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Recommendations and supporting information on the choice of zirconium oxidation models in severe accident codes

G. Schanz2003-01-01Repository KITopen (Karlsruhe Institute of Technology)

Fuel rod cladding oxidation is one of the key aspects of the accidental behaviour of LWR fuel elements, and a comprehensive base of experimental information on its kinetics is available. However, the conventional treatment of zirconium oxidation kinetics in some severe accident (SA) codes is unsatisfactory compared to…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesRisk and Safety Analysis

STUDY OF OPTICAL BAND GAP OF ZINC-BORATE GLASSES

Muhammad Tanveer Altaf、Muhammad Ashraf Chaudhry、Maria Zahid2003-01-01OpenAlex

The present study deals with binary xZnO-(100-x)B2O3 (x=50-60%) and ternary yV2O5-50ZnO-(50-y)B2O3 (y=5-10%) glass systems. The mass density, oxygen packing density, molar volume and optical energy gap of these glasses were measured at room temperature. The density varies in the range of 2.92 - 3.57 g/cm 3 . The absor…

Glass properties and applicationsMaterial Science and Thermodynamics

Structure and Transport Properties of Ferroelastic Domain Walls in a SImple Model

William T. Lee、Ekhard K. H. Salje、U. Bismayer2003-01-01Phase Transitions

In the ferroelastic material WO3 it has been observed that diffusion of both sodium ions and oxygen vacancies occurs at an enhanced rate within twin domain walls. A number of explanations can be proposed for this result. Here we investigate how the structure of a ferroelastic domain wall can influence diffusion rates.…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

The Influence of Albumin on Corrosion Resistance of Titanium in Fluoride Solution

Katsuhisa Ide、Masayuki Hattori、Masao Yoshinari 等 5 位作者2003-01-01Dental Materials Journal

Proteins can interact with corrosion reactions in several ways. In this study, we investigated the effect of albumin on the corrosion resistance of titanium in the presence of fluoride. The effects of the NaF concentration, albumin concentration, and pH on the corrosion characteristics of commercially pure titanium (C…

Dental materials and restorationsCorrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metals

Effect of Tumble-drying on Selected Properties of Knitted and Woven Cotton Fabrics: Part II: Effect of Moisture Content, Temperature Setting, and Time in Dryer on Cotton Fabrics

L. Higgins、S.C. Anand、Michael E. Hall 等 4 位作者2003-01-01Journal of the Textile Institute

Specimens of a plain-woven cotton fabric and a plain single-jersey weft-knitted cotton fabric were washed and then tumble-dried for predetermined periods of time under three different temperature settings. Length and width shrinkage, wrinkling, mass of the whole specimen, and warp and weft yarn diameters were determin…

Dyeing and Modifying Textile FibersTextile materials and evaluationsColor perception and design

Synthesis and Conformation of Star‐Shaped Poly(γ‐benzyl‐L‐glutamate)s on a Cyclotriphosphazene Core

Kenzo Inoue、Shigeru Horibe、Makiko Fukae 等 6 位作者2003-01-01Macromolecular Bioscience

Abstract The preparation of star‐shaped poly( γ ‐benzyl‐ L ‐glutamate)s by the ring‐opening polymerization of N ‐carboxy anhydride γ ‐benzyl‐ L ‐glutamate (BLG‐NCA) with hexakis(4‐aminomethylphenoxy)‐ ( 4 ) and hexakis(4‐aminophenoxy)cyclotriphosphazenes ( 6 ), and the conformation of resulting polymers has been studi…

Luminescence and Fluorescent MaterialsDendrimers and Hyperbranched PolymersSynthesis and Characterization of Heterocyclic Compounds

Localized Corrosion Behavior of High Nitrogen-bearing Austenitic Stainless Steels in Seawater Environment

Masayuki Sagara、Yasuyuki Katada、Toshiaki Kodama2003-01-01ISIJ International

Crevice corrosion behavior of high nitrogen-bearing stainless steels with up to 1.1 mass% nitrogen were investigated in artificial seawater. Specimens were highly purified and contained ultra-high nitrogen of about 1 mass% obtained by using nitrogen gas pressurized electroslag remelting (P-ESR) system. 23%Cr-4%Ni-0 to…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsHydrogen embrittlement and corrosion behaviors in metals

