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The environmental issue. A challenge for new generation polyolefins

Ugo Romano、F. Garbassi2000-01-01Pure and Applied Chemistry

Abstract The recent developments in the field of polyolefin technologies is reviewed in the light of the positive impact that they will have on several aspects of environmental issues.

Environmental Impact and SustainabilityPolymer Science and PVCChemistry and Chemical Engineering

Effect of atmospheric oxidation on the electronic and photoluminescence properties of silicon nanocrystal

I. N. Germanenko、M. Dongol、Yezdi B. Pithawalla 等 5 位作者2000-01-01Pure and Applied Chemistry

Abstract Web-like aggregates of coalesced Si nanocrystals produced by a laser vaporization-controlled condensation technique show luminescence properties that are similar to those of porous Si. The results are consistent with a quantum confinement mechanism as the source of the red photoluminescence (PL) in this syste…

Silicon Nanostructures and PhotoluminescenceCarbon and Quantum Dots ApplicationsIon-surface interactions and analysis

Characteristics of Pharmaceutical Grade Phyllosilicate Powders

César Viseras、César Iborra Viseras、Alberto López-Galindo2000-01-01Pharmaceutical Development and Technology

The purpose of this paper was to evaluate the possible use of three types of pharmaceutical grades of phyllosilicates as pharmaceutical excipients. Seven samples (two smectites, three palygorskites, and two sepiolites) were studied. A complete mineralogical and chemical characterization of each material was made and p…

Clay minerals and soil interactionsTherapeutic Uses of Natural Elements

Synthesis and structural characterisation of CsCoPO4-ABW

Paul F. Henry、Eric M. Hughes、Mark T. Weller2000-01-01Journal of the Chemical Society Dalton Transactions

The cobalt phosphate, CsCoPO4, possessing the zeolite ABW framework topology has been synthesised using a solid state route. Rietveld refinement from powder neutron diffraction data has shown the material to be a direct structural analogue of CsZnPO4 polymorph III. The framework is made up of alternating cobaltate and…

Zeolite Catalysis and SynthesisCrystal Structures and PropertiesChemical Synthesis and Characterization

Synthesis and structure of zinc oxide clusters encapsulated in zeolite LTA

Jennifer E. Readman、I. Gameson、Joseph A. Hriljac 等 5 位作者2000-01-01Chemical Communications

We report the synthesis and structure, obtained through Rietveld analysis of powder synchrotron X-ray diffraction data, of zinc oxide clusters encapsulated in zeolite LTA.

ZnO doping and propertiesZeolite Catalysis and SynthesisTransition Metal Oxide Nanomaterials

Microstructural Characterization of GPSed-RBSN and GPSed-Si<SUB>3</SUB>N<SUB>4</SUB> Ceramics

Byong‐Taek Lee、Jungho Yoo、Hai-Doo Kim2000-01-01Materials Transactions JIM

Microstructural characterization of gas-pressure-sintered reaction-bonded Si3N4 (GPSed RBSN) and gas pressure-sintered Si3N4 (GPSed Si3N4) ceramics at 2223 K for 12.6 ks has been investigated using by back-scattered SEM, TEM and XRD. No residual Si phase was observed in reaction bonded body nitrided at 1673 K for 72 k…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsAdvanced materials and composites

Thermal decomposition kinetics of thermotropic poly(oxybenzoate-co-trimethylene terephthalate)

Xuesong Wang、Xin‐Gui Li、Deyue Yan2000-01-01Journal of Applied Polymer Science

A new kind of thermotropic liquid crystalline, poly(oxybenzoate-co-trimethylene terephthalate), was prepared from p-hydroxybenzoic acid (B) and poly(trimethylene terephthalate) (PTT or T) by melting polycondensation. The monomer ratio of B to T is 60:40. The dynamic thermogravimetric kinetics of the copolymer B/T (60:…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesSynthesis and properties of polymers

Quantitative analysis of indium and iron at the surface of a commercial Al-Zn-In sacrificial anode

J. C. Norris、J.D. Scantlebury、Morgan R. Alexander 等 5 位作者2000-01-01Surface and Interface Analysis

X-ray photoelectron spectroscopy (XPS) was employed to analyse the surface of commercial Al–Zn–In sacrificial anodes in order to quantify the y the concentrations of indium and iron. Analysis was carried out on the as-cast and cut surfaces prior to corrosion testing, followed by short-term 5 h corrosion tests in a 3.5…

Advancements in Battery MaterialsExtraction and Separation ProcessesElectron and X-Ray Spectroscopy Techniques

Study of multiple melting behaviour of syndiotactic polystyrene in ?-crystalline form

Zhenhua Yuan、Rui Song、Deyan Shen2000-01-01Polymer International

A series of syndiotactic polystyrene (SPS) samples in β-crystalline form were prepared by cooling from the melt at various rates. The effects of cooling rate from the melt, DSC heating rate and annealing on the multiple melting behaviours of β crystals were investigated by differential scanning calorimetry (DSC) and t…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Synthesis and properties of novel polyimide/nylon-6 triblock copolymers

Youlee Pae、Frank W. Harris2000-01-01Journal of Polymer Science Part A Polymer Chemistry

Nylon-6-b-polyimide-b-nylon-6 copolymers were prepared by first synthesizing a series of imide oligomers end-capped with phenyl 4-aminobenzoate. The oligomers were then used to activate the anionic polymerization of molten ϵ-caprolactam. In the block copolymer syntheses, the phenyl ester groups reacted quickly with ca…

Polymer Nanocomposites and PropertiesEpoxy Resin Curing ProcessesSynthesis and properties of polymers

The physicomechanical properties and structure of superelastic porous titanium nickelide-based alloys

V. É. Gyunter、Yu. F. Yasenchuk、А. А. Клопотов 等 4 位作者2000-01-01Technical Physics Letters

The results are given investigations of the structural and physicomechanical properties in porous titanium nickelide, and these results are compared with analogous properties in cast alloys.

