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Effect of Temperature and Pressure on Segmental Relaxation in Polymethylphenylsiloxane

Sebastian Pawlus、Sylwester J. Rzoska、J. Zioło 等 5 位作者2003-11-01Rubber Chemistry and Technology

Abstract Segmental relaxation in a series of polymethylphenylsiloxanes (PMPS) was studied using dielectric spectroscopy. The measurements covered a temperature range of more than 40 deg at pressures from ambient to 115 MPa. The results confirmed that the shape of the loss peak is independent of temperature, pressure a…

Polymer Nanocomposites and PropertiesEpoxy Resin Curing ProcessesSilicone and Siloxane Chemistry

Analysis of cell gap-dependent driving voltage in a fringe field-driven homogeneously aligned nematic liquid crystal display

Hyang Yul Kim、Seung Ho Hong、John M. Rhee 等 4 位作者2003-11-01Liquid Crystals

We have studied cell gap-dependent driving voltage characteristics in a homogeneously aligned nematic liquid crystal (LC) cell driven by a fringe electric field, termed the fringe field switching (FFS) mode. The results show that for the FFS mode using a LC with positive dielectric anisotropy, the operating voltage de…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationPlant Reproductive Biology

Cathodoluminescence investigations on the Popigai, Ries, and Lappajärvi impact diamonds

Giovanni Pratesi、Alessandro Lo Giudice、S. A. Vishnevsky 等 5 位作者2003-11-01American Mineralogist

Twenty impact diamond samples from the Popigai, Ries, and Lappajärvi astroblemes were analysed using cathodoluminescence (CL) at room temperature (RT). Five of the samples were further investigated at liquid nitrogen temperature (LNT). Cathodoluminescence images allowed for the discrimination of diamond from graphite,…

Astro and Planetary ScienceHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

Gel Formation in Natural Rubber Latex: 2. Effect of Magnesium Ion

Lucksanaporn Tarachiwin、Jitladda Sakdapipanich、Yasuyuki Tanaka2003-11-01Rubber Chemistry and Technology

Abstract The effect of Mg 2+ ions on the gel formation in fresh and commercial high ammonia natural rubber latices (FL-latex and commercial HA-latex) was analyzed from the gel content and 2+ content after treatment with (NH 4 ) 2 SO 4 . The gel content of rubber from commercial HA-latex decreased significantly after (…

Polymer Nanocomposites and PropertiesAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Understanding the Chemistry of the Rubber/Silane Reaction for Silica Reinforcement, Using Model Olefins

Subhas Chandra Debnath、Raja Datta、J. W. M. Noordermeer2003-11-01Rubber Chemistry and Technology

Abstract Although bifunctional organosilanes, particularly bis-(triethoxy-silyl-propyl) tetrasulfide (TESPT), are very efficient silica-rubber coupling agents, a high level is required to realize an optimum balance of processing as well as other performance characteristics. As to the functionality of TESPT in silica s…

Synthesis and characterization of novel inorganic/organometallic compoundsSynthesis and properties of polymersSilicone and Siloxane Chemistry

Kinetics of the Catalytic Oxidation of Lean Trichloroethylene in Air over Pd/Alumina

A. Aranzabal、J. L. Ayastuy-Arizti、José A. González‐Marcos 等 4 位作者2003-11-01Industrial & Engineering Chemistry Research

Kinetic modeling of the catalytic oxidation of trichloroethylene (TCE) over a palladium supported on alumina was evaluated. On the basis of previous studies on the effect of temperature, inlet TCE and oxygen concentrations, and the space velocity on the reaction rate, a five-step reaction network scheme, based on an E…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsNanomaterials for catalytic reactions

Even-Odd Effect of 35Cl Quadrupole Coupling Constants in Solid n-Alkylammonium Chlorides (C5 - C10)

Hisashi Honda2003-11-01Zeitschrift für Naturforschung A

35 Cl NMR spectra were measured using the highest-temperature solid phase of n-C x H (2x+1) NH 3 Cl and n-C x H (2x+1) ND 3 Cl (x=5−10). The observed quadrupole coupling constants (e 2 Qqh −1 ) decreased upon heating in this phase, and significant frequency differences of ca. 20 − 30 kHz were detected between the -NH…

