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Reactivity of low-coordination sites on the surface of magnesium oxide

Salvatore Coluccia、Alan E. Barton、A. J. Tench1981-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

Photoluminescent and electron spin resonance studies of MgO smoke powders show that etching of the smoke cubes by water vapour leads to an increase in the number of reactive sites of low coordination on the surface without a parallel increase in the surface area. The formation of anion radicals after adsorption of oxy…

Magnesium Oxide Properties and Applications

Solid state properties of poly-β-hydroxybutyrate and of its oligomers

R. H. Marchessault、Suzanne Coulombe、Hiromichi Morikawa 等 5 位作者1981-01-01Canadian Journal of Chemistry

The solid state properties of poly-β-hydroxybutyrate (PHB) were investigated for samples with degrees of polymerization [Formula: see text] from 4 to 994. The observed melting points ranged from 47 °C to 180 °C. Electron diffractograms on carefully prepared single crystals of a high molecular weight sample provided da…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Scattering of waves from periodic surfaces

S. L. Chuang、Jin Au Kong1981-01-01Proceedings of the IEEE

The scattering of waves from periodic surfaces is studied. We give a general review of this problem and compare three analytical methods for a conducting sinusoidal surface in detail for both TE and TM polarized waves. The three methods are: 1) the method developed by Masel, Merrill, and Miller (MMM); 2) the Modified…

Advanced Fiber Optic SensorsElectromagnetic Scattering and AnalysisOptical Coatings and Gratings

Selective Chemical Extraction of Soil Components and Bound Metal Species

W.F. Pickering、L. M. Shuman1981-01-01C R C Critical Reviews in Analytical Chemistry

I. INTRODUCTION A. Background Soils and sediments are basic components of our environment, as they provide nurture for living matter and serve as "sinks" for deleterious species. The composition of these materials reflects the nature of the original base rock, the degree of degradation and leaching introduced by weath…

Heavy metals in environmentClay minerals and soil interactionsIron oxide chemistry and applications

Spin-density wave ground state in the one-dimensional conductor (TMTSF) 2PF6: microscopic evidence from 77Se and 1H NMR experiments

A. Andrieux、D. Jérôme、K. Bechgaard1981-01-01Journal de Physique Lettres

The vanishing of the 77Se nuclear resonance signal and the broadening by internal magnetic fields of the proton resonance line establish the existence of spin-density waves in the low temperature semiconducting state of (TMTSF) 2PF6. The thermally activated collective mode of the commensurate spin-density wave contrib…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallography

Cloning of 3-Isopropylmalate Dehydrogenase Gene of an Extreme Thermophile and Partial Purification of the Gene Product

Teruo Tanaka、Naoko Kawano、Tairo Oshima1981-01-01The Journal of Biochemistry

The gene of an extreme thermophile, Thermus thermophilus HB8, which codes for a leucine biosynthetic enzyme, 3-isopropylmalate (3-IPM) dehydrogenase [EC 1.1.1.85], was cloned in Escherichia coli using pBR322 as a vector. E. coli cells carrying this recombinant plasmid, pHB2, produced the thermophilic enzyme 7-fold mor…

Microbial Metabolic Engineering and BioproductionMetabolism and Genetic DisordersEnzyme Structure and Function

Structural studies on the caesium alums, CsM III [SO 4 ] 2 ·12H 2 O

James K. Beattie、Stephen P. Best、Brian W. Skelton 等 4 位作者1981-01-01Journal of the Chemical Society Dalton Transactions

Structure determinations of the caesium alums CsMIII[SO4]2·12H2O, M = V, Cr, Mn, Fe, Co, Al, Ga, or In, have been carried out at 295(1) K by X-ray diffraction methods. The data obtained include (i) MIII–O distances for the metals in the [M(OH2)6]3+ species [V–O, 1.992(6); Cr–O, 1.959(3); Mn–O, 1.991(6); Fe–O, 1.995(4)…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyX-ray Diffraction in Crystallography

Ionic Conductivity and Thermoelectric Power of Pure and Al2 O 3 ‐ Dispersed AgI

K. Shahi、Jeff Wagner1981-01-01Journal of The Electrochemical Society

Ionic and electronic conductivities, and thermoelectric power have been measured for AgI and AgI containing a dispersion of submicron size Al 2 O 3 particles. While the dispersion of Al 2 O 3 enhances the ionic conductivity significantly, it does not affect the electronic properties of the matrix. The enhancement is a…

Advanced Thermoelectric Materials and DevicesThermal Expansion and Ionic ConductivityChemical and Physical Properties of Materials

Theory of electrolyte crystal growth. The parabolic rate law

Arne E. Nielsen1981-01-01Pure and Applied Chemistry

Conference International Conference on Surface and Colloid Science, International Conference on Surface and Colloid Science, ICSCS, Surface and Colloid Science, Fourth, Jerusalem, Israel, 1981-07-05–1981-07-10 Published Online: 2009-01-01 Published in Print: 1981-01-01 © 2013 Walter de Gruyter GmbH, Berlin/Boston

Crystallization and Solubility StudiesChemical and Physical Properties in Aqueous SolutionsFreezing and Crystallization Processes

Translational diffusion and hydrodynamic radius of unperturbed flexible chains

Manfred Schmidt、Walther Burchard1981-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTranslational diffusion and hydrodynamic radius of unperturbed flexible chainsManfred Schmidt and Walther BurchardCite this: Macromolecules 1981, 14, 1, 210–211Publication Date (Print):January 1, 1981Publication History Published online1 May 2002Published inissue 1 January 1…

