Bulk Fe-Based Metallic Glass with Extremely Soft Ferromagnetic Properties
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A Solid Oxide Fuel Cell with a Novel Geometry That Eliminates the Need for Preparing a Thin Electrolyte Film
We propose a solid oxide fuel cell design based on a configuration of two electrodes on the same surface of the electrolyte in a flowing mixture of different hydrocarbons and air between 500 and 600°C. The ohmic resistance can be reduced without using a thin electrolyte film due to a significantly enhanced performance…
Synthesis, spectroscopy and metallation of mixed carbaporphyrinoid systems
Modified tripyrranes incorporating furan and thiophene rings were found to condense with benzene, pyridine and indene dialdehydes to give a series of novel porphyrin analogues, including thia- and oxa-carbaporphyrins; the latter readily forms nickel(II) and palladium(II) organometallic complexes.
Evolution of Ultrafine-grained Structure through Large Strain-High Z Deformation in a Low Carbon Steel
Ultrafine-grained structure formed dynamically through severe plastic deformation at elevated temperatures has been investigated in a 0.1% C-0.4% Si-1.5% Mn steel. The effects of the strain, the strain rate and the deformation temperature on the microstructural evolution were examined using a compression technique wit…
Diagnostics and insights on PECVD for gas-barrier coatings
Abstract In this work, we report on our last results concerning the polyethyleneterephtalate barrier performance optimization as a function of the chemistry of the SiOx coating, deposited by means of hexamethyldisiloxane/oxygen-fed plasmas ignited in an RF capacitively coupled parallel plates reactor. The influence of…
Dimensional Constraints on High Aspect Ratio Silicon Microstructures Fabricated by HF Photoelectrochemical Etching
The fabrication of macropores in crystalline silicon by photoelectrochemical etching in a hydrofluoric acid electrolyte is investigated. It is shown that the dimensional constraints on the pore diameters, which, in previous literature, are considered to depend on substrate doping, can be significantly relaxed. We show…
Characterization of Nanostructure of Rusts Formed on Weathering Steel.
Nano-scale structures of rusts formed on the weathering steel surface were investigated. It has been shown that the key structure is an Fe(O, OH)6 network, which is different from crystalline FeOOH. Atomic structures were analyzed quantitatively by a combination of X-ray absorption fine structure (XAFS) analysis inclu…
Plastic Deformation of Metal Thin Films without Involving Dislocations and Anomalous Production of Point Defects
Evidence for plastic deformation of crystalline metal thin films without involving dislocations is presented. Direct observation of the films during deformation under an electron microscope confirmed the absence of dislocations even for heavy deformation. In fcc metals, including aluminum, deformation leads to the for…
Spectroscopy of Excitons, Bound Excitons and Impurities in h-ZnO Epilayers
Photoluminescence (PL) and selective photoluminescence (SPL) experiments have been carried out to analyse the neutral donor bound exciton spectra of nominally undoped wurtzite ZnO epilayers and to study the electronic levels introduced by arsenic doping. The investigated samples were grown by molecular beam epitaxy on…
Juliá-Colonna Asymmetric Epoxidation in a Continuously Operated Chemzyme Membrane Reactor
Two novel soluble polymer-bound oligo-l-leucines 2 and 5, which can be retained by a membrane reactor system, have been prepared and used as catalysts for the continuously operated asymmetric epoxidation of chalcone. The optimized batch reaction conditions yield epoxychalcone in high enantioselectivities (up to 94%) a…
Interactions of H2O with SrTiO3(100) surfaces
Interactions of H2O with SrTiO3(100) surfaces were investigated using temperature-programed desorption (TPD) spectroscopy. TPD spectra show that water desorbs below 300 K on stoichiometric TiO2–terminated SrTiO3(100) surfaces. TPD features at 200–300 K are attributed to the nondissociative adsorption of H2O on cation…
Photodynamic Properties of Amphiphilic Derivatives of Aluminum Tetrasulfophthalocyanine¶
Photodynamic therapy (PDT) is a promising treatment modality that has recently been accepted in clinics as a curative or palliative therapy for cancer and other nonmalignant conditions. Phthalocyanines (Pc) are attractive photosensitizers for PDT because of their enhanced photophysical and photochemical properties. Th…
Bottom-up Filling of Submicrometer Features in Catalyst-Enhanced Chemical Vapor Deposition of Copper
A formation process for copper bottom-up filling of submicrometer via holes and trenches using iodine as a catalytic surfactant and hexafluoroacetylacetonate-copper-vinyltrimethylsilane in catalyst-enhanced chemical vapor deposition of copper is presented. The film growth rate of copper at the bottom of the submicrome…
Fast x-ray scattering measurements on molten alumina using a 120° curved position sensitive detector
Fast x-ray scattering measurements on molten alumina were performed on the H10 beam line at the DCI Synchrotron of LURE (Orsay, France). A high-temperature chamber with a levitation device was coupled with the four-circle goniometer of the beam line. A 100 W CO2 laser was used to melt the sample and the temperature wa…
A novel organometallic columnar complex containing endohedral silver( i )–ethynediyl binding and exterior silver( i )–aromatic interaction
Unprecedented eta 3 pi-donor behavior of the benzyltrimethy-lammonium ion is observed in the polymeric silver(I) complex [(PhCH2NMe3)Ag7(C2)(CF3CO2)6]n that comprises a columnar backbone constructed from the fusion of Ag8 square antiprisms each enclosing an acetylide dianion.
Direct‐Write Fabrication of Zinc Oxide Varistors
Zinc oxide (ZnO)‐based pastes with tailored rheological properties have been developed for direct‐write fabrication of thick‐film varistor elements in highly integrated, multifunctional electroceramic devices. Such pastes exhibited pseudoplastic behavior with a low shear apparent viscosity of roughly 1 × 10 4 Pa·s. Up…
Theoretical Study on the Chemistry of Intergranular Glassy Film in Si 3 N 4 –SiO 2 Ceramics
The intergranular glassy film (IGF) composed of silicon oxynitride in a Si 3 N 4 ceramic material has been studied by molecular dynamics calculations. Structural analyses showed that the presence of an IGF having both nitrogen and oxygen reduces the number of dangling bonds at the junction between the IGF and adjacent…
Theoretical investigation of the spin crossover transition states of the addition of methane to a series of Group 6 metallocenes using minimum energy crossing points
Density functional calculations are reported on the addition of methane to Group 6 metallocenes, M(η-C5H5)2 (M), M(CH2(η-C5H4)2) (a-M) and M(η-C5Me5)2 (M*) where M = Mo and W. Full geometry optimisations were carried out on the singlet and triplet 16 electron complexes, 1[M] and 3[M], the η2-methane complexes, 1[M(η2-…
Electrochemical Characterization of Polyacetylene Ionomers and Polyelectrolyte-Mediated Electrochemistry toward Interfaces between Dissimilarly Doped Conjugated Polymers
The electrochemical characterization of thin films of the ionically functionalized polyacetylene analogues poly(tetramethylammonium 2-cyclooctatetraenylethanesulfonate) (P(A)) and poly[(2-cyclooctatetraenylethyl)trimethylammonium trifluoromethanesulfonate] (P(C)) is reported along with an electrochemical approach to t…
Strong intramolecular chromophore interactions in novel bis([60]fullerene)–oligoporphyrin nanoarrays
Novel nanodimensional dyads were prepared by Bingel reaction of meso, meso-linked oligoporphyrin bis-malonates with C60. Distinct conformational effects were observed as a result of strong fullerene-porphyrin interactions, which also lead to efficient quenching of the porphyrin luminescence.