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Quantitative Relationship between Carbonated Apatite Metastable Equilibrium Solubility and Dissolution Kinetics

Jer Hsu、Jeffrey L. Fox、G. Lynn Powell 等 8 位作者1994-12-01Journal of Colloid and Interface Science

The purpose of this study was to compare the experimental dissolution rates of carbonated apatite (CAP) pellets in acidic acetate buffers under a variety of conditions with theoretical predictions. The theoretical predictions were made in the following way. Recently obtained data on metastable equilibrium solubility (…

Calcium Carbonate Crystallization and InhibitionCrystallization and Solubility StudiesThermal and Kinetic Analysis

Mikasaite, (Fe3+, Al)2(SO4)3, a new ferric sulphate mineral from Mikasa city, Hokkaido, Japan

Hiroyuki Miura、Kiyoaki Niida、Tadao Hirama1994-12-01Mineralogical Magazine

Abstract The new ferric sulphate mineral, mikasaite, the Fe analogue of millosevichite was found in Ikushunbe tsu, Mikasa city, Hokkaido, Japan. Mikasaite occurs as a sublimate around fractures from which coal gas escapes. The white-light brown coloured mineral shows aggregates of fine porous crystals. The SEM microgr…

Clay minerals and soil interactionsMine drainage and remediation techniquesCoal and Its By-products

X-ray topographic and optical imaging studies of synthetic diamonds

A. R. Lang1994-12-01Journal of Applied Crystallography

Large synthetic diamonds grown by the reconstitution method, all exhibiting the growth forms {100}, {111}, {110} and {113}, were studied. Crystal perfection was assessed by X-ray topography using a conventional source of Cu Kα1 radiation and employing the section, projection and limited-projection topographic techniqu…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchAdvanced materials and composites

Microstructure and Crystallinity of N-Type Porous Silicon

Kuniko Takemoto、Yoshio Nakamura、Osamu Nittono1994-12-01Japanese Journal of Applied Physics

Microstructure and crystallinity of a porous silicon (PS) layer formed on a highly doped n-type silicon substrate were examined in detail, and the luminescent nature of the PS layer was also studied qualitatively. A layered pore structure developed after about 3000 s of anodization, and pore morphology became simpler…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Statistical mechanical theory for liquid‐crystalline polymer solutions

Takahiro Sato、Akio Teŕamoto1994-12-01Acta Polymerica

Abstract A statistical mechanical theory is presented for liquid‐crystalline polymer solutions, where the liquid‐crystalline polymer is regarded as a wormlike spherocylinder interacting by the hard‐core repulsion and a soft (attractive or electrostatic) interaction with other spherocylinders. The theory is based on th…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Microstructure and Fracture Toughness of Hot‐Pressed Silicon Carbide Reinforced with Silicon Carbide Whisker

Dong‐Han Lee、Hyoun‐Ee Kim、Seong‐Jai Cho1994-12-01Journal of the American Ceramic Society

The effects of β‐SiC whisker addition on the microstructural evolution and fracture toughness ( K IC ) of hot‐pressed SiC were investigated. Most of the whiskers added disappeared during the densifcation process by transformation into the α‐phase. The remaining whiskers acted as nuclei for grain growth, resulting in t…

Advanced ceramic materials synthesisSilicon Carbide Semiconductor TechnologiesAluminum Alloys Composites Properties

SEM-EDS Investigations of Self-Phosphating Coatings

Li Li、Chhiu-Tsu Lin1994-12-01Industrial & Engineering Chemistry Research

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSEM-EDS Investigations of Self-Phosphating CoatingsLi Li and Chhiu-Tsu LinCite this: Ind. Eng. Chem. Res. 1994, 33, 12, 3241–3246Publication Date (Print):December 1, 1994Publication History Published online1 May 2002Published inissue 1 December 1994https://pubs.acs.org/doi/1…

Corrosion Behavior and InhibitionHigh-Temperature Coating BehaviorsCopper Interconnects and Reliability

