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Fabrication and Crack Deflection in Ceramic Laminates with Porous Interlayers

J.B. Davis、Annika Kristoffersson、Elis Carlström 等 4 位作者2000-10-01Journal of the American Ceramic Society

A simple and general method for making ceramic laminates with porous crack‐deflecting interlayers is demonstrated. Both the strong laminae and the porous interlayers are made by tape casting suitable slurries using the same ceramic powders. Porosity is introduced into the interlayer by adding starch particles to the s…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Coordination of Co2+ Ions in the Interior of Poly(propylene amine) Dendrimers Containing Fluorescent Dansyl Units in the Periphery

Fritz Vögtle、Sven Gestermann、Christopher Kauffmann 等 6 位作者2000-10-01Journal of the American Chemical Society

We have investigated the interaction of Co 2+ ions (as nitrate salt) with dendrimers of the poly(propylene amine) family functionalized in the periphery with fluorescent dansyl units. Each dendrimer n D, where the generation number n goes from 1 to 5, comprises 2 ( n +1) dansyl functions in the periphery and 2 ( n +1)…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsDendrimers and Hyperbranched Polymers

Radioactivity in Products Derived from Gypsum in Tanzania

P. Msaki、Firmi P. Banzi2000-10-01Radiation Protection Dosimetry

Scientific investigations have long concluded that prolonged exposure to low dose radiation can induce deleterious effects in humans. The aim of this paper is to investigate the radioactivity of gypsum and gypsum derived products as part of a bigger project aimed at establishing radiation levels in materials or/and pr…

Radioactivity and Radon MeasurementsGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Copper removal by polymer immobilised Rhizopus oryzae

M. S. Al-Hakawati、C.J. Banks2000-10-01Water Science & Technology

Rhizopus oryzae, strain IMI 057412, was immobilised by inclusion in six different polymers: polyvinlformal, polysulfone, polyurethane, alginate, polyacrylamide, k-carrageenan, polyethyleneimine(PEI). It was also grown on a seventh, polyurethane. The biomass/polymer matrices were formed into equal size units (4 mm sphe…

biodegradable polymer synthesis and propertiesPolymer Surface Interaction StudiesCalcium Carbonate Crystallization and Inhibition

A Comprehensive Study of Chemical and Physical Properties of Metal Sulfides

Bernhard Melcher、Peter Faullant2000-10-01SAE technical papers on CD-ROM/SAE technical paper series

<span class="label">1</span> <div class="htmlview paragraph">Natural and synthetic sulfides are important components in friction materials such as pads, linings and even clutch facings and are summarized under the term “Friction Stabilizers”. Their unique properties lead to a high and stable friction…

Chalcogenide Semiconductor Thin FilmsMetal Extraction and BioleachingThermal and Kinetic Analysis

Slurry Chemistry Control to Produce Easily Redispersible Ceramic Powder Compacts

Jooho Moon、Jason E. Grau、Michael J. Cima 等 4 位作者2000-10-01Journal of the American Ceramic Society

The slurry‐based Three Dimensional Printing (3DP TM ) process requires the production of an easily redispersible powder bed from a well‐dispersed slurry. Understanding and control of the interparticle potential in the dispersed state, as well as in the dry consolidated state, are important. The strength of the particl…

Advanced ceramic materials synthesisAdditive Manufacturing and 3D Printing TechnologiesInnovations in Concrete and Construction Materials

Volume Porosity of Woven Fabrics

Polona Dobnik Dubrovski2000-10-01Textile Research Journal

A new experimental model based on the geometric parameters of a woven structure's yarn linear density and fabric tightness has been developed to predict the volume porosity of woven fabrics. The experimental model is based on a factor analysis. Experiments involve fabrics made from staple yams, but the mathematical mo…

Mechanical Behavior of CompositesTextile materials and evaluationsIndustrial Vision Systems and Defect Detection

Tuning of the pitch height of thermotropic cellulose esters

Haoqing Hou、Arndt Reuning、Joachim H. Wendorff 等 4 位作者2000-10-01Macromolecular Chemistry and Physics

Butyric esters of (2-hydroxypropyl) cellulose (BuPC) with different degree of substitution (DS) were synthesized via control of the esterification time of butyryl chloride and (2-hydroxypropyl) cellulose. These BuPCs are thermotropic and displayed different colors at ambient temperature due to the formation of a chole…

Liquid Crystal Research AdvancementsAdvanced Cellulose Research StudiesMaterial Properties and Processing

Pyramidalization of backbone carbonyl carbon atoms in proteins.

