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Effect of Surfactants on Phosphogypsum Crystallization and Filtration during Wet-Process Phosphoric Acid Production

H. El‐Shall、E.A. Abdel‐Aal、Brij M. Moudgil2000-01-03Separation Science and Technology

A nonionic surfactant (CMR-100) containing a mixture of C6–C22 sorbitan esters was tested to improve the filtration rate of phosphogypsum produced from a South Florida phosphate concentrate at different sulfate levels. Tests were carried out on a lab-scale under operating conditions that simulate, to a large extent, t…

Calcium Carbonate Crystallization and InhibitionMinerals Flotation and Separation TechniquesMine drainage and remediation techniques

Mechanical characterization of closed-cell polyolefin foams

M. A. Rodr�guez-P�rez、José Ignácio Velasco、D. Arenc�n 等 5 位作者2000-01-03Journal of Applied Polymer Science

Three different experimental techniques [compression experiments at low strain rates, instrumented falling-weight impact tests, and dynamic mechanical analysis (DMA)] have been used for the mechanical characterization of a collection of crosslinked closed-cell polyolefin foams of different chemical compositions, densi…

Cellular and Composite StructuresPolymer composites and self-healingPolymer Foaming and Composites

Advances in Oxide-Oxide CMC

Robert A. Jurf、Steven C. Butner2000-01-03Journal of Engineering for Gas Turbines and Power

Recent advances in COI’s oxide–oxide CMC materials will be presented including basic processing steps, updated material properties, and fabrication techniques. Material properties of COI’s alumino-silicate system reinforced with various oxide fabrics will be compared, along with progress in developing a 1200°C oxide m…

Advanced ceramic materials synthesis

Synthesis and characterization of a thiourea derivative of chitosan for platinum recovery

Eric Guibal、Thierry Vincent、Ricardo Navarro2000-01-03Journal of Applied Polymer Science

Chitosan is effective at removing platinum from dilute solutions, but sorption properties are significantly affected by the presence of competitor anions, such as chloride and, especially, sulfate anions. Sorption capacities in such complex solutions are enhanced by grafting thiourea through glutaraldehyde linkage. Th…

Polymer Surface Interaction StudiesExtraction and Separation ProcessesRecycling and Waste Management Techniques

Full Load and Part-Load Performance Prediction for Integrated SOFC and Microturbine Systems

Stefano Campanari2000-01-03Journal of Engineering for Gas Turbines and Power

During the last years, two new subjects among the others have raised interest in the field of small scale electric power generation: advanced microturbines and solid oxide fuel cells. This paper investigates the thermodynamic potential of the integration of the solid oxide fuel cell technology with microturbine system…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsThermodynamic and Exergetic Analyses of Power and Cooling Systems

Ordered Two-Dimensional Monolayers of Au55 Clusters

Günter Schmid、Monika Bäumle、Norbert Beyer2000-01-03Angewandte Chemie International Edition

Simply dipping polyethyleneimine-modified surfaces into aqueous solutions of acid-functionalized Au55 clusters generates two-dimensional hexagonal and cubic arrangements of the clusters. The picture shows the transmission electron micrograph of the cubic arrangement; the bar length corrsponds to 10 nm.

Machine Learning in Materials ScienceNanocluster Synthesis and ApplicationsInorganic Chemistry and Materials

Properties of segmented polyurethanes derived from different diisocyanates

Da‐Kong Lee、Hong‐Bing Tsai2000-01-03Journal of Applied Polymer Science

Various segmented polyurethane materials with a polyurethane hard segment (HS) content of 40 wt % were prepared by bulk polymerization of a poly(tetramethylene ether) glycol with Mn of 2000, 1,4-butanediol, and various diisocyanates. The diisocyanates used were pure 4,4′-diphenylmethane diisocyanate (MDI), 2,4-toluene…

Polymer composites and self-healingEpoxy Resin Curing ProcessesPhotopolymerization techniques and applications

Ordered Two-Dimensional Monolayers of Au55 Clusters

Günter Schmid、Monika Bäumle、Norbert Beyer2000-01-03Angewandte Chemie International Edition

Simply dipping polyethyleneimine-modified surfaces into aqueous solutions of acid-functionalized Au(55) clusters generates two-dimensional hexagonal and cubic arrangements of the clusters. The picture shows the transmission electron micrograph of the cubic arrangement; the bar length corrsponds to 10 nm.

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsSurface Chemistry and Catalysis

Antiferromagnetic Coupling in a Gadolinium(III) Semiquinonato Complex

Andréa Caneschi、Andrea Dei、Dante Gatteschi 等 5 位作者2000-01-03Angewandte Chemie International Edition

The strongest antiferromagnetic coupling to Gd(III) so far reported was found for the complex [Gd(Hbpz(3))(2)(dtbsq)] small middle dot2 CHCl(3) (1; Hbpz(3)=hydrotris(pyrazolyl)borate; dtbsq=3,5-di-tert-butylsemiquinonato; see structure). At 245 K the magnetic susceptibility of 1 is lower than expected for two uncorrel…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryLanthanide and Transition Metal Complexes

A Metamagnetic Two-Dimensional Molecular Material with Nickel(II) and Azide

Montserrat Monfort、I. Resino、Joan Ribas 等 4 位作者2000-01-03Angewandte Chemie International Edition

