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Single metallic nanoparticle imaging for protein detection in cells

Laurent Cognet、Catherine Tardin、David Boyer 等 6 位作者2003-09-17OpenAlex

We performed a visualization of membrane proteins labeled with 10-nm gold nanoparticles in cells, using an all-optical method based on photothermal interference contrast. The high sensitivity of the method and the stability of the signals allows 3D imaging of individual nanoparticles without the drawbacks of photoblea…

Gold and Silver Nanoparticles Synthesis and ApplicationsBiosensors and Analytical DetectionPhotoacoustic and Ultrasonic Imaging

A Synthetic Route to Ordered Mesoporous Carbon Materials with Graphitic Pore Walls

Tae‐Wan Kim、In‐Soo Park、Ryong Ryoo2003-09-17OpenAlex

Carbonization of aromatic sources in an aluminosilicate mesoporous template yields mesoporous carbon materials with highly graphitic framework structures and excellent mechanical strength and thermal stability (see picture). TEM analysis shows discoid graphitic layers that are packed so that the most preferred orienta…

Metal-Organic Frameworks: Synthesis and ApplicationsMesoporous Materials and CatalysisCovalent Organic Framework Applications

Nanostructure fabrication using block copolymers

Ian W. Hamley2003-09-17OpenAlex

A brief overview is provided of recent developments in the use of block copolymer self-assembly to create morphologies that may be used to template the fabrication of nanostructures in other materials. The patterning of semiconductor surfaces using block copolymer film masks and the production of high-density arrays o…

Nanoparticle-Based Drug DeliveryMesoporous Materials and CatalysisBlock Copolymer Self-Assembly

Small-angle scattering studies of biological macromolecules in solution

Dmitri I. Svergun、Michel H. J. Koch2003-09-17OpenAlex

Small-angle scattering (SAS) of x-rays and neutrons is a fundamental tool in the study of biological macromolecules. The major advantage of the method lies in its ability to provide structural information about partially or completely disordered systems. SAS allows one to study the structure of native particles in nea…

Protein Structure and DynamicsEnzyme Structure and FunctionAdvanced NMR Techniques and Applications

Sufficient Conditions for Direct Methods with Swift Electrons

Laurence D. Marks、Wharton Sinkler2003-09-16Microscopy and Microanalysis

We investigate cases where one can argue that sufficient conditions exist for Direct Methods to work with swift electrons. In addition to simple cases where kinematical scattering holds (e.g., surfaces in plan view), we identify three other configurations: (a) when 1s channeling holds and kinematical scattering is sta…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesAdvanced Materials Characterization Techniques

Response of LiF-TLD micro-rods around125I radioactive seed

Paul Mobit、Iulian Badragan2003-09-16Physics in Medicine and Biology

The EGSnrc Monte Carlo system has been used to calculate the energy response of LiF-TLDs of different sizes around 125I permanent brachytherapy sources. The source model includes the effects of an encapsulation, self-absorption within the source and in the welded ends of the encapsulation. The LiF-TLD material has cyl…

Radiation Shielding Materials AnalysisGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Experimental study of maleation of polypropylene in various twin‐screw extruder systems

Dohoon Chang、James L. White2003-09-16Journal of Applied Polymer Science

Abstract A range of continuous mixing machines were used as continuous reactors for grafting maleic anhydride onto polypropylene. The machines used were (1) a nonintermeshing modular counterrotating twin‐screw extruder, (2) an intermeshing modular corotating twin‐screw extruder, (3) intermeshing modular counterrotatin…

Advanced Sensor and Energy Harvesting MaterialsPolymer crystallization and propertiesHigh voltage insulation and dielectric phenomena

Simplified synthesis of carbohydrate‐functional siloxanes via transacetalation. I. Glucose‐functional siloxanes

Takuya Ogawa2003-09-16Journal of Polymer Science Part A Polymer Chemistry

Abstract Carbohydrate‐functional siloxanes (CHFSs) that exhibit high intermolecular interactions and good environmental friendliness have successfully been synthesized by acid‐catalyzed transacetalation between an acetal‐functional siloxane and glucose in dimethylformamide/dioxane mixed solvents. Activated clay has pr…

biodegradable polymer synthesis and propertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Charged-particle potential for boron nitrides, silicon nitrides, and borosilazane ceramics: Derivation of parameters and probing of capabilities

Marcus Gastreich、Julian D. Gale、Christel M. Marian2003-09-16Physical review. B, Condensed matter

A classical pair potential, augmented by three-body interactions, for the modeling of borosilazane ceramics has been derived on the basis of both experimental and ab initio data. The primary goals were a good description of structural parameters and applicability in molecular dynamics. Furthermore, major challenges we…

Advanced Chemical Physics StudiesSemiconductor materials and devicesBoron and Carbon Nanomaterials Research

Electron dynamics in chromium probed with 20-fs optical pulses

Hideki Hirori、Takehiro Tachizaki、Osamu Matsuda 等 4 位作者2003-09-16Physical review. B, Condensed matter

Electron excitation and relaxation in chromium are probed with 20-fs time resolution using an ultrafast optical technique. We obtain good fits to the data for the transient reflectivity and transmittivity changes in a thin film using a simple model of electron relaxation, suggesting the existence of an efficient elect…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Meissner response of anisotropic superconductors