Luciana Esposito、Luigi Vitagliano、Adriana Zagari 等 4 位作者2000-10-01PubMed

The high accuracy of X-ray analyses at atomic resolution is now able to display subtle deformations from standard geometry of building blocks in proteins. From the analysis of nine ultra-high resolution protein structures, we derived the first experimental evidence that a significant pyramidalization at the main-chain…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function

First Asymmetric Photochemistry with Nucleosides and DNA: Enantiodifferentiating Z–E Photoisomerization of Cyclooctene

Takehiko Wada、Norimitsu Sugahara、Mahito Kawano 等 4 位作者2000-10-01Chemistry Letters

Abstract Thymidine and uridine, as well as calf thymus DNA (ctDNA), have been shown for the first time to function as chiral photosensitizers in aqueous solution, to effect the enantiodifferentiating photoisomerization of (Z)-cyclooctene, giving the chiral (E)-isomer in enantiomeric excesses of up to 15%.

Radical Photochemical ReactionsFluorine in Organic ChemistryPhotochromic and Fluorescence Chemistry

Cation distribution in synthetic zinc ferrite (Zn 0.97 Fe 2.02 O 4 ) from in situ high-temperature neutron powder diffraction

Alessandrο Pavese、Davide Levy、A. Hoser2000-10-01American Mineralogist

Neutron powder diffraction experiments at high temperature (300-1600 K) were performed at BENSC (Berlin, D), on synthetic Zn 0.97 Fe 2.02 O 4 , to investigate the cation partitioning of Zn and Fe over the tetrahedral and octahedral sites as a function of T. The data analysis combined Rietveld structure refinements wit…

Magnetic Properties and Synthesis of FerritesAdvanced Condensed Matter PhysicsX-ray Diffraction in Crystallography

Synthesis of Manganite Perovskites by Reverse Homogeneous Precipitation Method in the Presence of Alkylammonium Cations

Yasutake Teraoka、Shinichi Nanri、Isamu Moriguchi 等 6 位作者2000-10-01Chemistry Letters

Abstract A single-phase LaMnO3+δ perovskite with high surface area could be synthesized after air-calcining the hydroxide precursor at 650 °C and above. The precursor was easily obtained by dropping a mixed aqueous solution of La and Mn nitrates into highly basic aq. NH3 with and without the presence of N(CH3)4Br. The…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Low Molecular Weight Gelator Containing β-Diketonato Ligands: Stabilization of Gels by Metal Coordination

Kenji Hanabusa、Yukinobu Maesaka、Masahiro Suzuki 等 5 位作者2000-10-01Chemistry Letters

Abstract A low molecular weight gelator containing β-diketonato ligands was prepared from a derivative based on trans-(1R,2R)-diaminocyclohexane. Gels were converted to mechanically-robust and thermally-stable gels by complexation between β-diketonato ligands and divalent metal ions.

