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Microbial Reduction of Structural Fe(III) in Illite and Goethite

Hailiang Dong、Ravi Kukkadapu、James K. Fredrickson 等 6 位作者2003-03-04Environmental Science & Technology

Microbial reduction of Fe(III) in illite was studied to evaluate the possibility of microbial utilization of Fe(III) in sedimentary clays and to determine the effects of bioreduction on clay composition and structure. A subsurface bacterium ( Shewanella putrefaciens CN32) and illite separates (<0.2 μm) from St. Peter…

Clay minerals and soil interactionsIron oxide chemistry and applicationsSoil and Unsaturated Flow

Composites of Perylene Chromophores and Layered Double Hydroxides: Direct Synthesis, Characterization, and Photo‐ and Chemical Stability

Johann Bauer、Peter Behrens、Markus Speckbacher 等 4 位作者2003-03-04Advanced Functional Materials

Abstract Composites of the tetra‐anion of the perylene dye N , N ′‐di(phenyl‐3,5‐disulfonic acid)perylene‐3,4:9,10‐tetracarboxydiimide (PBITS) with layered double hydroxides (LDHs) were formed by direct synthesis (co‐precipitation at constant pH). The LDHs were of the hydrotalcite (Mg–Al–OH and Zn–Al–OH compositions).…

Silicone and Siloxane ChemistryLayered Double Hydroxides Synthesis and ApplicationsPolyoxometalates: Synthesis and Applications

Single‐Crystalline Barium Titanate Nanowires

Jeffrey J. Urban、Jonathan E. Spanier、L. Ouyang 等 5 位作者2003-03-04Advanced Materials

Abstract Single‐crystalline barium titanate nanowires are synthesized using a solution‐based method, and their ferroelectric properties are investigated by scanning probe microscopy. Pristine nanowires have diameters ranging from 5 to 70 nm and lengths exceeding 10 μm, and they possess perovskite structures with a pri…

Ferroelectric and Piezoelectric MaterialsAdvanced Sensor and Energy Harvesting MaterialsElectrophoretic Deposition in Materials Science

Field-tuned quantum tunneling in a supramolecule dimer $[Mn_4]_2$

Yuanchang Su、Ruibao Tao2003-03-04arXiv

Field-tuned quantum tunneling in two single-molecule magnets coupled antiferromagnetically and formed a supramolecule dimer is studied. We obtain step-like magnetization curves by means of the numerically exact solution of the time-dependent Schrődinger equation. The steps in magnetization curves show the phenomenon o…

Materials Science

Improved Tight Binding Parametrization for the Simulation of Stacking Faults in Aluminium

Anders G. Froseth、Peter M. Derlet、Randi Holmestad 等 4 位作者2003-03-04arXiv

We refit the NRL tight binding parameterization for Aluminium by Mehl \emph{et al} [Phys. Rev. B, 61, 4894 (2000)], to a database generated via full potential Linearized Augmented Plane Wave (LAPW) Density Functional Theory (DFT) calculations. This is performed using a global optimization algorithm paying particular a…

Materials Science

A mean-field kinetic lattice gas model of electrochemical cells

Marc-Olivier Bernard、Mathis Plapp、Jean-Francois Gouyet2003-03-04arXiv

We develop Electrochemical Mean-Field Kinetic Equations (EMFKE) to simulate electrochemical cells. We start from a microscopic lattice-gas model with charged particles, and build mean-field kinetic equations following the lines of earlier work for neutral particles. We include the Poisson equation to account for the i…

Materials Sciencecond-mat.stat-mech

A Reduced Moment Magnetic Ordering in a Kondo Lattice Compound: Ce8pd24ga

D. T. Adroja、W. Kockelmann、A. D. Hillier 等 6 位作者2003-03-04arXiv

The magnetic ground state of the antiferromagnet Kondo lattice compound Ce8Pd24Ga has been investigated using neutron powder diffraction, inelastic neutron scattering and zero-field muon spin relaxation measurements. The neutron diffraction analysis, below TN (3.6(0.2)K), reveals a commensurate type-C antiferromagneti…

Materials ScienceStrongly Correlated Electrons

Solvothermal Route to Semiconductor Nanowires

Kaibin Tang、Yitai Qian、Jie Zeng 等 4 位作者2003-03-04Advanced Materials

Abstract Solvothermal synthesis is an important technology for the preparation of nanowires at low temperature. Nanowires can grow as long as 100 μm with the aid of polymer matrix, and under the pressure generated by solvothermal reactions, the as‐prepared nanowires are well crystallized. For water‐sensitive reactions…

Quantum Dots Synthesis And PropertiesCopper-based nanomaterials and applicationsChalcogenide Semiconductor Thin Films

Preparation and Organization of Nanoscale Polyelectrolyte‐Coated Gold Nanoparticles

K. Subramanya Mayya、Bjoern Schoeler、Frank Caruso2003-03-04Advanced Functional Materials

Abstract The layer‐by‐layer (LbL) desposition of oppositely charged polyelectrolytes from adsorption solutions of different ionic strength onto ∼7 nm diameter carboxylic acid‐derivatized gold nanoparticles has been studied. The polyelectrolyte‐modified nanoparticles were characterized by UV‐vis spectrophotometry, micr…

Gold and Silver Nanoparticles Synthesis and ApplicationsPolymer Surface Interaction Studies

Roughness of stylolites: a stress-induced instability with non local interactions