Bridging azido ligands transmit both ferro- and antiferromagnetic interactions. The sheetlike structured complex [Ni(µ-N(3))(2)(N,N-Et(2)-N'-Me-en)](n) (see picture) exhibits a range of magnetic behaviors at low temperature. Short-range ferromagnetic and three-dimensional antiferromagnetic ordering compete, giving met…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research

Biomechanical Properties of Skin

Maurice Morad Khosh and Wayne F. Larrabee, Jr.2000-01-03OpenAlex

Epidermis has a thickness of 0.07 to 1.4 mm and serves to protect the body surface against physical and ultraviolet injury, to provide a barrier to water and chemicals, and to resist microbial penetration. The presence of disulfide bonds within the keratin layer and the desmosomal attachments between the epithelial ce…

Textile materials and evaluations

Advances in Homogeneous and Heterogeneous Catalysis with Metal-Containing Silsesquioxanes

Hendrikus C. L. Abbenhuis2000-01-03Chemistry - A European Journal

Metal-containing silsesquioxane derivatives provide new catalysts with both homogeneous and heterogeneous applicability. The steric and electronic properties of silsesquioxane silanolate ligands render metal centers more Lewis acidic than conventional alkoxide or siloxide ligands do. This concept has been exploited in…

Organometallic Complex Synthesis and CatalysisCatalysis and Hydrodesulfurization StudiesSilicone and Siloxane Chemistry

An asymptotic form of the reciprocity theorem with applications in x-ray scattering

Ariel Caticha2000-01-03arXiv

The emission of electromagnetic waves from a source within or near a non-trivial medium (with or without boundaries, crystalline or amorphous, with inhomogeneities, absorption and so on) is sometimes studied using the reciprocity principle. This is a variation of the method of Green's functions. If one is only interes…

Materials Sciencephysics.class-phphysics.ed-phphysics.gen-phphysics.optics

Polyurethane/conducting carbon black composites: Structure, electric conductivity, strain recovery behavior, and their relationships

Fengkui Li、Lanying Qi、Jiping Yang 等 6 位作者2000-01-03Journal of Applied Polymer Science

The polyurethane composites with conducting carbon black (CB) were prepared by a solution-precipitation process, which was followed by melt compression molding. The polyurethane used has good shape memory effect. The morphology of CB fillers in polyurethane matrix and the resulting conductivity of the composites were…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsPolymer composites and self-healing

Self-ordered pore structure of anodized aluminum on silicon and pattern transfer

David T. Crouse、Yu‐Hwa Lo、A. E. Miller 等 4 位作者2000-01-03OpenAlex

A practical approach of transferring a hexagonal array of nanosized pores produced in porous alumina into silicon and other substrates is discussed. The alumina pores have dimensions of 25–250 nm pore diameters and 50–300 nm pore spacings depending on the anodization conditions used. The characteristics of the alumina…

Photonic Crystals and ApplicationsAnodic Oxide Films and NanostructuresSmart Materials for Construction

Intrinsic Ferroelectric Coercive Field

Stephen Ducharme、V. M. Fridkin、A. V. Bune 等 7 位作者2000-01-03OpenAlex

The Landau-Ginzburg theory of ferroelectricity predicts the intrinsic coercive field for polarization reversal, but the observed extrinsic coercive field is always much smaller as a result of nucleation, dynamic processes not covered by the static theory. We have realized the intrinsic coercive field for the first tim…

Ferroelectric and Piezoelectric MaterialsLiquid Crystal Research AdvancementsMaterial Dynamics and Properties

Validation of Nannfeldt's ordinal name Helotiales

R P Korf、Pavel Lizoň2000-01-01Mycotaxon

The ordinal name Helotiales Nannfeldt, in common use for over 60 years, was not validly published, since it was based on an invalidly published family name, Helotiaceae Rehm.Rehm's family name has recently been conserved, but since the ordinal name is still technically incorrect, steps are taken here to validate it.

Diatoms and Algae ResearchPlant-based Medicinal ResearchHistorical Studies in Science

Mechanisms and Application of a Rapid Solid State Reaction at Fine Particle Interfaces with Atoms is Low-coordination States.

Mamoru Senna2000-01-01Journal of the Japan Society of Powder and Powder Metallurgy

Theoretical background of bridging bond formation of dissimilar metal atoms mediated by an oxygen atom is given for the system Ca(OH)2-SiO2. Physicochemical significance of low coordination state is emphasized in conjunction with higher reaction probability. A solid state addition reaction at room temperature is shown…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisElectronic and Structural Properties of Oxides

First-Principles simulations of ferroelectric oxides

A. V. Postnikov、R. I. Eglitis、Vasile Caciuc 等 4 位作者2000-01-01Ferroelectrics

Problematics, choice of adequate calculational scheme and obtained results in the first-principles simulations of potassium niobate (in different ferroelectric phases), pure and Li-doped potassium tantalate, and lithium niobate are discussed. The ferroelectric instability, zone-center TO phonons, and crystallographic…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsAcoustic Wave Resonator Technologies

Magnetic Materials and Semiconductors. Static Magnetic Field Analysis of DC Brushless Motor for Hard Disc Drive.

Takayuki Nishio、Takahiko Iriyama2000-01-01DENKI-SEIKO

It is necessary for material suppliers to know a relationship between specifications of device and those of materials used, in order to develop a suitable material for the target device. A computer simulation is one of the effective methods for this purpose. In this paper, an example of static magnetic field analysis…

Magnetic Properties of Alloys