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Comparative IR Study of Nitric Oxide Reactions with Sublimed Layers of Iron(II)− and Ruthenium(II)−meso-Tetraphenylporphyrinates

Tigran S. Kurtikyan、Garik G. Martirosyan、Ivan M. Lorković 等 4 位作者2002-08-01Journal of the American Chemical Society

The interactions of nitric oxide gas with thin layers of Fe(II)(TPP) and Ru(II)(TPP), obtained by sublimation onto low-temperature substrate (77 K), has been investigated by means of IR spectroscopy (TPP = meso-tetraphenylporphyrinate). Only simple addition of NO to form Fe(TPP)(NO) is observed for the iron-porphyrin…

Nitric Oxide and Endothelin EffectsPorphyrin and Phthalocyanine ChemistryHemoglobin structure and function

Charge Ordering in θ-(BEDT-TTF)2X Materials

R. Torsten Clay、S. Mazumdar、David Campbell2002-08-01Journal of the Physical Society of Japan

We investigate theoretically charge ordered states on the anisotropic triangular lattice characteristic of the theta-(BEDT-TTF)_2 X materials. Using exact diagonalization studies, we establish that the charge order (CO) pattern corresponds to a ``horizontal'' stripe structure, with ...1100... CO along the two directio…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchN-Heterocyclic Carbenes in Organic and Inorganic Chemistry

EBSD Spatial Resolution in the SEM when Analyzing Small Grains or Deformed Material

P.A. Rolland、Keith Dicks、R. Ravel-Chapuis2002-08-01Microscopy and Microanalysis

P Rolland, K Dicks, R Ravel-Chapuis; EBSD Spatial Resolution in the SEM when Analyzing Small Grains or Deformed Material, Microscopy and Microanalysis, Vol

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Self-organized nanostructures of poly(4‐vinylpyridine), polyaniline and polyamides due to metal complexation

Sami Valkama、Juha Hartikainen、Mika Torkkeli 等 8 位作者2002-08-01Macromolecular Symposia

Comb-shaped supramolecules are constructed using flexible polymers and semi-rigid conjugated undoped or doped conjugated polymers upon complexing Zinc dodecyl benzene sulphonate, Zn(DBS)2. Selforganized nanostructures are formed in the bulk due to competing attractive interactions (coordination or water mediated hydro…

Conducting polymers and applicationsAnalytical Chemistry and SensorsSynthesis and properties of polymers

Neutronics Experiment of6Li-enriched Breeding Blanket with Li2TiO3/Be/F82H Assembly Using D-T Neutrons

Kentaro Ochiai、Axel Klix、Jun-ichi Hori 等 6 位作者2002-08-01Journal of Nuclear Science and Technology

To improve the nuclear performance of fusion breeding blankets, the application of thermal type blankets with 6Li-enriched ceramics and low-activation ferritic steel is suggested. However, appropriate neutronics experiments to investigate the nuclear performance of such blankets have never been carried out. Therefore,…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Physics and Applications

Interdiffusion at TiO 2 /Ti, TiO 2 /Ti 3 Al and TiO 2 /TiAl interfaces studied in bilayer structures

A. Zalar、J. van Lier、E. J. Mittemeijer 等 4 位作者2002-08-01Surface and Interface Analysis

Abstract Early‐stage interfacial reactions were studied in three different heat‐treated oxide/metal bilayers (the oxide is amorphous (a) TiO 2 and the metal is crystalline (c) Ti, c‐Ti 3 Al or amorphous a‐TiAl) by means of Auger electron spectroscopy (AES) depth profiling. The oxide/metal bilayers were sputter deposit…

Catalytic Processes in Materials ScienceMetal and Thin Film MechanicsIntermetallics and Advanced Alloy Properties

Formation of a polyetheramide triblock copolymer by reactive extrusion; process and properties

Byung Ho Lee、James L. White2002-08-01Polymer Engineering and Science

Abstract The synthesis of polyetheramide, containing poly(tetramethylene ether) (PTMEG) as the soft segment phase and polylactams as the hard phase was carried out in a Leistritz modular intermeshing counter‐rotating twin‐screw extruder in a one‐step, solvent‐free process. No by‐product such as carbon dioxide or H 2 O…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisSynthesis and properties of polymers