Pressure control of enantiodifferentiating photoisomerization of cyclooctenes sensitized by chiral benzenepolycarboxylates. The origin of discontinuous pressure dependence of the optical yield

Masayuki Kaneda、Asao Nakamura、Sadayuki Asaoka 等 7 位作者2003-01-01Organic & Biomolecular Chemistry

Pressure effects on enantiodifferentiating geometrical photoisomerizations of (Z)-cyclooctene and (Z,Z)-cycloocta-1,5-diene sensitized by chiral benzene-1,2,4,5-tetracarboxylate were investigated over a pressure range of 0.1-750 MPa. Enantiomeric excesses (ee's) of the (E)- and (E.Z)-isomers obtained displayed discont…

Photochemistry and Electron Transfer StudiesPhotochromic and Fluorescence ChemistryOrganic Chemistry Cycloaddition Reactions

Using a novel plug flow reactor for the in situ, simultaneous, monitoring of SAXS and WAXD during crystallisation from solution

H. Alison、Roger J. Davey、John Garside 等 7 位作者2003-01-01Physical Chemistry Chemical Physics

The design and application of a novel plug flow crystalliser is described. Simultaneous collection of SAXS and WAXD during the nucleation and crystal growth of a small organic molecule from solution is reported. Preliminary data imply the separation of a non-diffracting phase prior to the appearance of crystalline sol…

Analytical Chemistry and ChromatographyInnovative Microfluidic and Catalytic Techniques InnovationCrystallization and Solubility Studies

DESTRUCTION OF VOLATILE ORGANIC COMPOUNDS BY CATALYTIC OXIDATION

Alice Oana Rusu、Emil Dumitriu2003-01-01Environmental Engineering and Management Journal

Volatile organic compounds, emitted by a lot of sources, particularly from gasoline engines of automobiles, are air pollutants that give rise to deleterious health and environmental effects.Total catalytic oxidation is an attractive method in controlling these emissions due the great amounts of energy saved, by the mo…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsWater Quality Monitoring and Analysis

Potential of chicken feather fibre in wood MDF composites

Jerold E. Winandy、James H. Muehl、Jessie A. Micales 等 5 位作者2003-01-01OpenAlex

We made a series of aspen fibre medium density fibreboard panels adding various levels of chicken feather fibre to determine the relative effect of the feather fibre-wood fibre mixtures on composite panel properties. Chicken feathers are a waste product left over after processing chickens for meat. The feather fibre a…

Natural Fiber Reinforced CompositesTextile materials and evaluationsMaterial Properties and Processing

Thermal and infrared spectroscopic studies on hydrogen-bonding interaction of biodegradable poly(3-hydroxybutyrate)s with natural polyphenol catechin

Bo Zhu、Jianchun Li、Yong He 等 6 位作者2003-01-01Green Chemistry

Thermal and infrared spectroscopic studies were performed on the hydrogen-bonding interaction in the blends of biodegradable atactic, highly syndiotactic and isotactic poly(3-hydroxybutyrate)s with catechin. From the analysis of Fourier-transform infrared spectra, it was found that the crystalline phase could greatly…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Phenol hydroxylation using Ti- and Sn-containing silicalites

Raweewan Klaewkla、Santi Kulprathipanja、Pramoch Rangsunvigit 等 5 位作者2003-01-01Chemical Communications

New bimetallic framework and non-framework titanium and tin silicalite have been investigated for phenol hydroxylation with H2O2 in different solvents, and the optimized catalyst composition showed 26% higher initial rate than reference TS-1.

