is an increased participation of a light hole band increasing the mobility of holes. The Nernst effect and…

High-pressure geophysics and materialsMagnetic and transport properties of perovskites and related materialsRare-earth and actinide compounds

Bambu como matéria-prima para papel: III - Estudos sôbre o emprego de quatro espécies de Bambusa,na produção de celulose sulfato

Dirceu Ciaramello、Anísio Azzini1971-05-01Bragantia

Dando seqüência ao estudo do bambu como matéria-prima para as indústrias de celulose e papel, foram determinadas as características tecnológicas de quatro espécies tropicais exóticas, com bom desenvolvimento nas condições ecológicas do Estado de São Paulo. Em cozimentos efetuados pelo processo sulfato constataram-se d…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research Studies

Correlation of second virial coefficients through potential function parameters

Robert G. Kunz、Robert S. Kapner1971-05-01AIChE Journal

Abstract An analytical technique based on the method of least squares has been developed to fit experimental second virial coefficients to the functional form derived from the Lennard‐Jones (6–12) potential. Both the functional form and the normal equations of the least squares fit are rigorously derived. Because of t…

Phase Equilibria and ThermodynamicsThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Phase Equilibria in the System NaAlSi3O8 – NaAlSiO4 – H2O Up to 15 Kb. A Theoretical Discussion

Ki‐Tae Kim、B. J. Burley1971-05-01Canadian Journal of Earth Sciences

Phase relations in the system NaAlSi 3 O 8 – NaAlSiO 4 – H 2 O up to ~15 Kb have been discussed from a theoretical standpoint. The discussion is based on the equilibrium compositions of invariant phases. Two new invariant points, I 5 and I 6 , have been predicted: I 5 at ~13 Kb/~500 °C where five phases, jadeite, neph…

Zeolite Catalysis and SynthesisGlass properties and applicationsChemical Synthesis and Characterization

Chemical Heterogeneity of Anhydrogalactose-containing Polysaccharides from Gloiopeltis furcata

Kunihiko Izumi1971-05-01Agricultural and Biological Chemistry

Five anhydrogalactose-containing polysaccharides have been extracted in high yields with hot water and dilute alkali from Gloiopeltis furcata and purified by precipitation with cetylpyridinium chloride and by some chromatographic techniques. The analytical results showed that they all contained galactose, 3, 6-anhydro…

Diatoms and Algae Research

Studies on the Uranium Dicarbide Phase

Hiroaki Tagawa、Kimio Fujii、Yasuichi Sasaki1971-05-01Journal of Nuclear Science and Technology

The lattice parameters of UC2 are examined as a function of carbon content and annealing: conditions on sintered carbides between UC1·5 and UC2·2 (7.0 to 10.0W/0 of carbon). The values of UC2 obtained under equilibrium state are around a 0=3.5253 Å and c 0=5.9994Å. The lattice parameter measurements were made also on…

Rare-earth and actinide compoundsNuclear Materials and PropertiesBoron and Carbon Nanomaterials Research

The Effects of High-Voltage DC Power Transmission Systems on Buried Metallic Pipelines

Adrian L. Verhiel1971-05-01IEEE Transactions on Industry and General Applications

The types of high-voltage direct-current (HVDC) system configuration and the detrmental effects that this type of transmission can have on its surroundings are summarized. Discussed in detail are the test procedures followed and camred out to determine some of the effects on a major pipeline by simulated conditions, f…

High voltage insulation and dielectric phenomenaElectrical Fault Detection and ProtectionThermal Analysis in Power Transmission

Selected Optical Properties of Mixtures of Cholesteric Liquid Crystals

Lawrence E. Melamed、David A. Rubin1971-05-01Applied Optics

The reflection, transmission, optical activity, and extinction ratio of a series of mixtures of cholesteryl oleyl carbonate, cholesteryl nonanoate, and cholesteryl chloride of different proportions were measured. The wavelength of minimum transmission (lambda(o)), maximum rate of change of optical activity, and minimu…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsMolecular spectroscopy and chirality

Preparation of a new ternary lithium silicon nitride, LiSi2N3, and the high-pressure synthesis of magnesium silicon nitride, MgSiN2

E. Dow Whitney、R. F. Giese1971-05-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreparation of a new ternary lithium silicon nitride, LiSi2N3, and the high-pressure synthesis of magnesium silicon nitride, MgSiN2E. Dow Whitney and Rossman F. Giese Jr.Cite this: Inorg. Chem. 1971, 10, 5, 1090–1092Publication Date (Print):May 1, 1971Publication History Pub…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsBoron and Carbon Nanomaterials Research

Magneto-seebeck effect in graphite: Giant thermoelectric power due to phonon drag

T. Takezawa、Takurō Tsuzuku、Akio Ono 等 4 位作者1971-05-01Philosophical magazine

The in-plane thermoelectric power () of single-crystal graphite in the presence of a magnetic field applied parallel to the c direction was measured at temperatures (T) from 4.2°K up to 300°K. With an increase of the field intensity (H), the sharp negative dip of the  versus T diagram previously found to be (0) = −…

Graphene research and applicationsThermal properties of materialsGraphite, nuclear technology, radiation studies

The impulse electric strength of polythene as a function of voltage rise time

David B. Watson1971-05-01Journal of Physics D Applied Physics

The electric strength of polythene has been measured using impulse voltages of differing rise times. The mean value of electric strength increases from 5·6 MV cm −1 for a voltage rise time of 60 μs to 6·6 mV cm −1 when the voltage rise time is 80 μs. The dc strength is 6·4 mV cm −1 . The change in electric strength co…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaPower Transformer Diagnostics and Insulation

Effects of Icing on DC Insulation Strength

Harold Hill、P.E. Renner、O. Ratz1971-05-01IEEE Transactions on Power Apparatus and Systems

Laboratory tests were conducted to determine the degradation of dc line and station insulation strength by icing. Curves are presented which relate flashover levels to the degree of icing and the resistivity of the ice, and comparisons are made between the ice test results and fog chamber and wet test data.

High voltage insulation and dielectric phenomenaIcing and De-icing TechnologiesThermal Analysis in Power Transmission

Über Erdalkalimetall‐Oxogallate. I. Zur Kenntnis von CaGa4O7

H. J. Deiseroth、Hk. Müller‐Buschbaum1971-05-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Die Verbindung CaGa 4 O 7 wurde dargestellt und ihre Struktur mit Hilfe von Einkristallen röntgenographisch bestimmt. CaGa 4 O 7 kristallisiert monoklin in der Raumgruppe C C2/c mit den Gitterkonstanten a = 13,06 5 , b = 9,07 9 , c = 5,60 0 Å; β = 105,15°. Ungewöhnlich ist die Sauerstoffkoordination des Calc…

Luminescence Properties of Advanced MaterialsMicrowave Dielectric Ceramics SynthesisGa2O3 and related materials

Degradation of polymers and morphology: Photo‐oxidative degradation of isotactic polystyrene in presence of sulfur dioxide as function of polymer crystallinity

Pavol Hrdlovič、J. Pavlineč、H. H. G. Jellinek1971-05-01Journal of Polymer Science Part A-1 Polymer Chemistry

Abstract The photo‐oxidative chain scission of isotactic polystyrene films has been studied as a function of the degree of crystallinity, SO 2 , and NO 2 pressures, and temperature. The rate of chain scission increases in the presence of SO 2 with extent of crystallinity. It is assumed to be faster due to strain in an…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer composites and self-healing