Materials Literature
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[Co(2,9-dimethyl-1,10-phenanthroline)(solvent)4]2+ ([Co(neo)]2+) undergoes a significant decrease in symmetry to form an inner-sphere surface complex when grafted directly on performed silica or introduced during the sol-gel process. The visible and X-ray absorption spectra of the surface adducts are interpreted in te…
A modified approach to design Rotman (1963) type multiple beam forming lens has been proposed. The path length error at the wavefront has been calculated. The error obtained by the proposed approach and by the conventional approach has been compared. Two-dimensional electromagnetic field analysis of the lens obtained…
We have investigated the effects of oxygen annealing on the transport properties and surface microstructures of epitaxial La 0.8 Ba 0.2 MnO 3 (LBMO) films deposited on SrTiO 3 substrate at different oxygen pressures using the pulsed laser deposition technique. The thickness dependence of the transport properties was s…
We present a set of equations for a bulk ferromagnetic hysteresis model. We establish the connection between this set of equations and classical energy loss expressions for ferromagnetic hysteresis. We show analytically that for periodic inputs the system of equations has a limit set that is a periodic orbit in the H-…
The meta-dinitrobenzene crystal structure has been determined at five temperatures in the 100-300 K temperature range. The thermal expansion coefficients have been calculated from the temperature variation of the lattice parameters. Rigid-body motion analysis with allowance for large-amplitude internal motions provide…
The metastable orange crystals of HgI(2) comprise three different crystal structures, all of which are built from corner-linked Hg(4)I(10) supertetrahedra. Two of them are end members with the maximum degree of order (MDO) of a polytypic layer structure; the third shows a three-dimensional linkage. This paper presents…
A new nonionic water-soluble fluorescent conjugated polymer is reported with hydroxyl and amide side chains surrounding an aromatic polymer backbone.
A rigid-ion lattice-dynamical treatment accounts reasonably well for most of the atomic displacement parameters (ADPs) reported in the literature for a synthetic sample of spessartine Mn(3)Al(2)Si(3)O(12); the model accounts less well for the ADPs of the Mn atom. These results are similar to those obtained for the cor…
Coplanar transmission lines were fabricated on porous silicon layers of varying thickness, in the range of 1-15 /spl mu/m, on silicon substrates. For suitably thick porous silicon regions, the capacitive coupling to the conducting silicon substrate and the associated attenuation are suppressed. The use of porous silic…
The incommensurately modulated structure of Sr(2)Nb(2)O(7) at room temperature is reported, as determined by single-crystal X-ray diffraction. The crystal structure of Sr(2)Nb(2)O(7) comprises slabs with a perovskite-type structure that are separated by planes of additional O atoms. The driving force for the modulatio…
Reformatsky reactions of a phenyl ketone, an alpha-bromoester, zinc dust, and a catalytic amount of iodine in dioxane under high-intensity ultrasound (HIU) irradiation from an ultrasonic probe give high yields of beta-hydroxyesters in short reaction times. A series of alkyl phenyl ketones with increasing steric demand…
The novel two-dimensional iron(II) compound of formula {[Fe2(bpym)(ox)2]·5H2O}n (1) [bpym = 2,2′-bipyrimidine and ox = oxalate dianion] is obtained by reaction of oxalic acid, iron(II) chloride and 2,2′-bipyrimidine in aqueous solution. The structure of 1 is made up of oxalato-bridged iron(II) chains cross-linked by b…
Nona-alkanoyloxy tribenzocyclononene (CTV-n, where n is the number of carbons in the side chains) were prepared for n = 2 to 14. The homologues of this series appear in two stable isomeric forms, rigid crown and flexible saddle. We report on their isomerization equilibria and dynamics in solution and on their mesomorp…
The chemical and thermal stability of several solid acid compounds under fuel cell operating conditions has been investigated, primarily by thermogravimetric methods. Thermal decomposition of CsHSO 4, a material which has shown promise as an alternative electrolyte for proton exchange membrane (PEM) fuel cells, initia…
Using θ–2θ and grazing incidence synchrotron X-ray diffraction experiments, the domain of existence of the different phases is established for spin-coated mesoporous silica films as a function of the surfactant/Si molar ratio and the condensation rate of the initial silica sol. These phases derive from three different…
Polar structures with pseudosymmetry related to a hypothetical non-polar configuration are considered as good candidates for ferroelectrics. Recently, a procedure has been developed for a systematic pseudosymmetry search among structures with a given space-group symmetry. The aim of this paper is the extension of the…
Mechanical recycling of plastics from waste from electrical and electronical equipment (WEEE) is increasingly expected by regulators and demanded by original equipment manufacturers (CEMs); however, mechanical recycling is generally recognized to be the most economically costly and technically challenging method of re…
A wet chemical route is developed for the preparation of Sr2CeO4 denoted the carbonate-gel composite technique. This involves the coprecipitation of strontium as fine particles of carbonates within hydrated gels of ceria (CeO2·xH2O, 40 < x < 75) by the addition of ammonium carbonate. During calcination, CeO2·xH2O dehy…
In this paper, different arc furnace methods are reviewed for the purpose of harmonic analysis. In general, these models may be classified into time domain method and frequency domain method. The difference between these two methods is discussed and evaluated. In this paper, six typical arc furnace models from the tim…
Reaction of poly(succinimide) with a mixture of 5-aminopentanol and 6-aminohexanol produced new thermoresponsive polymers based on biodegradable poly(amino acids)s, poly(N-substituted alpha/beta-asparagine)s, showing a clear LCST in water.