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications

Miscibility of Chitosan and Poly(Ethylene Oxide) in Dilute Solution

Elvan Yılmaz、Noyan Erdenizci、O. Yılmaz2003-01-01International Journal of Polymer Analysis and Characterization

Miscibility of chitosan (CHI) with poly(ethylene oxide) (PEO) was studied in dilute solution by viscometry. Blends with CHI/PEO compositions of 0.1/0.9, 0.2/0.8, and 0.3/0.7 were studied at 25°, 30°, and 35°C, in a buffer solution of 0.1 M acetic acid/0.2 M sodium acetate. Starting with the classical Huggins equation,…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesPolymer Surface Interaction Studies

Mechanical properties and creep of Mg – rare earth – Sc – Mn squeeze cast alloys

Ivana Stulíková、Bohumil Smola、F. von Buch 等 4 位作者2003-01-01Materialwissenschaft und Werkstofftechnik

Abstract The microstructure developed during the T5 treatment of squeeze cast magnesium alloys containing rare earth (Gd, Y, or Ce, ≈ 3–10 wt.%), Sc (< 1 wt.%) and Mn (< 1.5 wt.%) is responsible for a reasonable age hardening in MgGdScMn alloys. Moderate age hardening is only possible in MgY4Sc1Mn1 or MgCe3Sc1Mn…

Magnesium Alloys: Properties and ApplicationsAluminum Alloys Composites PropertiesMetallurgical and Alloy Processes

Effect of drying history on swelling properties and cell attachment to oligo(poly(ethylene glycol) fumarate) hydrogels for guided tissue regeneration applications

Johnna S. Temenoff、Emilys. Steinbis、Antonios G. Mikos2003-01-01Journal of Biomaterials Science Polymer Edition

In these experiments, the effects of the drying history of hydrogels made from a novel polymer, oligo(poly(ethylene glycol) fumarate) (OPF) with two different poly(ethylene glycol) (PEG) molecular weights (approximately 920 (1K) and 9110 (10K) g/mol), were investigated. The hydrogels were either formed, dried and then…

Bone Tissue Engineering MaterialsHydrogels: synthesis, properties, applicationsElectrospun Nanofibers in Biomedical Applications

Copper Corrosion Monitoring with Total Internal Reflection Ellipsometry

Michal Poksinski、H. Dzuho、Hans Arwin2003-01-01Journal of The Electrochemical Society

A technique for in situ monitoring of changes on surfaces of semitransparent thin films is presented. This technique combines ellipsometry and total internal reflection and is called total internal reflection ellipsometry. It utilizes the high surface sensitivity of ellipsometry and can be applied to detect and quanti…

Optical Coatings and GratingsOptical Polarization and EllipsometrySurface Roughness and Optical Measurements

Structural-phase transformations in bentonite after acid treatment

М. Vlasova、G. Dominguez‐Patiño、N. G. Kakazey 等 6 位作者2003-01-01Science of Sintering

The methods of X-ray diffraction, Fourier transform infra-red spectroscopy (FTIR), X-ray microanalysis, electron microscopy, BET and cation exchange capacity (CEC) were used for investigation of the structural-phase transformations in bentonite under the influence of hydrochloric acid and temperature treatment (100-80…

Clay minerals and soil interactionsAdsorption, diffusion, and thermodynamic properties of materials

Effect of Heating Rate on Thermal Properties and Kinetics of Raw and Cleaned Coal Samples

Kazim Esber Özbas、Mustafa Verşan Kök2003-01-01Energy Sources

In this article, thermogravimetry (TG/DTG) was used to determine the effect of heating rate on the thermal properties and kinetics of raw and cleaned coal samples from Soma, Tunçbilek, and Afşin Elbistan regions. TG/DTG experiments were carried out at 4 different heating rates (5, 10, 15, and 20°C/min). Generally, for…

Thermochemical Biomass Conversion ProcessesCoal Properties and UtilizationThermal and Kinetic Analysis

EVALUATION OF FOAM FRACTIONATION COLUMN SCALE-UP FOR RECOVERING BOVINE SERUM ALBUMIN

Czarena Crofcheck、Katy Gillette2003-01-01Transactions of the ASAE

Foam fractionation is an adsorptive-bubble separation method that, according to researchers, is a feasibletechnique for the separation and/or concentration of proteins. The foam fractionation of bovine serum albumin (BSA) inlaboratory -scale foam fractionation columns (750 and 1250 mL) and the relationship between the…

Minerals Flotation and Separation TechniquesInnovative Microfluidic and Catalytic Techniques InnovationPickering emulsions and particle stabilization