Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTConformational characteristics of some model polydienes and polyolefinsPaul Hattam, Stephen Gauntlett, Jimmy W. Mays, Nikos Hadjichristidis, Ronald N. Young, and Lewis J. FettersCite this: Macromolecules 1991, 24, 23, 6199–6209Publication Date (Print):November 1, 1991Publica…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhenomenological kinetics of complex systems: mechanistic considerations in the solubilization of hemicelluloses following aqueous/steam treatmentsK. Belkacemi, N. Abatzoglou, R. P. Overend, and E. ChornetCite this: Ind. Eng. Chem. Res. 1991, 30, 11, 2416–2425Publication Dat…
Aqueous mixtures of Zr(C 2 H 3 O 2 ) 4 and Gd(NO 3 ) 3 were used to prepare chemically homogeneous ZrO 2 —Gd 2 O 3 solid solutions containing 0 to 9 mol% Gd 2 O 3 . The application of kinetically limited equilibria concepts explains why a metastable tetragonal phase crystallized subsequent to precursor pyrolysis from…
Abstract Illite crystallinity (IC) and other indicators of the grade of very‐low‐grade metamorphism associated with the appearance of various stages of slaty cleavage in phyllosilicate‐rich rocks have been compiled from a wide variety of terranes. IC values have been converted to a Kübler‐equivalent standard scale, bu…
The influence of silver oxide additions on the fracture behavior of YBa2Cu3O7−x superconducting ceramic was studied. The KIC value has been found to increase from about 1 MPa√m to as much as 2.4 MPa√m with the blending of 30 wt.% Ag2O with the 1-2-3 powder. All compositions exhibited increasing resistance to fracture…
Polyurethanes chain extended with N,N-bis (2-hydroxyethyl)-2-aminoethane-sulfonic acid (BES) were synthesized. The effect of the sulfonic acid group on the polymers' bulk, surface, and blood-contacting properties was evaluated by comparing the BES-based polymers with polyurethanes based on N-ethyldiethanolamine (EDEA)…
The interiors of hysteresis loops were examined for commercial recording tape samples of gamma -Fe/sub 2/O/sub 3/ and Co-modified gamma -Fe/sub 2/O/sub 3/. It was found that the minor loops did not satisfy the congruency condition of the classical Preisach model. Since both the moving model and the product model are c…
An elementary discussion of time-dependent correlation functions is presented. These functions are discussed in the context of dielectric relaxation and nuclear magnetic resonance for two forms of decay: Simple exponential and stretched (Kohlrausch–Williams–Watts) exponential. A guide to the calculation of the stretch…
The ultimate resolution in secondary-electron images obtained in a scanning transmission electron microscope depends strongly on secondary-electron-production mechanisms. In such a microscope, equipped with an electron-energy-loss spectrometer as well as secondary-electron-energy analyzer, coincidences have been achie…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTShallow reorientation in the surface dynamics of plasma-treated fluorinated ethylene-propylene polymerHans J. Griesser, Youxian Da, Anthony E. Hughes, Thomas R. Gengenbach, and Albert W. H. MauCite this: Langmuir 1991, 7, 11, 2484–2491Publication Date (Print):November 1, 199…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLiquid-crystalline polyethers based on conformational isomerism. 18. Polyethers based on a combined mesogenic unit containing rigid and flexible groups: 1-(4-hydroxy-4'-biphenyl)-2-(4-hydroxyphenyl)butaneVirgil Percec and Masaya KawasumiCite this: Macromolecules 1991, 24, 23…
The stability and lifetime of a shape memory device is characterised by the changes of its transformation temperatures, its cold shape, its hot shape, its global two way shape memory effect, its recovery stress. This global behaviour is influenced by a complex combination of internal and external parameters. Internal…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and x-ray diffraction crystal structure of bis[bis(2,2,6,6-tetramethylheptane-3,5-dionato)diamminebarium]. A novel low-molecularity barium compoundWilliam S. Rees Jr., Michael W. Carris, and Werner HesseCite this: Inorg. Chem. 1991, 30, 24, 4479–4481Publication Dat…
Abstract Specimen thickness is the main experimental factor controlling the results of illite crystallinity (IC) or crystallite size measurements on sedimentation slides. Different values obtained from thick and thin preparations are due to grain‐size gradation effects, which may exclude larger and higher ordered grai…
peer reviewed
The fracture and fracture resistance behaviors of zirconmatrix composites uniaxially reinforced with either uncoated or BN‐coated silicon carbide fibers are studied by performing experiments in three‐point flexure and by analyzing results analytically using a cohesive crack model that incorporates crack bridging and f…
Abstract The valence bands (VB) of remote oxygen and remote nitrogen plasma‐treated polyethylene and polypropylene were studied to determine changes in the basic polymer structure. Each of the polymers showed a characteristic valence band profile, which retained much of its original shape after plasma treatment. This…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructure-property relationships for the thermal phase behavior of discotic liquid crystals: the effect of branching and unsaturation in the side chains of disklike moleculesDavid M. Collard and C. Peter LillyaCite this: J. Am. Chem. Soc. 1991, 113, 23, 8577–8583Publication…
Twenty adult male volunteers were studied in an unblinded, ascending-dose study to evaluate the safety, tolerance, and pharmacokinetics of intravenously administered nonionic gadodiamide injection. Dosages administered were 0.05, 0.1, 0.2, and 0.3 mmol/kg. Subjects were monitored from 36 hours before, through 72 hours…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIntercalation of poly(ethylene oxide) in vanadium pentoxide (V2O5) xerogelY. J. Liu, D. C. DeGroot, J. L. Schindler, C. R. Kannewurf, and M. G. KanatzidisCite this: Chem. Mater. 1991, 3, 6, 992–994Publication Date (Print):November 1, 1991Publication History Published online1…