Reactive blending of poly(ethylene terephthalate)(pet)/ poly(ethylene 2,6‐naphthalate)(pen). I: Effect of mixing conditions on chain structure

Haihua Yang、Jinghong Ma、Wengang Li 等 5 位作者2002-08-01Polymer Engineering and Science

Abstract Reactive blending of poly(ethylene terephthalate)/poly(ethylene naphthalene 2,6dicarboxylate) with addition of 2,2'‐bis(1,3‐oxazoline) (BOZ) has been studied under various mixing conditions for the different compositions. The transesterification level, the sequence length of both PET and PEN short blocks, and…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Quantitative analysis of the plasmon loss intensities in x‐ray photoelectron spectra of magnesium

M. Kurth、P. C. J. Graat2002-08-01Surface and Interface Analysis

Abstract X‐ray photoelectron spectra of free‐electron metals such as magnesium and aluminium contain pronounced electron energy‐loss peaks due to plasmon excitations. Part of the intensity contained in these plasmon peaks is of an intrinsic nature. In this work a procedure is presented that allows the determination of…

Corrosion Behavior and InhibitionX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Rigorous coupled-wave analysis calculus of submicrometer interference pattern and resolving edge position versus signal-to-noise ratio

Alexander V. Tavrov2002-08-01Optical Engineering

Universita¨t StuttgartInstitut fu¨r Technische OptikPfaffenwaldring 970569 Stuttgart, DeutschlandE-mail: tavrov@ito.uni-stuttgart.deAbstract. The signal-to-noise ratio required to obtain 10-nm accuracy inthe measurement of lateral position is studied with an interference mi-croscope. Evaluations are performed using th…

Optical measurement and interference techniquesAdvanced Measurement and Metrology TechniquesOptical Coatings and Gratings

Spin-spin interaction of Dy3+ ions in KY(WO4)2

I. M. Krygin、A. D. Prokhorov、V. Dyakonov 等 5 位作者2002-08-01Physics of the Solid State

The spin-spin interaction of Dy3+ ions in a KY(WO4)2 single crystal is investigated by electron paramagnetic resonance (EPR) spectroscopy at a temperature of 4.2 K and a frequency of 9.2 GHz. The EPR spectra of ion pairs located in different coordination shells are analyzed. It is revealed that the considerable contri…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsTheoretical and Computational Physics

Thermodynamic modeling of the Ni–In system

Peter Waldner、Herbert Ipser2002-08-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract The complete nickel-indium system was thermodynamically assessed at a total pressure of 1 bar from room temperature up to liquidus temperatures. The Gibbs energies of five condensed soluti...

Electronic Packaging and Soldering Technologiesnanoparticles nucleation surface interactionsMetallurgical and Alloy Processes

Electrolytic process technologies for the production of primary magnesium

P. Duhaime、P. Mercille、Mitchell Antonine Pineau2002-08-01Mineral Processing and Extractive Metallurgy Transactions of the Institutions of Mining and Metallurgy Section C

Two routes currently exist for the commercial production of primary magnesium: thermal and electrolytic. The electrolytic process accounts for 75% of the Western world's production capacity and this level is expected to increase if known magnesium projects materialize in the near future. Commercial applications of the…

Zeolite Catalysis and SynthesisBauxite Residue and UtilizationMagnesium Oxide Properties and Applications

Structural relationships in (Mn 1−x Zn x )Mn 2 O 4 (0 ≤ x ≤ 0.26): The “dragging effect” of the tetrahedron on the octahedron

Ferdinando Bosi、Sergio Lucchesi、A. Della Giusta2002-08-01American Mineralogist

Ten hausmannite crystals (from Ilfeld and Friedrichrode, Harz, Germany), belonging to the (Mn 1-x Zn x )Mn 2 O 4 (0 ≤ x ≤ 0.26) system (I4 1 /amd hausmannite structure type), were characterized by chemical (electron microprobe) and structural (single-crystal X-ray diffractometer) analysis. The prevailing trivalent cat…