On the Effect of Organic Substitution of Silicon Alkoxides in Poly(Vinyl Acetate) Organic-Inorganic Composites

Christine J. T. Landry、Bradley K. Coltrain1994-12-01Journal of Macromolecular Science Part A

Organic-inorganic composites (OICs) were prepared via the in-situ polymerization of an organically (phenyl) substituted trialkoxysilane, phenyltriethoxysilane (PhTEOS), in the presence of poly(vinyl acetate) (PVAc). The mechanical reinforcement above T g previously observed in OICs of unfunctionalized organic polymers…

Analytical Chemistry and SensorsMarine Biology and Environmental ChemistrySilicone and Siloxane Chemistry

Determination of white K-mica polytype ratios; comparison of different XRD methods

M. Dalla Torre、W. B. Stern、Michel Frey1994-12-01Clay Minerals

Six different X-ray diffraction (XRD) methods for determining the relative amounts ofM 1 and 1M white K-mica polytypes were compared. Unoriented samples of different concentrations of the two polytypes were prepared using the technique described by Handschin & Stern (1989) and Stern (1991). An evaluation of different…

Concrete and Cement Materials ResearchSoil and Unsaturated FlowClay minerals and soil interactions

A Study of Thread Tensions on a Lockstitch Sewing Machine (Part III): Further Stitch Formation Analysis

Fernando Ferreira、S.C. Harlock、P. Grosberg1994-12-01International Journal of Clothing Science and Technology

The purpose of this investigation was to try to develop a theoretical model to satisfy and explain the interaction between the needle and bobbin threads, the tensions developed and their influence on seam balance. An explanation of the conditions determining seam balance is proposed based on a “robbing back” theory of…

Textile materials and evaluations

Effect of rare earth elements on microstructure and properties of high chromium white iron

M. Radulović、M. Fiset、K. Peev1994-12-01Materials Science and Technology

The influence of rare earth elements, such as cerium, lanthanum, and neodymium, on the microstructure and properties of high chromium white cast iron are examined. It has been demonstrated that rare earth elements can change the microstructural characteristics of white iron containing 18 wt-%Cr and that these elements…

Microstructure and Mechanical Properties of SteelsMetal Alloys Wear and PropertiesPowder Metallurgy Techniques and Materials

Effect of Heterogeneous Secondary Pyrolysis Reactions on the Thermal Decomposition of Polyurethane Scrap

Dawn Y. Takamoto、Mark A. Petrich1994-12-01Industrial & Engineering Chemistry Research

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffect of Heterogeneous Secondary Pyrolysis Reactions on the Thermal Decomposition of Polyurethane ScrapDawn Y. Takamoto and Mark A. PetrichCite this: Ind. Eng. Chem. Res. 1994, 33, 12, 3004–3009Publication Date (Print):December 1, 1994Publication History Published online1 M…

Flame retardant materials and properties

Effect of Heating Rate on the Dielectric Properties of the PMN‐PT Relaxor Ceramics

Yi‐Cheng Liou、Long Wu1994-12-01Journal of the American Ceramic Society

The effect of heating rate (2 to 30°C/min) during sintering on the perovskite phase content, density, microstructure, and dielectric properties of 0.9PbMg 1/3 Nb 2/3 O 3 –0.1PbTiO 3 relaxor ferroelectric ceramics has been studied. Increasing the heating rate reduced the level of PbO evaporation and resulted in high pe…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Interaction of slip dislocations with the (0112) twin interface in zinc

S. Lay、G. Nouet1994-12-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

The interaction of slip dislocations with the (012) twin interface in zinc has been investigated using transmission electron microscopy. Several processes have been pointed out: slip transfer across the grain boundary, dissociation into secondary dislocations and reaction with interfacial dislocations. Moreover, the s…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsMagnesium Alloys: Properties and Applications

Absolute differential cross sections for the excitation of molecular oxygen by electron impact: Decomposition of the Schumann-Runge continuum

