Materials Literature
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Passive layers on cobalt were prepared under potentiostatic control in borate buffer pH 9.3 and examined with x-ray photoelectron spectroscopy (XPS). The electrochemical preparation of the sputter-cleaned samples and their transfer to the ultrahigh vacuum was performed in a closed system under protection of purified a…
Interaction parameter, A, proposed in Yamashita-Kurosawa's theory of dielectric constant, has been calculated for numerous binary oxide glasses on the basis of polarizability of oxide ion determined from refractive index. It has been established that the interaction parameter is closely related to the oxide ion polari…
The subnitride Ca2N has been prepared via several synthetic routes described for the first time, including reduction of Ca3N2 and reaction of Ca metal dissolved in liquid sodium with nitrogen gas. Products have been characterised by powder X-ray and powder neutron diffraction. Crystallite morphology and compound stoic…
Highly ordered hexagonal silica/block copolymer mesostructured composites have been prepared using syntheses with fluoride over a wide range of pH conditions (pH 0–9), by controlling the rates of hydrolysis and condensation of the tetramethoxysilane silica source.
Liquefaction of the bark of Acacia mearnsii (BK) and cornstarch (CS) was conducted by using a solvent mixture consisting of poly(propylene glycol) (PPG), glycerol, and sulfuric acid with a weight fraction of 94/5/1 at 150°C. Solubilities of BK and CS were about 80% after 60 min and 100% after 20 min in the same solven…
Nucleation and growth mechanism of polypyrrole films was investigated on vapor deposited gold/highly oriented pyrolytic graphite by current‐time transient ( i‐t ) measurements and atomic force microscopy. It was found that the nucleation and growth was an instantaneous two‐dimensional process before nuclei overlapping…
A porphyrin-capped molecular clip epoxidises olefins, depending on the axial ligand used, with enhanced activity or stability
We have studied the effect of magnetostatic interactions on the overall shape of hysteresis loops for arrays of single domain particles. A computational model was used to calculate major hysteresis loops of arrays of particles with an easy axis along the applied field. The shear of the hysteresis loop, and consequent…
Thin films of MgO were deposited by atomic layer epitaxy (ALE) from bis(cyclopentadienyl)magnesium and water using soda lime glass and Si(100) as substrates. Deposition parameters were studied in the temperature range of 100–400 °C. A plateau of surface-controlled growth was observed at 200–300 °C with a growth rate o…
Mechanical and dynamic mechanical properties of a waste rubber powder-filled high-density polyethylene (HDPE) composite are investigated. Rubber powder is surface-modified with acrylamide (AAm) using ultraviolet. Rubber powder and HDPE are extruded using a single-screw extruder and maleic anhydride-grafted polypropyle…
As far as the flame-retardant polyester fibers are concerned, the copolymerization of phosphorus retardants is the most common method. But a serious problem is that the phosphorus-containing polymer is easily hydrolyzed. We investigated the flame retardancy and the hydrolysis properties of two poly(ethylene terephthal…
The equation of state for expansion of detonation gas together with a model for gas flow through fracturing solid is proposed and implemented into the combined finite-discrete element code. The equation of state proposed enables gas pressure to be obtained in a closed form for both reversible and irreversible adiabati…
Two series of polyurethanes were prepared to investigate the effect of comacrodiol structure on properties and morphology of polyurethanes based on the siloxane macrodiol, α,ω-bis(6-hydroxyethoxypropyl) polydimethylsiloxane (PDMS). All polyurethanes contained a 40 wt % hard segment derived from 4,4′-methylenediphenyl…
A variety of new polymeric materials ranging from soft rubbers to hard, tough, and brittle plastics were prepared from the cationic copolymerization of regular soybean oil, low saturation soybean oil (LoSatSoy oil), or conjugated LoSatSoy oil with styrene and divinylbenzene initiated by boron trifluoride diethyl ether…
Two phosphorus-containing diacids were synthesized from 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) and either maleic acid or itaconic acid and then reacted with diglycidyl ether of bisphenol A (DGEBA) to form two series of advanced epoxy resins. Reaction conditions, such as reaction time, temperature an…
Double-layer capacitors are a recent technology based on the well-known electrochemical phenomenon of extremely high capacitance/unit area in an electrode-electrolyte interface and the high surface area achievable in activated carbon fibers. Capacitances are available in the range of a few farads to a few hundred fara…
Phase-type gratings formed by photochemical phase transitions of a polymer azobenzene liquid crystal have been characterized. The sensitivity of the material was improved by a factor of 23 in the liquid-crystalline phase owing to effective induction of the photochemical phase transition in the bright fringes of the in…
Pseudomonas oleovorans (ATCC 29347) was grown in batch and chemostat cultures with citrate, hexanoate, heptanoate, octanoate, and nonanoate as single carbon substrates. The growth medium for batch cultures was adjusted such that nitrogen (NH(4)(+)) limitation terminated the exponential-growth phase. During batch culti…
Tissue engineering has been applied to various tissues, and particularly significant progress has been made in the areas of skin, cartilage, and bone regeneration. Inclusion of bioactive factors into the synthetic scaffolds has been suggested as one of the possible tissue engineering strategies. The growth factors are…
Manganese-exchanged Al-MCM-41 modified by the chiral salen ligand [(R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)cyclohexane-1,2-diamine] has been investigated as a heterogeneous catalyst for the enantioselective epoxidation of (Z)-stilbene using iodosylbenzene as oxygen donor, with particular interest in the effec…