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Luminescent Oil-Soluble Carbon Dots toward White Light Emission: A Spectroscopic Study

Annamaria Panniello、A. Evelyn Di Mauro、Elisabetta Fanizza 等 7 位作者2017-12-08The Journal of Physical Chemistry C

Carbon dots (C-dots) are emerging as new emitting nanomaterials for optoelectronics, bioimaging, and biosensing thanks to their high quantum yield (QY), biocompatibility, low toxicity, and cost-effective sources. Although the origin of their photoluminescence (PL) mechanism (i.e., their strong blue-green emission and…

Quantum Dots Synthesis And PropertiesCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Characterization and mechanical properties of cellulose acetate/carbon nanotube composite nanofibers

Ahmed Salama、Alaa Mohamed、Nada M. Aboamera 等 5 位作者2017-12-08Advances in Polymer Technology

Abstract Cellulose acetate/carbon nanotube composite nanofibers were prepared using electrospinning technique. The morphology, crystalline, and mechanical properties were characterized by scanning electron microscopy ( SEM ), transmission electron microscopy ( TEM ), X‐ray diffraction ( XRD ), Fourier transform infrar…

Advanced Sensor and Energy Harvesting MaterialsAdvanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical Applications

Meltwater Evolution during Defrosting on Superhydrophobic Surfaces

Fuqiang Chu、Xiaomin Wu、Lingli Wang2017-12-08ACS Applied Materials & Interfaces

Defrosting is essential for removing frost from engineering surfaces, but some fundamental issues are still unclear, especially for defrosting on superhydrophobic surfaces. Here, defrosting experiments on prepared superhydrophobic surfaces were conducted along with the investigation on meltwater evolution characterist…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferIcing and De-icing Technologies

Unraveling the Electronic Structure of Narrow Atomically Precise Chiral Graphene Nanoribbons

Néstor Merino‐Díez、Jingcheng Li、Aran García-Lekue 等 11 位作者2017-12-08The Journal of Physical Chemistry Letters

Recent advances in graphene-nanoribbon-based research have demonstrated the controlled synthesis of chiral graphene nanoribbons (chGNRs) with atomic precision using strategies of on-surface chemistry. However, their electronic characterization, including typical figures of merit like band gap or frontier band's effect…

Graphene research and applicationsTopological Materials and PhenomenaSurface Chemistry and Catalysis

Measurement of O and Ti atom displacements in TiO 2 during flash sintering experiments

Bola Yoon、Devinder Yadav、Rishi Raj 等 7 位作者2017-12-08Journal of the American Ceramic Society

Abstract In‐situ flash experiments on rutile TiO 2 were performed at the synchrotron at the Brookhaven National Laboratory. Pair distribution function analysis of total X‐ray scattering measurements yielded mean‐square atomic displacements of oxygen and titanium atoms during the progression of the 3 stages of flash. T…

Nuclear materials and radiation effectsElectronic and Structural Properties of OxidesX-ray Diffraction in Crystallography

Nanoplasmonic Alloy of Au/Ag Nanocomposites on Paper Substrate for Biosensing Applications

Moonseong Park、Charles Soon Hong Hwang、Ki‐Hun Jeong2017-12-08ACS Applied Materials & Interfaces

Plasmonic alloy has attracted much interest in tailoring localized surface plasmon resonance (LSPR) for recent biosensing techniques. In particular, paper-based plasmonic substrates allow capillary-driven lateral flow as well as three-dimensional metal nanostructures, and therefore they become actively transferred to…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesBiosensors and Analytical Detection

Role of Surface-Capping Ligands in Photoexcited Electron Transfer between CdS Nanorods and [FeFe] Hydrogenase and the Subsequent H2 Generation

Molly B. Wilker、James K. Utterback、Sophie Greene 等 7 位作者2017-12-08The Journal of Physical Chemistry C

Complexes of CdS nanorods and [FeFe] hydrogenase I from Clostridium acetobutylicum have been shown to photochemically produce H 2 . This study examines the role of the ligands that passivate the nanocrystal surfaces in the electron transfer from photoexcited CdS to hydrogenase and the H 2 generation that follows. We f…