Ionic liquids properties and applicationsSolid-state spectroscopy and crystallographyElectron Spin Resonance Studies

Localized strain autowaves at the initial stage of plastic flow in single crystals

В. И. Данилов、С. А. Баранникова、Л. Б. Зуев2003-11-01Technical Physics

Plastic strain localization in single crystals of pure metals and alloys is studied on the yield plateau and at the easy glide stage with a zero or small strain hardening coefficient. The difference between localization patterns in the two cases is explained, and strain localization mechanisms are suggested. At these…

Microstructure and mechanical propertiesElectromagnetic Effects on MaterialsMaterial Properties and Failure Mechanisms

Modeling Permeability in Homogeneous Three-Dimensional Nonwoven Fabrics

Ningtao Mao、Stephen J. Russell2003-11-01Textile Research Journal

A simplified three-dimensional structural model for a series of nonwoven fabrics is presented. The corresponding directional permeabilities of the fabrics are calculated based on the measured two-dimensional fiber orientation distribution. The influences of fiber diameter, fabric porosity, and fiber orientation distri…

Textile materials and evaluationsAerosol Filtration and Electrostatic PrecipitationMaterial Properties and Processing

Effect of niobium in medium alloyed ductile cast irons

A. Bedolla-Jacuinde、Eunice Solis、B. Hernández2003-11-01International Journal of Cast Metals Research

The present work studies the effect of niobium addition on the mechanical properties and microstructure of an as-cast 4·3%Ni alloyed ductile iron. The experimental iron was made from high purity raw materials in a laboratory induction furnace. Eight castings were produced with niobium content in the range 0–0·8%. Sili…

Microstructure and Mechanical Properties of SteelsAdvanced materials and compositesMetal Alloys Wear and Properties

Structural, Electrical and Spectral Studies on Double Rare-Earth Orthoferrites La 1 x Nd x FeO 3

O. M. Hemeda、Mohsen Mohamed Barakat、D. M. Hemeda2003-11-01TURKISH JOURNAL OF PHYSICS

Samples of double rare-earth ferrite La1 xNdxFeO3 are synthesized by a high-temperature double sintering ceramic technique. X-ray diraction shows that all compounds have an orthorhombic structure. The values of lattice parameter and the volume of the unit cell, changes with increasing Nd 3+ content. The Goldschmidt to…

Multiferroics and related materialsSolid-state spectroscopy and crystallographyHeusler alloys: electronic and magnetic properties

Preparation and Characterization of Films Using Barley and Oat β‐Glucan Extracts

S. Tejinder2003-11-01Cereal Chemistry

ABSTRACT Films for potential food use were prepared from aqueous solutions of β‐glucan extracted from hulled barley, hull‐less barley, and oats. The extracts (75.2–79.3% β‐glucan) also contained proteins, fat, and ash. Glycerol was used as a plasticizer. The films were translucent, smooth, and homogeneous in structure…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Primary photoprocesses in cationic 5,10,15,20-meso-tetrakis(4-N-methylpyridiniumyl)porphyrin and its transition metal complexes bound with nucleic acids

Vladimir S. Chirvony2003-11-01Journal of Porphyrins and Phthalocyanines

Photophysical properties of meso-tetrakis(4-N-methylpyridiniumyl)porphyrin ( TMpyP 4) and its metallocomplexes M (II) TMpy P4 ( M = Zn , Cu , Ni , Co ) bound to natural DNA and synthetic poly-, oligo- and mononucleotides are considered with a primary emphasis placed upon intermolecular interaction of the photoexcited…

DNA and Nucleic Acid ChemistryPorphyrin and Phthalocyanine ChemistryPorphyrin Metabolism and Disorders

Two scenarios for phase-transformation in disordered media

В. В. Бражкин、A. G. Lyapin2003-11-01Journal of Experimental and Theoretical Physics Letters