Titanium Alloys Microstructure and PropertiesMaterial Properties and ApplicationsPolymer Science and Applications

Thermodynamic properties at the phase transition of Pb(Zr, Sn, Ti)O3solid solutions

A. Fuith、H. Kabelka、E. Birks 等 5 位作者2000-01-01Ferroelectrics

Field induced deformation and electrocaloric effect are investigated in the vicinity of phase transition at 163°C. The sharp increase of electrostriction below Tc is explained by the field induced ferroelectric to antiferroelectric phase transition. The antiferroelectric phase appears and remains stable below Tc in th…

Ferroelectric and Piezoelectric MaterialsUltrasonics and Acoustic Wave PropagationOptical and Acousto-Optic Technologies

Birefringence investigations of the Sn2P2(SexS1−x)6uniaxial ferroelectrics behaviour near the lifshitz point

Yu. M. Vysochanskiǐ、V. V. Mitrovcij、A. A. Grabar 等 6 位作者2000-01-01Ferroelectrics

The temperature dependencies of optical birefringence for nominally pure crystals Sn2P2S6 and these crystals with the impurities of lead or selenium atoms, and solid solutions of Sn2P2(SexS1−x)6 have been investigated. The changes of the anomalies in the vicinity of the second order ferroelectric phase transition with…

Nonlinear Optical Materials ResearchSolid-state spectroscopy and crystallographyOptical and Acousto-Optic Technologies

Vibrational study of structural phase transitions in (NH4)2HPO4 and (ND4)2DPO4

A. Hadrich、A. Lauti�、T. Mhiri2000-01-01Journal of Raman Spectroscopy

The infrared and Raman spectra of (NH4)2HPO4 and (ND4)2DPO4 were investigated between 10 and 450 K in the 4000–10 cm−1 wavenumber range. For the two compounds, four crystalline phases were evidenced and characterized spectroscopically, and structural and dynamic information was obtained. The crystalline structures and…

Crystallography and molecular interactionsAdvanced Chemical Sensor TechnologiesSolid-state spectroscopy and crystallography

Carrier Concentration Dependence of Thermal Conductivity of Iodine-Doped n-Type PbTe

Masaki Orihashi、Yasutoshi Noda、Lidong Chen 等 4 位作者2000-01-01Materials Transactions JIM

Thermal conductivity (κ) of iodine doped n-type PbTe with carrier concentration (n) in the range of 1.5×1024 to 3.4×1025 m−3 was measured by using a laser flash method in the temperature range from 300 to 600 K. The scattering factor (r) was estimated from the temperature dependence of Hall mobility. The r values belo…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsOptical properties and cooling technologies in crystalline materials

Lyapunov exponent for pure and random Fibonacci chains

M. T. Velhinho、I. R. Pimentel2000-01-01Physical review. B, Condensed matter

We study the Lyapunov exponent for electron and phonon excitations, in pure and random Fibonacci quasicrystal chains, using an exact real-space renormalization-group method, which allows the calculation of the Lyapunov exponent as a function of the energy. It is shown that the Lyapunov exponent on a pure Fibonacci cha…

Quasicrystal Structures and PropertiesX-ray Diffraction in Crystallography

Cloning and Sequencing of the Maltohexaose-producing Amylase Gene ofKlebsiella pneumoniae

Mitsuru Momma2000-01-01Bioscience Biotechnology and Biochemistry

The molecular characterization of the maltohexaose-producing amylase gene of Klebsiella pneumoniae revealed an open reading frame in which 2,031 base pairs encode a protein of 677 amino acids with a calculated molecular weight of 75,921. The amylase gene had high similarities of 73.6% in DNA sequence and 79.3% in dedu…

Genomics and Phylogenetic StudiesEnzyme Structure and FunctionMachine Learning in Bioinformatics

Hygrothermal Durability and Thermal Aging Behavior Prediction of High-Temperature Polymer-Matrix Composites and Their Resins

E. Eugene Shin、Roger J. Morgan、Jiming Zhou 等 6 位作者2000-01-01Journal of Thermoplastic Composite Materials

Prediction of the cure-induced Tg increases and associated matrix and composite mechanical property deterioration of BMI systems in real service environments is attempted by network structure interrelations with mechanical and thermal properties as a function of composition (initial monomer ratio) and time-temperature…

Natural Fiber Reinforced CompositesSynthesis and properties of polymersTribology and Wear Analysis

Effects of Strong Magnetic Field on Recrystallization and Coarsensing of Grains During Annealing in 3% Silicon Steel.

Ying Xu、Hideyuki Ohtsuka、K. Itoh 等 4 位作者2000-01-01Journal of the Magnetics Society of Japan

Effects of a strong magnetic field on recrystallization and coarsening of grains after primary recrystallization were studied in non-oriented 3% silicon steels. The strongest applied magnetic field strength was 10 tesla. It was found that primary recrystallization process is retarded by applying a strong magnetic fiel…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsElectromagnetic Effects on Materials

Electrochemical Examinations in 350°C Water with Respect to the Mechanism of Corrosion-Hydrogen Pickup

Karl Baur、F. Garzarolli、H Ruhmann 等 4 位作者2000-01-01OpenAlex

During corrosion of Zr alloys in pressurized water at high temperatures a fraction of the corrosion-hydrogen is picked up by the metal. Long-term out-of-pile corrosion experiments have shown that chemical composition of Zr alloys and the size of second-phase particles (SPP) in Zircaloy-4 (Zry-4) affect the corrosion a…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metals