Fuel Cells and Related MaterialsDendrimers and Hyperbranched Polymers

Coherent scattering by one reptating chain

P. G. de Gennes1981-01-01Journal de physique

We discuss the time dependent correlation functions Sq( t) for one deuterated polymer chain, moving inside an entangled melt of chemically identical, protonated, chains. The region of interest corresponds to wave-vectors q such that D-1 >> q >> R0-1 where D is the tube diameter and R0 the overall chain size. In this r…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsRheology and Fluid Dynamics Studies

Coprecipitated nickel–alumina catalysts for methanation at high temperature. Part 1.—Chemical composition and structure of the precipitates

E.C. Kruissink、L. L. van Reijen、J.R.H. Ross1981-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

A series of materials containing nickel and aluminium ions has been prepared by coprecipitation with alkaline solutions, under various conditions, from solutions of the nitrates. The composition and structure of the precipitates has been examined using a number of techniques including chemical analysis, X-ray diffract…

Zeolite Catalysis and SynthesisLayered Double Hydroxides Synthesis and ApplicationsAmmonia Synthesis and Nitrogen Reduction

Development of Laboratory Test Method for Stress Corrosion Cracking of Steels in Liquid Ammonia

Youichi NAKAI、Yasuji Uesugi、Hayao KURAHASHI1981-01-01鐵と鋼 : 日本鐡鋼協會々誌

To develop a laboratory test method for accelerating stress corrosion cracking (SCC) of steels in liquid ammonia, effects of ammonia contaminants, such as O2, N2, CO2, etc., and electro-chemical polarization on the time to failure of specimen under a constant tensile load have been studied.SCC is strongly accelerated…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Burial Diagenesis of Illite/Smectite, a Kinetic Model: ABSTRACT

J. W. Patton D. G. McCubbin1981-01-01AAPG Bulletin

This DOI is not currently attached to any metadata records. DOIs can’t actually ever be deleted (they’re persistent), but sometimes our members create DOIs in error. We do have a process to approximate deletion which we follow only in rare cases where the DOI has been genuinely created in error, and most crucially, if…

Soil and Unsaturated FlowCO2 Sequestration and Geologic InteractionsClay minerals and soil interactions

Polarization techniques in coherent Raman spectroscopy

M. D. Levenson1981-01-01Journal of Raman Spectroscopy

Abstract The advantages of performing coherent Raman spectroscopy with definite input and output polarizations are reviewed. Methods are described for evaluating Raman susceptibility tensor elements, depolarization ratios and nonresonant contributions to the third order nonlinear susceptibility. A systematic developme…

Nonlinear Optical Materials ResearchSpectroscopy and Quantum Chemical StudiesSpectroscopy Techniques in Biomedical and Chemical Research

Catalysis by Molten Metals and Molten Alloys

Yoshisada Ogino1981-01-01Catalysis Reviews

It appears pertinent for the opening of this review to cite the work of Ipatiew [1]. In 1901 he reported that certain metals catalyzed the decomposition of alcohols even above the melting points of the catalyst metals, However, he gave no special attention to the catalytic activity of the molten metal (liquid metal),…

Extraction and Separation ProcessesMetallurgical Processes and ThermodynamicsMetallurgical and Alloy Processes

The Ionic Conductivity and Thermoelectric Power of the Superionic Conductor Ag3SBr

Junichi Kawamura、Mitsuo Shimoji、Hideoki Hoshino1981-01-01Journal of the Physical Society of Japan

The electrical conductivity and thermoelectric power of the superionic conductor Ag 3 SBr were measured in the temperature range from 293 K to 493 K. Considerable deviations from the Arrhenius law was observed in the results of the ionic conductivity. The temperature dependence of the thermoelectric power of this syst…

Material Dynamics and PropertiesIonic liquids properties and applicationsSolid-state spectroscopy and crystallography

Anisotropic hyperfine fields in FeSn by Mossbauer spectroscopy

S.K. Kulshreshtha、P. Raj1981-01-01Journal of Physics F Metal Physics

57 Fe and 19 Sn Mossbauer investigations of the antiferromagnetic compound FeSn are reported from 77K to well above its magnetic transition temperature. The observation of a single nuclear Zeeman pattern from 1(a) Sn sites implies that the spin ordering in the basal plane is collinear. The 57 Fe Mossbauer studies show…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

The observation of a shear flow instability in a rotating system with a soap membrane

Y. Couder1981-01-01Journal de Physique Lettres

A pattern of driven vortices can be observed in the shear layer created in a fluid by a rotation movement. We present such an experiment where a liquid membrane is used to close a thin experimental volume of air thus forming a wall with the following properties : — The parallel component of the fluid velocity does not…

Pickering emulsions and particle stabilization

Resonance in the Raman scattering of CaF2, SrF2, BaF2 and diamond

M. Grimsditch、M. Cardona、J. M. Calleja 等 4 位作者1981-01-01Journal of Raman Spectroscopy

Abstract The dependence of the first order Raman scattering efficiency of CaF 2 , SrF 2 , BaF 2 and diamond on photon energy ω L has been measured with different techniques. We find that in the visible these cross‐sections increase with ω L much faster than ω . This result has important implications as CaF 2 , for ins…

High-pressure geophysics and materialsGlass properties and applicationsNuclear Physics and Applications