The reasons for the existence of various scenarios for structural transformations in disordered condensed media, such as liquids and amorphous substances, where both smeared transformations and sharp first-order transitions may occur, were analyzed. The ratio between the spatial scale of structural correlations and th…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesGlass properties and applications

Torsion Properties of High Density Polyethylene Foams

Yaolin Zhang、Denis Rodrigue、A. Aı̈t-Kadi2003-11-01Journal of Cellular Plastics

High density closed-cell HDPE foams (450–950 kg/m3) were prepared by compression molding, and torsion rectangular tests were performed to measure their shear modulus in order to study: (1) the relationship between the modulus as a function of the density, and (2) to determine the effect of thin skins. Based on the ass…

Polymer crystallization and propertiesCellular and Composite StructuresPolymer Foaming and Composites

Use of Monomethyl Itaconate Grafted Poly(propylene) (PP) and Ethylene Propylene Rubber (EPR) as Compatibilizers for PP/EPR Blends

Mehrdad Yazdani‐Pedram、Raúl Quijada、Miguel A. López‐Manchado2003-11-01Macromolecular Materials and Engineering

Abstract The use of grafted poly(propylene) (PP) and a random copolymer of ethylene and propylene (EPR) with an itaconic acid derivative, monomethyl itaconate (MMI), as compatibilizer for PP/EPR blends was analyzed. The grafting reaction was performed at 190 °C in a Brabender Plasticorder. 2,5‐Dimethyl‐2,5‐bis( tert ‐…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

ADDENDUM TO “CATALOGUE OF THE DIATOM GENERA”

Elisabeth Fourtanier、John Patrick Kociolek2003-11-01Diatom Research

This addendum to “Catalogue of the diatom genera” (Fourtanier & Kociolek, Diatom Research, 14, 1–190, 1999) includes nomenclatural information for 93 generic names, most of which were published in the last 6 years. The data for each name include authorship, place of publication with pages on which the protologue appea…

Paleontology and Stratigraphy of FossilsProtist diversity and phylogenyDiatoms and Algae Research

Halogen- and Phosphorus-free Flame Retardant PC Plastic with Excellent Moldability and Recyclability

Hajime Nishihara、Yoshikazu Suda、Toshiharu Sakuma2003-11-01Journal of Fire Sciences

Silicon compounds containing R3SiO1/2 (M-unit), R2SiO (D-unit), RSiO3/2 (T-unit), and SiO2 (Q-unit) in various combinations are commonly used as flame-retardant auxiliaries for polycarbonate (PC) plastics, and the use of branched DT-type silicones as the main flame retardant has also gained interest. We have found, ba…

Flame retardant materials and propertiesFiber-reinforced polymer compositesSynthesis and properties of polymers

Modification of the Monomer Composition of Polyhydroxyalkanoate Synthesized in Saccharomyces cerevisiae Expressing Variants of the β-Oxidation-Associated Multifunctional Enzyme

Silvia Marchesini、Nadine Erard、Tuomo Glumoff 等 5 位作者2003-11-01Applied and Environmental Microbiology

Expression by Saccharomyces cerevisiae of a polyhydroxyalkanoate (PHA) synthase modified at the carboxy end by the addition of a peroxisome targeting signal derived from the last 34 amino acids of the Brassica napus isocitrate lyase (ICL) and containing the terminal tripeptide Ser-Arg-Met resulted in the synthesis of…

Parkinson's Disease Mechanisms and Treatmentsbiodegradable polymer synthesis and propertiesPeroxisome Proliferator-Activated Receptors

Study of magnetic correlations in nanostructured ferromagnets by correlation magnetometry

Р. С. Исхаков、V. A. Ignatchenko、С. В. Комогорцев 等 4 位作者2003-11-01Journal of Experimental and Theoretical Physics Letters

We propose a theoretically justified experimental magnetometric technique for determining the size of stochastic domains spontaneously formed in the spin system of nanostructured ferromagnets and for evaluating the effective anisotropy in these magnetically correlated regions. The method is based on monitoring the Δ M…

Magnetic properties of thin filmsMetallic Glasses and Amorphous AlloysMagnetic Properties and Applications