Hydrogels: synthesis, properties, applicationsbiodegradable polymer synthesis and propertiesSupramolecular Self-Assembly in Materials

Effects of Chemical Blowing Agents on Swelling Properties of Expanded Elastomers

Narongrit Sombatsompop、P. Lertkamolsin2000-10-01Journal of Elastomers & Plastics

Two commercial chemical blowing agents, azodicarbonamide (ADC) and oxybisenzenesulphonylhydrazide (OBSH), were used alone and in blends for expanded natural rubber vulcanisates. The expanded rubber vulcanisates were characterised with respect to the apparent foam density, degree of crosslinking, tensile properties and…

Polymer Nanocomposites and PropertiesElasticity and Material ModelingPolymer Foaming and Composites

New Adventures in the Synthesis of Hetero-Bridgedsyn-Facially Fused Norbornadienes (“[n]Polynorbornadienes”) and Their Topological Diversity

Ronald N. Warrener2000-10-01European Journal of Organic Chemistry

Molecular Scaffolds formed by the linking of bicyclo[2.2.1]heptane (norbornane) subunits by sharing a common C2-bridge have great appeal to the molecular architect since modelling studies have shown that the syn-facially fused members have a curved topology. Furthermore, this curvature can be modified by replacement o…

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistryOrganic Chemistry Cycloaddition Reactions

Promotive Effects of a Silk Film on Epidermal Recovery from Full‐Thickness Skin Wounds

Akira Sugihara、Kikuya Sugiura、Haruo Morita 等 10 位作者2000-10-01Proceedings of The Society for Experimental Biology and Medicine

Abstract. We examined the effects of the transparent fibroin film (silk film) on full‐thickness skin wounds. Full‐thickness dermatotomies (15 mm × 9 mm) were prepared on the dorsal wall of CRJ:CD‐1 nu/nu (ICR nu/nu ) mice. The area of the wounds dressed with silk film was reduced to 10% of that made by the dermatotomy…

Wound Healing and TreatmentsAntimicrobial Peptides and ActivitiesSilk-based biomaterials and applications

Bleaching Properties of Alumina-Pillared Acid-Activated Montmorillonite

Polycarpos Falaras、Fani Lezou、Georgios Seiragakis 等 4 位作者2000-10-01Clays and Clay Minerals

Abstract The bleaching of cottonseed oil by alumina-pillared (Al-pillared) acid-activated clays was investigated. Acid activation of a Ca-rich montmorillonite (CMS STx-1) following treatment with 1, 4, and 8 eq/L sulfuric-acid solutions, as well as subsequent pillaring with alumina, produces new materials. These mater…

Mesoporous Materials and CatalysisClay minerals and soil interactionsAerogels and thermal insulation

Infrared study of OH sites in tourmaline from the elbaite-schorl series

Cristiane Castañeda、Ester Figueiredo de Oliveira、Newton Sousa Gomes 等 4 位作者2000-10-01American Mineralogist

Two different behaviors controlled by local lattice environment of crystallization are observed in the IR spectra of polycrystalline natural tourmalines from the elbaite-schorl series in the O-H stretching region (3800-3100 cm -1 ). The first case is characterized by the presence of three O-H stretching bands, and is…

Geological and Geochemical AnalysisCrystal Structures and PropertiesMineralogy and Gemology Studies

Characterization, Seasonal Occurrence, and Diel Fluctuation of Poly(hydroxyalkanoate) in Photosynthetic Microbial Mats

Mary M. Rothermich、Ricardo Guerrero、Robert W. Lenz 等 4 位作者2000-10-01Applied and Environmental Microbiology

In situ poly(hydroxyalkanoate) (PHA) levels and repeating-unit compositions were examined in stratified photosynthetic microbial mats from Great Sippewissett Salt Marsh, Mass., and Ebro Delta, Spain. Unlike what has been observed in pure cultures of phototrophic bacteria, the prevalence of hydroxyvalerate (HV) repeati…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Motion and Disorder in Crystal Structure Analysis: Measuring and Distinguishing Them

Hans‐Beat Bürgi2000-10-01Annual Review of Physical Chemistry

Dynamic processes in crystalline solids are reflected in the atomic displacement amplitudes determined, together with the atomic coordinates, by crystal structure analysis. The interpretation of such amplitudes poses two severe problems: (a) The relative phases of the atomic displacements are lost; and (b) the amplitu…

High-pressure geophysics and materialsX-ray Diffraction in CrystallographyCrystallography and Radiation Phenomena