Magnetic Properties and Synthesis of FerritesLayered Double Hydroxides Synthesis and ApplicationsMicrowave Dielectric Ceramics Synthesis

Conducting Polymer/Silicon Heterojunction Diode for Gamma Radiation Detection

Jane Maria Gonçalves Laranjeira、Helen J. Khoury、W.M. de Azevêdo 等 5 位作者2002-08-01Radiation Protection Dosimetry

In this work, alternative heterojunction devices to be used for gamma-radiation detection are presented. The high quality silicon/polyaniline heterostructures use polyaniline thin films as an active part of the device structure. Polyaniline thin films 40 nm thick were deposited onto silicon substrates (n-type, <100>,…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsAnalytical Chemistry and Sensors

The Structure of Gallium Phosphate Glasses by High-energy X-ray Diffraction

Uwe Hoppe、D. Ilieva、J. Neuefeindb2002-08-01Zeitschrift für Naturforschung A

X-ray diffraction experiments are used to obtain short-range order information of gallium phosphate glasses of meta- and pyrophosphate compositions. Parameters of the first-neighbor peaks, such as coordination numbers and distances, are obtained. A strong decrease of the Ga-O coordination number from 6.0±0.2 to 4.6±0.…

Glass properties and applicationsPhotonic Crystals and ApplicationsSilicon Nanostructures and Photoluminescence

Crystal Structure of Lu 4 Si 2 O 7 N 2 Analyzed by the Rietveld Method Using the Time‐of‐Flight Neutron Powder Diffraction Pattern

Junichi Takahashi、Hisanori Yamane、Masahiko Shimada 等 9 位作者2002-08-01Journal of the American Ceramic Society

The crystal structure of a lutetium silicon oxynitride (Lu 4 Si 2 O 7 N 2 ) was analyzed by the Rietveld method using time‐of‐flight (TOF) neutron powder diffraction data. The compound crystallizes in a monoclinic cell, space group P 2 1 / c (No. 14‐1) with a = 7.4243(1), b = 10.2728(1), c = 10.6628(1) Å, and β= 109.7…

Advanced ceramic materials synthesisInorganic Chemistry and MaterialsX-ray Diffraction in Crystallography

JANIS: A New Software for Nuclear Data Services

Ali Nouri、P. Nagel、N. Soppera 等 10 位作者2002-08-01Journal of Nuclear Science and Technology

Janis (Java-based nuclear information software) is a display program designed to facilitate the visualisation and manipulation of nuclear data. Its objective is to allow the user of nuclear data to access numerical and graphical representations without prior knowledge of the storage format. It offers maximum flexibili…

Nuclear reactor physics and engineeringNuclear Physics and ApplicationsGraphite, nuclear technology, radiation studies

BURNSITE, KCdCu7O2(SeO3)2Cl9, A NEW MINERAL SPECIES FROM THE TOLBACHIK VOLCANO, KAMCHATKA PENINSULA, RUSSIA

S. V. Krivovichev、L. P. Vergasova、Галина Л. Старова 等 7 位作者2002-08-01The Canadian Mineralogist

La burnsite, dont la formule ideale est KCdCu 7 O 2 (SeO 3 ) 2 Cl 9 , a ete decouverte dans une fumerolle dans la breche du Nord de la grande eruption fissurale du volcan Tolbachik (1975-1976), dans la peninsule de Kamchatka, en Russie. Elle se presente en grains rouge fonce, xenomorphes, equidimensionnels. Lui sont a…

Geological and Geochemical AnalysisCrystal Structures and PropertiesMineralogy and Gemology Studies

Adsorption of Phenols onto 1,1′-Dimethyl-4,4′-bipyridinium-smectites

Tomohiko Okada、Makoto Ogawa2002-08-01Chemistry Letters

Abstract Adsorption of phenols (phenol and 2-naphthol) onto the 1,1′-dimethyl-4,4′-bipyridinium (methylviologen:MV2+)-smectite intercalation compounds, which were synthesized by ion exchange reactions, led to the change in the color and the basal spacing. The color change was ascribed to the formation of charge-transf…

Mesoporous Materials and CatalysisClay minerals and soil interactionsIron oxide chemistry and applications