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Exploiting spiders’ silk

Paula Gould2002-12-01Materials Today

Scientists and engineers have long envied spiders’ ability to manufacture a material that is simultaneously strong, fine, and tough. This combination of properties makes spider silk an extremely attractive candidate for numerous applications in medicine, defense, and the leisure industry. Research teams worldwide are…

Invertebrate Immune Response MechanismsSilk-based biomaterials and applicationsSilkworms and Sericulture Research

Use of Cement By-pass Dust in Flowable Fill Mixtures

Khalifa Al‐Jabri、Ramzi Taha、A Al-Harthy 等 5 位作者2002-12-01Cement Concrete and Aggregates

Abstract Flowable fill is a self-compacted, cementitious material used primarily as a backfill in lieu of compacted fill. It is generally a mixture of sand, small amount of cement, fly ash, and water. Sand is the major component of most flowable fill mixes. Waste materials such as fly ash, ground granulated blast furn…

Innovations in Concrete and Construction MaterialsMaterial Properties and ApplicationsMaterials Engineering and Processing

Near infrared (NIR) spectroscopy compared with thermogravimetric analysis as a tool for on‐line prediction of water diffusion in polyamide 6,6

Walker Camacho、Mikael S. Hedenqvist、Sigbritt Karlsson2002-12-01Polymer International

Abstract NIR spectroscopy in the transmission mode and thermogravimetric analysis were used to predict diffusion of water into polyamide 6,6 samples immersed in water at 40, 60, 75 and 90 °C for different periods of time. The sorption curves between 40 and 75 were sigmoidal indicating that the surface concentration wa…

Polymer crystallization and propertiesAdvanced Chemical Sensor TechnologiesRecycling and Waste Management Techniques

New Cathode Materials for Molten Carbonate Fuel Cells

Athula Wijayasinghe、Carina Lagergren、Bill Bergman2002-12-01Fuel Cells

Abstract Development of alternative cathode materials, has been a main strategy for solving the cathode dissolution problem of the Molten Carbonate Fuel Cell (MCFC). Ternary compositions of LiFeO 2 , LiCoO 2 and NiO are expected to combine some desirable properties of each component. Preliminary studies on LiFeO 2 ‐Li…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsMolten salt chemistry and electrochemical processes

High speed steels for hot rolls with improved impact and thermal fatigue resistance

A. Molinari、Alberto Tremea、M. Pellizzari 等 5 位作者2002-12-01Materials Science and Technology

Experimental centrifugally cast high speed steels (HSSs) with a modified solidification microstructure were produced, with the aim of improving impact properties and thermal fatigue resistance to extend the application of these materials to the production of roughing and intermediate finishing hot rolls. On the basis…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Oxidation behavior of silicide coating on Ti3SiC2-based ceramic

G. M. Liu、Muzhi Li、Yanchun Zhou 等 4 位作者2002-12-01Materials Research Innovations

A silicide coating was prepared on Ti3SiC2- based ceramic by pack cementation to improve the oxidation resistance of Ti3SiC2, which is a technologically important material for high temperature applications. The microstructure, phase composition and oxidation resistance of the coated sample were investigated. The resul…

Advanced ceramic materials synthesisIntermetallics and Advanced Alloy PropertiesMXene and MAX Phase Materials

PP-based Model Compounds as Tools for the Development of High-impact-ethylene-propylene Copolymers

Markus Gahleitner、Andreas Hauer、Klaus Bernreitner 等 4 位作者2002-12-01International Polymer Processing

Abstract The development of heterophasic PP-copolymers, which are necessary in many applications because of their specific property profile, requires large capacities in pilot plants (or at least in bench-scale reactors) for a systematic variation of the matrix and elastomer properties. A possible alternative are mode…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Anomalous states of the structure of (NH4)2SO4 crystals in the temperature range 4.2–300 K

I. M. Shmytko、N. S. Afonikova、В. И. Торгашев2002-12-01Physics of the Solid State

Crystals of the (NH 4 ) 2 SO 4 ammonium sulfate are studied using x-ray diffractometry. It is revealed that the temperature dependence of the lattice parameters exhibits an anomalous behavior, namely, a global hysteresis, and an anomalous increase in the lattice parameter a and the unit cell volume at temperatures bel…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyOptical and Acousto-Optic Technologies

Preparation and Characterization of Acrylic/Nano-TiO2 Composite Latex

Qiyang He、Limin Wu、Guangxin Gu 等 4 位作者2002-12-01High Performance Polymers

Acrylic/nano-TiO 2 composite latex samples were prepared via high-shear stirring and mixing (SM), ball milling and mixing (BM) and in situ polymerization (IS) methods, and investigated by transmission electron micrography (TEM), testing with an Instron machine, dynamic mechanical analysis (DMA) and ultraviolet-visible…

Advanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and PropertiesSynthesis and properties of polymers

Effect of isotacticity distribution on crystallization kinetics of polypropylene

Hongbin Lu、Jinliang Qiao、Yuliang Yang2002-12-01Polymer International

Abstract The crystallization kinetics of isotactic polypropylene (iPP) depends not only on the undercooling but also on its microstructure characteristics. In this paper the effect of isotacticity distribution on the isothermal kinetics of iPPs in the crystallization regime III was examined by differential scanning ca…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Control of In‐Plane and Out‐Of‐Plane Reorientation in Photo‐Cross‐Linkable Copolymer Liquid‐Crystal Films by Irradiation with Linearly Polarized Ultraviolet Light and Annealing

Nobuhiro Kawatsuki、Nobuyoshi Furuso、Emi Uchida 等 4 位作者2002-12-01Macromolecular Chemistry and Physics

Abstract This paper describes thermally enhanced in‐plane and out‐of‐plane reorientation of mesogenic groups in copolymer liquid‐crystal (CPLC) films that have a photo‐cross‐linkable 4‐(4′‐methoxycinnamoyl)biphenyl (MCB) side group and a 4‐methoxybiphenyl (4MB) side group. The side groups are cross‐linked by irradiati…

Liquid Crystal Research AdvancementsPhotochromic and Fluorescence ChemistryOptical Polarization and Ellipsometry

In vivo evaluation of lumbrokinase, a fibrinolytic enzyme extracted from Lumbricus rubellus, in a prosthetic vascular graft.