J. Schmittbuhl、F. Renard、J. P. Gratier2003-03-04arXiv

We study the roughness of stylolite surfaces (i.e. natural pressure-dissolution surfaces in sedimentary rocks) from profiler measurements at laboratory scales. The roughness is shown to be nicely described by a self-affine scaling invariance. At large scales, the roughness exponent is $ζ_1 \approx 0.5$ and very differ…

Materials Sciencecond-mat.dis-nn

Semiconductor Nanorod Liquid Crystals and Their Assembly on a Substrate

Lanfang Li、A. Paul Alivisatos2003-03-04Advanced Materials

The macroscopic alignment and superlattice structures of CdSe nanorods in a nematic liquid‐crystalline (LC) phase are determined by the phases that form prior to complete solvent evaporation (e.g., vortex structures in linear arrays, see Figure). By controlling the phase of the LC solution and its orientation using pr…

Photonic Crystals and ApplicationsLiquid Crystal Research AdvancementsPlant Reproductive Biology

Ground-state phase diagram ofS=1XXZchains with uniaxial single-ion-type anisotropy

Wei Chen、Kazuo Hida、B. C. Sanctuary2003-03-04Physical review. B, Condensed matter

One-dimensional $S=1$ $\mathrm{XXZ}$ chains with uniaxial single-ion-type anisotropy are studied by numerical exact diagonalization of finite-size systems. The numerical data are analyzed using conformal field theory, the level spectroscopy, phenomenological renormalization-group, and finite-size scaling method. We th…

Physics of Superconductivity and MagnetismOrganic and Molecular Conductors ResearchMagnetism in coordination complexes

Morphogenesis of One‐Dimensional ZnO Nano‐ and Microcrystals

Huang Yan、Ruihua He、Jean Pham 等 4 位作者2003-03-04OpenAlex

The deterministic growth of different shapes of ZnO crystals from nanometer to micrometer scale is reported. Tetrapods (see Figure) and dendrites have been synthesized by simply adjusting the reaction temperature and the partial pressure of oxygen within the system. Size control of these structures can be achieved. Zn…

nanoparticles nucleation surface interactionsZnO doping and properties

Anisotropic Shape Control of Colloidal Inorganic Nanocrystals

Seung Min Lee、S.‐N. Cho、Jinwoo Cheon2003-03-04OpenAlex

Abstract The systematic shape control of colloidal nanocrystals including one‐dimensional (1D) nanorods remains a key issue in the “bottom–up” approach of nanoscience. Here, we examine the anisotropic structural evolution of various semiconductor nanocrystals and systematically elucidate the key growth parameters for…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Mechanisms for the Shape‐Control and Shape‐Evolution of Colloidal Semiconductor Nanocrystals

Xiaogang Peng2003-03-04OpenAlex

Abstract The shape of CdSe and other semiconductor nanocrystals is controlled, producing dots, rods, rice‐shaped particles, tetrapods, or other elongated shapes. Monomer concentration in the growth solution is the determining factor in shape‐control and shape‐evolution. The elongated shapes could be transformed into m…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

An Improved Synthesis of High‐Aspect‐Ratio Gold Nanorods

B.D. Busbee、Sherine O. Obare、Catherine J. Murphy2003-03-04OpenAlex

By using seed‐mediation and careful control of pH , gold nanorods of high aspect ratio (∼ 18–25, 20 in the Figure) have been produced by surfactant‐directed synthesis. The yield is high (∼ 90 %) and the method can be readily adapted for scaling up.

Nanocluster Synthesis and ApplicationsGold and Silver Nanoparticles Synthesis and ApplicationsNanomaterials for catalytic reactions

Growth of Arrayed Nanorods and Nanowires of ZnO from Aqueous Solutions

Lionel Vayssières2003-03-04OpenAlex

Abstract A novel approach to the rational fabrication of smart and functional metal oxide particulate thin films and coatings is demonstrated on the growth of ZnO nanowires and oriented nanorod arrays. The synthesis involves a template‐less and surfactant‐free aqueous method, which enables the generation of, at large‐…

ZnO doping and properties

One‐Dimensional Nanostructures: Synthesis, Characterization, and Applications

Yan Xia、Pengfei Yang、Yugang Sun 等 9 位作者2003-03-04OpenAlex

Abstract This article provides a comprehensive review of current research activities that concentrate on one‐dimensional (1D) nanostructures—wires, rods, belts, and tubes—whose lateral dimensions fall anywhere in the range of 1 to 100 nm. We devote the most attention to 1D nanostructures that have been synthesized in…

2D Materials and ApplicationsGa2O3 and related materialsZnO doping and properties

Comparative Properties of TPE Materials for Automotive Interiors

Daryl Way、Craig L. Shoemaker2003-03-03SAE technical papers on CD-ROM/SAE technical paper series

&lt;div class="htmlview paragraph"&gt;With the recent interest in the possibilities of utilizing TPE materials as alternatives to flexible PVC (fPVC) in interior automotive applications, we have conducted a study of several soft touch polymer compounds in order to compare and contrast their characteristics with those…

Material Properties and ApplicationsTextile materials and evaluationsMaterial Properties and Processing

Correlation Study on Different Bumper Impact Test Method and Predicted Results

Darin Evans2003-03-03SAE technical papers on CD-ROM/SAE technical paper series

&lt;div class="htmlview paragraph"&gt;Laboratory testing and computer aided engineering (CAE) techniques have long been employed in the development and optimization of automotive bumper systems. However, as more aggressive automotive styling and performance trends and mass and cost reduction objectives continue to pus…

High-Velocity Impact and Material BehaviorCellular and Composite StructuresMechanical Engineering and Vibrations Research