Electrocatalysts for Energy ConversionQuantum Dots Synthesis And PropertiesMetalloenzymes and iron-sulfur proteins

Multimodal Kelvin Probe Force Microscopy Investigations of a Photovoltaic WSe2/MoS2 Type-II Interface

Yann Almadori、Nedjma Bendiab、Benjamin Grévin2017-12-08ACS Applied Materials & Interfaces

Atomically thin transition-metal dichalcogenides (TMDC) have become a new platform for the development of next-generation optoelectronic and light-harvesting devices. Here, we report a Kelvin probe force microscopy (KPFM) investigation carried out on a type-II photovoltaic heterojunction based on WSe 2 monolayer flake…

2D Materials and ApplicationsForce Microscopy Techniques and ApplicationsNanowire Synthesis and Applications

A DFT +Ustudy on structural, electronic, vibrational and thermodynamic properties of TiO2polymorphs and hydrogen titanate: tuning the Hubbard ‘U-term’

E. D. German、Ricardo Faccio、Álvaro W. Mombrú2017-12-08Journal of Physics Communications

Structural, electronic, vibrational and thermodynamic properties have been tested when Hubbard parameter U is implemented in density functional theory calculations for TiO 2 polymorphs: anatase, rutile, TiO 2 –B and for hydrogen titanate (H 2 Ti 3 O 7 ) bulk. Optimum U parameter values were found for each system, bala…

TiO2 Photocatalysis and Solar CellsThermal and Kinetic AnalysisNuclear materials and radiation effects

Probing defect dynamics in monolayer MoS2 via noise nanospectroscopy

Seung Hyun Song、Min‐Kyu Joo、Michael Neumann 等 5 位作者2017-12-08Nature Communications

Abstract Monolayer molybdenum disulfide (MoS 2 ) has received intense interest as a strong candidate for next-generation electronics. However, the observed electrical properties of monolayer MoS 2 exhibit several anomalies: samples universally exhibit unexpectedly low mobilities, n-type characteristics, and large cont…

2D Materials and ApplicationsNanowire Synthesis and ApplicationsMXene and MAX Phase Materials

One-way transport in laser-illuminated bilayer graphene: A Floquet isolator

Virginia Dal Lago、Eric Suárez Morell、L E F Foa Torres2017-12-08Physical review. B./Physical review. B

We explore the Floquet band structure and electronic transport in laser-illuminated bilayer graphene ribbons. By using a bias voltage perpendicular to the graphene bilayer we show how to get one-way charge and valley transport among two unbiased leads. In contrast to quantum pumping, our proposal uses a different mech…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Impact of the synthesis method on the solid-state charge transport of radical polymers

Yiren Zhang、Albert Park、Alicia Cintora 等 9 位作者2017-12-08Journal of Materials Chemistry C

Though poly(2,2,6,6-tetramethylpiperidinyloxy methacrylate) (PTMA) was reported to be conductive, careful measurements indicate its insulating nature regardless of synthesis method, which have implication for its application in organic electronics.

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

DA+ data acquisition and analysis software at the Swiss Light Source macromolecular crystallography beamlines

J.A. Wojdyla、Jakub W. Kamiński、Ezequiel Panepucci 等 7 位作者2017-12-08Journal of Synchrotron Radiation

Data acquisition software is an essential component of modern macromolecular crystallography (MX) beamlines, enabling efficient use of beam time at synchrotron facilities. Developed at the Paul Scherrer Institute, the DA+ data acquisition software is implemented at all three Swiss Light Source (SLS) MX beamlines. DA+…

Protein Structure and DynamicsMass Spectrometry Techniques and ApplicationsEnzyme Structure and Function

One-Pot Synthesis of MeAl2O4(Me = Ni, Co, or Cu) Supported on γ-Al2O3with Ultralarge Mesopores: Enhancing Interfacial Defects in γ-Al2O3To Facilitate the Formation of Spinel Structures at Lower Temperatures

Alexandre A. S. Gonçalves、Maria J. F. Costa、Liping Zhang 等 5 位作者2017-12-08Chemistry of Materials