Hwang Cm、Kim Di、Huh Sh 等 10 位作者2002-12-01PubMed

BACKGROUND: Lumbrokinase (LK) is a fibrinolytic enzyme purified from the earthworm Lumbricus rubellus. To investigate the fibrinolytic and antithrombotic effects of lumbrokinase, a series of animal experiments were performed. METHODS: The Dacron graft (3 mm in diameter, 3 cm in length) were treated with LK via two dif…

Electrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applicationsHemostasis and retained surgical items

Melt strength of calcium carbonate filled polypropylene melts

Nhol Kao、Arnab Chandra、Sati N. Bhattacharya2002-12-01Polymer International

Abstract This paper investigates the extensional rheology (through melt strength measurement) of calcium carbonate (CaCO 3 ) filled polypropylene (PP) melts. Different concentrations of CaCO 3 filled PP were produced by mixing two master batches of pure PP and 70 wt% CaCO 3 filled PP in required proportions in a count…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Sensitivity analysis of grating parameter estimation

C. Logofatu2002-12-01Applied Optics

An optimization method for the sensitivity of diffraction efficiency measurements is presented. I define the sensitivity as the estimation precision of the grating parameters. The optimization method called sensitivity analysis for fitting scans all the possible measurement configurations and selects the configuration…

Optical measurement and interference techniquesAdvancements in Photolithography TechniquesOptical Coatings and Gratings

Thermotropic liquid crystalline behaviour of piperazinium and homopiperazinium alkylsulphates

Aspasia Nikokavoura、Dimitris Tsiourvas、Michael Arkas 等 5 位作者2002-12-01Liquid Crystals

A series of 1,4-piperazinium di-n-alkyl sulphates was synthesized and compared with an analogous series of 1,5-homopiperazinium di-n-alkyl sulphates. Their thermotropic liquid crystalline behaviour was studied by differential scanning calorimetry, polarizing optical microscopy and X-ray diffraction. For the piperazini…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

MOLECULAR AND MORPHOLOGICAL DATA IDENTIFY A CRYPTIC SPECIES COMPLEX IN ENDOPHYTIC MEMBERS OF THE GENUS COLEOCHAETE BRÉB. (CHAROPHYTA: COLEOCHAETACEAE)1

Matthew T. Cimino、Charles F. Delwiche2002-12-01Journal of Phycology

The genus Coleochaete Bréb. is a relatively small group of freshwater microscopic green algae with about 15 recognized species. Although Coleochaete has long been considered to be a close relative of embryophytes, a comprehensive study of the genus has not been published since Pringsheim's 1860 monograph. As part of a…

Marine and coastal plant biologyDiatoms and Algae ResearchBiocrusts and Microbial Ecology

Dielectric Response of Aramid Fiber‐Reinforced PEEK

Nina Korbakov、H. Harel、Yuri Feldman 等 4 位作者2002-12-01Macromolecular Chemistry and Physics

Abstract Dielectric spectroscopy was applied for the first time to aramid fiber‐reinforced PEEK, wherein the effect of the fiber on the dielectric response was examined for both amorphous and crystalline poly(ether ether ketone) (PEEK) over wide temperature and frequency ranges. Whereas the temperature behavior of the…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

Vitrifying star-shaped liquid crystals: synthesis and application in cholesteric polymer networks

Thomas Pfeuffer、Doris Hanft、Peter Strohriegl2002-12-01Liquid Crystals

In this paper, the formation of glass-forming reactive mesogens, that do not crystallize upon cooling, but vitrify and form supercooled LC phases, is described. These molecules exhibit broad range LC phases and enable us to carry out photopolymerization in a broad range of temperatures. From such reactive mesogens den…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Zinc runoff from galvanised steel materials exposed in industrial/marine environment

James Sullivan、David Worsley2002-12-01British Corrosion Journal

An investigation has been carried out to assess the zinc runoff from a variety of galvanised materials over 16 months at the industrial/marine Port Talbot weathering site. Over 16 months of exposure, bare zinc, and Electrozinc have the highest levels of zinc runoff (4·38 and 4·20 g m-2) followed by general galvanised…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityEnvironmental Chemistry and Analysis

Reaction Synthesis of Aluminum Nitride–Boron Nitride Composites Based on the Nitridation of Aluminum Boride

Guojun Zhang、Jianfeng Yang、Motohide Ando 等 4 位作者2002-12-01Journal of the American Ceramic Society

Aluminum nitride–boron nitride (AlN–BN) composites were prepared based on the nitridation of aluminum boride (AlB 2 ). AlN powder was added to change the BN volume fraction in the obtained composites. Thermogravimetry–differential thermal analysis (TG‐DTA), X‐ray diffractometry, and the nitridation ratio were used to…

Advanced ceramic materials synthesisBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials