Materials Literature
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Using a new interfacial polymerization method for the synthesis of polyaniline nanofibers, we have developed nanofiber sensors and compared them to conventional polyaniline sensors. Five different response mechanisms are explored: acid doping (HCl), base dedoping (NH 3 ), reduction (with N 2 H 4 ), swelling (with CHCl…
Weit reichende Kapillarkräfte werden zum selbstorganisierten Aufbau von dreidimensionalen Mikromustern auf Filmen aus Kohlenstoffnanoröhren (CNTs) genutzt (siehe Bild). Die Methode beruht auf der Spreitung eines Wassertropfens nach dem Erzeugen des CNT-Films. Entscheidend für die Musterbildung ist die Steuerung der Di…
Abstract In this work the photoconductivity measurements are carried out for single crystals of the Tl 2 S compound by using both pulsed excitation (a.c) and steady state (d.c) methods in order to elucidate the nature of photoconductivity (PC) in this compound. Results are reported in the temperature range from 77 K t…
The present article presents a spatiotemporal growth of isotactic polypropylene (iPP) single crystals, melt crystallized from a polymeric solvent, i.e., poly (ethylene octene) copolymer that is known to be miscible with iPP. Optical and atomic force microscopic investigations reveal that the melt grown single crystals…
We study the linear elastic response of multiblock copolymer melts in the lamellar phase, where the molecules are composed of tethered symmetric AB diblock copolymers. We use a self-consistent field theory method, and introduce a real space approach to calculate the tensile and shear moduli as a function of block numb…
A smooth Ru(0001) surface prepared under ultra-high vacuum conditions has been loaded with oxygen under high-pressure (p approximately 1 bar) and low-temperature (T < 600 K) conditions. Oxygen phases created in this way have been investigated by means of thermal desorption spectroscopy, low-energy electron diffraction…
Abstract We demonstrate a possibility to create custom‐made surface patterns on multiple length scales by melting selected nano‐meter‐sized polymer crystals confined in a highly ordered, spherical mesostructure of a hydrogenated poly(butadiene‐ block ‐ethylene oxide) (PB h ‐ b ‐PEO) block copolymer. With heatable prob…
Thermal expansion and impurity effects on the lattice thermal conductivity of solid argon have been investigated with equilibrium molecular dynamics simulation. Thermal conductivity is simulated over the temperature range of 20-80 K. Thermal expansion effects, which strongly reduce thermal conductivity, are incorporat…
Abstract The thermal behavior and overall isothermal crystallization kinetics of a series of organophilic modified montmorillonite–poly(ϵ‐caprolactone) nanocomposites were investigated. In general, the thermal behavior was influenced more by the type of dispersion than by the clay content. For nanocomposites in which…
The perovskite manganites Pr 1 - x Sr x MnO 3 in the region 0.45 ≤ x ≤ 0.75 exhibit two crystallographic modifications at room temperature orthorhombic Ibmm and tetragonal I 4/ mcm with boundary situated at x ∼ 0.48. The high-temperature X-ray diffraction data show that for x ≥ 0.6 the tetragonal phase of I 4/ mcm sym…
Abstract A series of polymer–clay nanocomposite (PCN) materials consisting of 1,4‐bis(4‐aminophenoxy)‐2‐ tert ‐butylbenzene–4,4′‐oxydiphthalic anhydride (BATB–ODPA) polyimide (PI) and layered montmorillonite (MMT) clay were successfully prepared by an in situ polymerization reaction through thermal imidization up to 3…
Abstract The thermal degradation of two epoxy systems diglycidyl ether of bisphenol A (DGEBA n = 0)/1,2‐diamine cyclohexane (DCH) containing different concentrations of an epoxy reactive diluent, vinylcyclohexene dioxide (VCHD), was studied by thermogravimetric analysis to determine the reaction mechanism of the degra…
The low-field response from single bicrystal grain boundary junction of ${\mathrm{La}}_{0.7}{\mathrm{Sr}}_{0.3}{\mathrm{MnO}}_{3}$ has been investigated. We provide experimental data for the temperature, magnetic field, and bias current dependence of its low-field magnetoresistance. We are then able to separate the co…
In this paper we report on experimental data for the frequency and temperature dependence of the thermal properties of supercooled glycerol and propylene glycol. By using a photopyroelectric method the specific heat capacity and thermal conductivity were separately determined in a bandwidth of several decades. We have…
In a previous work [Heinz, Castelijns, and Suter, J. Am. Chem. Soc. 115, 9500 (2003)], we developed an accurate force field and simulated the phase transitions in C18-mica (octadecyltrimethylammonium-mica) as well as the absence of such transitions in 2C18-mica (dioctadecyldimethylammonium-mica) between room temperatu…
Heat conduction in a one-dimensional chain of equivalent rigid particles in the field of the external on-site potential is considered. The zero diameters of the particles correspond to the integrable case with the divergent heat conduction coefficient. By means of a simple analytical model it is demonstrated that for…
Surface relief gratings on azobenzene containing polymer films were prepared under irradiation by actinic light. Finite element modeling of the inscription process was carried out using linear viscoelastic analysis. It was assumed that under illumination the polymer film undergoes considerable plastification, which re…
Delamination of advanced composite materials due to various scenarios such as low velocity and ballistic impacts and high strain rate is one of the major problems for aerospace and automotive structural applications. The low velocity impact does not immediately induce any visible damage on the surface of structures wh…
Two Bacillus subtilis genes encoding two proteins (currently annotated ThiD and YjbV) were overexpressed and characterized. YjbV has 4-amino-5-hydroxymethyl-2-methylpyrimidine and 4-amino-5-hydroxymethyl-2-methylpyrimidine pyrophosphate kinase activity and should be reannotated ThiD, and B. subtilis ThiD has pyridoxin…
A nanocomposite of a multiwalled carbon nanotube and polythiophene was prepared by functionalizing the nanotube surface with a polythiophene, poly[3-(2-hydroxyethyl)-2,5-thienylene], containing pendant hydroxyl groups. The composite was characterized by IR, high resolution TEM and conductivity measurements. The poly[3…