V. G. Kogan2003-09-16Physical review. B, Condensed matter

The response field of a half-space anisotropic superconductor is evaluated for an arbitrary weak external field source. Example sources of a point magnetic moment and a circular current are considered in detail. For the penetration depth $\ensuremath{\lambda}\ensuremath{\ll}L$ with L being any other relevant distance…

Magnetic Properties and ApplicationsNon-Destructive Testing TechniquesSurface and Thin Film Phenomena

Molecular Energy and Electron Transfer Assemblies Made of Self‐Organized Lipid‐Porphyrin Bilayer Vesicles

Teruyuki Komatsu、Miho Moritake、Eishun Tsuchida2003-09-16Chemistry - A European Journal

Novel molecular energy and electron transfer assemblies in vesicular form, which are made of self-organized amphiphilic porphyrins bearing phospholipid-like substituents (lipid-porphyrins), have been photochemically characterized. Tetraphenylporphyrin (TPP) derivatives with four dialkylphosphocholine groups [free-base…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Electrochemical Synthesis and Characterization of Redox Polymer Nanostructures

I. Tchepournaya、Svetlana Vasilieva、S. A. Logvinov 等 6 位作者2003-09-16Langmuir

Template-based electrochemical methods for the synthesis of nanostructures on the basis of new redox polymers poly[M(Schiff)] (M = Ni, Pd; Schiff = tetradentate Schiff bases) with nanowire diameters in the range of 20−200 nm were developed. Polymeric nanostructures were characterized by means of electron microscopy, c…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Evidence for Secondary Minimum Flocculation of Stöber Silica Nanoparticles at the Air−Water Interface: Film Balance Investigations and Computer Simulations

Gyula Tolnai、A. Agod、M. Kabai-Faix 等 6 位作者2003-09-16The Journal of Physical Chemistry B

The interactions of Stöber silica nanospheres having diameters of ca. 40, 100, and 200 nm were studied at the water−air interface with a Wilhelmy film balance. The particle sizes and size distribution functions were determined from TEM measurements. According to in situ Brewster angle microscopy investigations and the…

Surfactants and Colloidal SystemsMinerals Flotation and Separation TechniquesPickering emulsions and particle stabilization

Formation of ordered microporous films with water as templates from poly(D,L‐lactic‐co‐glycolic acid) solution

Xiaoyong Zhao、Qing Cai、Guixin Shi 等 5 位作者2003-09-16Journal of Applied Polymer Science

Abstract Recently a method that uses water droplets at the air–solution interface as an ordered template was reported for the preparation of ordered micrometer‐size honeycomb structures. Here we show that the method can also be used for formation of honeycomb‐like porous films from random copolymers with certain hydro…

Advanced Polymer Synthesis and CharacterizationMesoporous Materials and CatalysisBlock Copolymer Self-Assembly

Electron–optical phonon interaction in carbon nanotubes

G. D. Mahan2003-09-16Physical review. B, Condensed matter

The electron-phonon interaction is calculated for electrons states in single wall carbon nanotubes. Explicit results are presented for armchair and zig-zag tubes. The scattering by acoustical phonons confirm earlier results, while the scattering by optical phonons is new.

Carbon Nanotubes in CompositesMechanical and Optical ResonatorsNanotechnology research and applications

Structure and chemical composition of LiB3O5 surfaces

Victor V. Atuchin∥⊥、V. G. Kesler、Irina A. Lisova 等 6 位作者2003-09-16Crystal Research and Technology

Abstract The electronic and structural properties of LiB 3 O 5 (LBO) surfaces have been studied by X‐ray photoemission spectroscopy (XPS) and reflectance high‐energy electron diffraction (RHEED). The as‐grown (110) crystal face and mechanically polished (001) surfaces have been investigated comparatively. Electronic s…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchElectronic and Structural Properties of Oxides

On the Consistency of QCBED Structure Factor Measurements for TiO2 (Rutile)

Bin Jiang、Jian‐Min Zuo、Jesper Friis 等 4 位作者2003-09-16Microscopy and Microanalysis

The same Bragg reflection in TiO2 from 12 different (CBED) patterns (from different crystals, orientations, and thicknesses) are analyzed quantitatively to evaluate the consistency of the quantitative CBED method for bond-charge mapping. The standard deviation in the resulting distribution of derived X-ray structure f…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesX-ray Diffraction in Crystallography

Quantitative Convergent Beam Electron Diffraction Measurements of Low-Order Structure Factors in Copper

Jesper Friis、Bin Jiang、John C. H. Spence 等 4 位作者2003-09-16Microscopy and Microanalysis

Accurate low-order structure factors for copper metal have been measured by quantitative convergent beam electron diffraction (QCBED). The standard deviation of the measured structure factors is equal to or smaller than the most accurate measurement by any other method, including X-ray single crystal Pendellösung, Bra…

Electron and X-Ray Spectroscopy TechniquesX-ray Diffraction in CrystallographySurface and Thin Film Phenomena

Poly(etherimide)/montmorillonite nanocomposites prepared by melt intercalation

Zhu‐Mei Liang、Jie Yin2003-09-16Journal of Applied Polymer Science

Abstract A novel aromatic amine organo‐modifier synthesized in our previous work was used to treat montmorillonite (MMT) and the organo‐modified MMT was used to prepare poly(etherimide) (PEI)/MMT nanocomposites by a melt intercalation method. MMT treated by this amine exhibited large layer‐to‐layer spacing and a high…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesSynthesis and properties of polymers