High Resolution Image Download MS PowerPoint Slide Sintering is an important issue in creating crystalline metal oxides with high porosity and surface area, especially in the case of high-temperature materials such as metal aluminates. Herein we report a rationally designed synthesis of metal aluminates that diminishe…

Advanced ceramic materials synthesisCatalytic Processes in Materials ScienceMesoporous Materials and Catalysis

How Inter- and Intramolecular Processes Dictate Aggregation-Induced Emission in Crystals Undergoing Excited-State Proton Transfer

Michael Dommett、Miguel Rivera、Rachel Crespo‐Otero2017-12-08The Journal of Physical Chemistry Letters

Aggregation-induced emission (AIE) offers a route for the development of luminescent technologies with high quantum efficiencies. Excited-state intramolecular proton transfer (ESIPT) coupled to AIE can produce devices with emission across the visible spectrum. We use a combination of theoretical models to determine th…

Organic Light-Emitting Diodes ResearchPhotochemistry and Electron Transfer StudiesLuminescence and Fluorescent Materials

Sonochemical synthesis, structural inspection and semiconductor behavior of three new nano sized Cu(II), Co(II) and Ni(II) chelates based on tri‐dentate NOO imine ligand as precursors for metal oxides

Laila H. Abdel Rahman、Ahmed M. Abu‐Dief、Rafat M. El‐Khatib 等 6 位作者2017-12-08Applied Organometallic Chemistry

Three novel nanosized Cu(II), Co(II) and Ni(II) complexes of imine ligand attained from the condensation of 2‐amino‐3‐hydroxypyridine and 3‐methoxysalicylaldehyde have been prepared and investigated using diverse chemical methods such as NMR, CHN analysis, conductance, IR, Spectral studies, TGA and magnetic moment mea…

Conducting polymers and applicationsNonlinear Optical Materials ResearchCopper-based nanomaterials and applications

Plant Protein-Directed Synthesis of Luminescent Gold Nanocluster Hybrids for Tumor Imaging

Li Zhao、Haibao Peng、Jialin Liu 等 8 位作者2017-12-08ACS Applied Materials & Interfaces

Nowadays, fluorescence detection has emerged as one of the most frequently used noninvasive biosensing methods to selectively monitor biological processes within living systems. Among fluorescent nanoparticles (NPs), gold nanoclusters (AuNCs) have been intensively studied because of their intrinsic fluorescence and th…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Yellowish and blue luminescent graphene oxide quantum dots prepared via a microwave-assisted hydrothermal route using H 2 O 2 and KMnO 4 as oxidizing agents

Chechia Hu、Tzer-Rurng Su、Tzu-Jen Lin 等 5 位作者2017-12-08New Journal of Chemistry

Microwave-assisted hydrothermal synthesized GOQDs exhibit yellowish-green and blue light emission with quantum yields of 15.1% and 8.4%, respectively.

Carbon and Quantum Dots ApplicationsNanocluster Synthesis and ApplicationsGraphene and Nanomaterials Applications

Biocompatibility Assessment of Conducting PANI/Chitosan Nanofibers for Wound Healing Applications

Panagiota Moutsatsou、Karen Coopman、Stella Georgiadou2017-12-08Polymers

As electroactive polymers have recently presented potential in applications in the tissue engineering and biomedical field, this study is aiming at the fabrication of composite nanofibrous membranes containing conducting polyaniline and at the evaluation of their biocompatibility. For that purpose, conducting polyanil…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Homoepitaxial Growth of Large‐Scale Highly Organized Transition Metal Dichalcogenide Patterns

Jianyi Chen、Xiaoxu Zhao、Gustavo Grinblat 等 18 位作者2017-12-08Advanced Materials

Abstract Controllable growth of highly crystalline transition metal dichalcogenide (TMD) patterns with regular morphology and unique edge structure is highly desired and important for fundamental research and potential applications. Here, single‐crystalline MoS 2 flakes are reported with regular trigonal symmetric pat…

Perovskite Materials and Applications2D Materials and ApplicationsAdvanced Sensor and Energy Harvesting Materials