T. W. Shyn、Christopher J. Sweeney、Alan Grafe 等 4 位作者1994-12-01Physical Review A

Using a crossed-beam method, we have measured electron-energy-loss spectra for the excitation of the Schumann-Runge continuum of molecular oxygen. The scattering angle and electron-impact energy ranges covered were 12\ifmmode^\circ\else\textdegree\fi{}--156\ifmmode^\circ\else\textdegree\fi{} and 15--50 eV, respectivel…

Diamond and Carbon-based Materials ResearchAtomic and Molecular PhysicsPorphyrin and Phthalocyanine Chemistry

Dehydrogenation of Ethylbenzene over Spinel Oxides

N. John Jebarathinam、Muthusamy Eswaramoorthy、Vengaimuthu Krishnasamy1994-12-01Bulletin of the Chemical Society of Japan

Abstract NiCr2O4, ZnCr2O4, CuCr2O4, CuAl2O4, and CuFe2O4 were prepared and characterized by XRD, DRS, and IR and by measurements of surface area, acidity, and electrical conductivity. XRD analysis indicates, that chromites, aluminate, and ferrite have normal, partially inversed, and inversed spinel structure, respecti…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Verdoheme-like Oxaporphyrin Formation by Oxygenation of a Co(II) Porphyrinyl Naphthoic Acid. A New Model of Heme Degradation

Chi K. Chang、Gladys Avilés、Nilkamal Bag1994-12-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTVerdoheme-like Oxaporphyrin Formation by Oxygenation of a Co(II) Porphyrinyl Naphthoic Acid. A New Model of Heme DegradationC. K. Chang, Gladys Aviles, and Nilkamal BagCite this: J. Am. Chem. Soc. 1994, 116, 26, 12127–12128Publication Date (Print):December 1, 1994Publication…

Porphyrin and Phthalocyanine ChemistryHeme Oxygenase-1 and Carbon MonoxidePorphyrin Metabolism and Disorders

Synthesis of polytitanosiloxanes and their transformation to SiO2–TiO2 ceramic fibers

Takahiro Gunji、Iis Sopyan、Yoshimoto Abe1994-12-01Journal of Polymer Science Part A Polymer Chemistry

Abstract A one‐pot synthesis of polytitanosiloxanes (PTS) and its transformation to SiO 2 –TiO 2 ceramic fibers were investigated. PTS was prepared by the hydrolysis of tetraethoxysilane followed by the reaction with bis(2,4‐pentanedionato)titanium diisopropoxide in methanol in 33–95 SiO 2 mol %. PTS was considered to…

Dental materials and restorationsSilicone and Siloxane ChemistryPhotopolymerization techniques and applications

Molecular Orientation and Surface Morphology in Methyl Iodide Films Grown on MgO(100) Probed by Photodissociation

D. Howard Fairbrother、Kimberly A. Briggman、Peter C. Stair 等 4 位作者1994-12-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMolecular Orientation and Surface Morphology in Methyl Iodide Films Grown on MgO(100) Probed by PhotodissociationD. Howard Fairbrother, K. A. Briggman, P. C. Stair, and Eric WeitzCite this: J. Phys. Chem. 1994, 98, 49, 13042–13049Publication Date (Print):December 1, 1994Publ…

Advanced Chemical Physics StudiesAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Electrical conductivity in iodine‐doped ethyl cellulose

P. K. Khare、J. M. Keller、M. S. Gaur 等 5 位作者1994-12-01Polymer International

Abstract The electrical conductivity of solution‐grown ethyl cellulose (EC) films, 5–30 μm thick, has been studied in the sandwich configuration (metal–EC–metal) as a function of iodine concentration from 0.5 to 5.0 wt% ratio. The studies were conducted in the temperature range 333–383 K, while the field was varied ov…

Thin-Film Transistor TechnologiesConducting polymers and applicationsAnalytical Chemistry and Sensors