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Microstructural evolution of the al2o3-zro2 composite and its correlation with electrical conductivity

Carlos Alberto Fortulan、Dulcina P. F. de Souza1999-07-01Materials Research

The Al2O3-ZrO2 composite was studied by impedance spectroscopy, a non destructive technique that was found to be sensitive to the composite's microstructure. The observed decrease in the zirconia grain and grain boundary conductivities points to compression on zirconia grain by alumina matrix. This effect increased wi…

Advanced ceramic materials synthesisAdvanced materials and compositesNuclear materials and radiation effects

Report of a Subcommittee on the Nomenclature of n-Dimensional Crystallography. I. Symbols for point-group transformations, families, systems and geometric crystal classes

Τ. Janssen、Joseph L. Birman、V. A. Kopt︠s︡ik 等 8 位作者1999-07-01Acta Crystallographica Section A Foundations of Crystallography

The notation of crystallography in arbitrary dimensions is considered. Recommended symbols for point-group transformations, geometric crystal classes, families and systems are presented.

Quasicrystal Structures and PropertiesX-ray Diffraction in CrystallographyMineralogy and Gemology Studies

Long alkyl chain dimethylammonioalkoxydicyanoethenolates as new zwitterionic thermotropic liquid crystals

A. Mathis、Monique Galin、J. C. Galin 等 5 位作者1999-07-01Liquid Crystals

The liquidcrystalline thermotropic behaviour of a series of long alkyl chain dimethylammonioalkoxydicyanoethenolates of the type CH3-(CH2)n-1-N+(CH3)2-(CH2)p-O-CO-C-(CN)2 (n=10-18, even values only, with p=2, 3; p=4 for n=16) was analysed through differential scanning calorimetry, X-ray diffraction and polarizing opti…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsPorphyrin and Phthalocyanine Chemistry

Molybdenum(V) on an Oxide String. Synthesis and Structure of the Novel Linear Trinuclear Complex {[MoO(TPP)][O−Mo(TPP)−O][MoO(TPP)]}ClO4

Brent J. Hamstra、Beisong Cheng、M.K. Ellison 等 4 位作者1999-07-01Inorganic Chemistry

The syntheses and crystallographic characterization of the linear trinuclear complex [Mo(3)O(4)(TPP)(3)]ClO(4) and the monomeric precursors [MoO(TPP)(OClO(3))] and [MoO(TPP)(OH(2))]ClO(4) are described. The crystallographic analyses of [MoO(TPP)(OClO(3))] and [MoO(TPP)(OH(2))]ClO(4) show that these similar complexes a…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Disappearances of energy minima and loss of order in polydisperse colloidal systems

Daniel J. Lacks、Jeffrey R. Wienhoff1999-07-01The Journal of Chemical Physics

Simulations are carried out to determine how polydispersity (δ) affects the potential energy surface of a colloidal system. Increases in polydispersity are shown to cause the disappearance of potential energy minima, such that energy minima corresponding to homogeneous highly ordered structures exist only for δ&lt…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

Fabrication of CVD Diamond Optics with Antireflective Surface Structures

Victor Ralchenko、А. В. Хомич、Alexander Baranov 等 5 位作者1999-07-01physica status solidi (a)

Polycrystalline CVD diamond is an excellent material for advanced optical applications, especially in the IR spectral range. However, one drawback of diamond is the significant reflection loss of 29%, caused by its high refraction index n = 2.4. We fabricated subwavelength, “moth-eye” antireflective structured (ARS) s…

Diamond and Carbon-based Materials ResearchAdvanced Surface Polishing TechniquesOptical Coatings and Gratings

Mixed (Oxygen Ion and n‐Type) Conductivity and Structural Characterization of Titania‐Doped Stabilized Tetragonal Zirconia

P. Durän、F. Capel、C. Moure 等 6 位作者1999-07-01Journal of The Electrochemical Society

Mixed (Oxygen Ion and n‐Type) Conductivity and Structural Characterization of Titania‐Doped Stabilized Tetragonal Zirconia, Durán, P., Capel, F., Moure, C., González‐Elipe, A. R., Caballero, A., Bañares, M. A.

Advancements in Solid Oxide Fuel CellsZeolite Catalysis and SynthesisMetal Extraction and Bioleaching

Embolization with Polyhydroxybutyrate (PHB) Microspheres: In-Vivo Studies

A. Ch. Kassab、E. Pi̇şki̇n、Semra Bi̇lgi̇ç 等 5 位作者1999-07-01Journal of Bioactive and Compatible Polymers

In this study polyhydroxybutyrate (PHB), produced by a methanol-utilizing bacteria, was used to prepare microspheres in the 120-200 μm size range for embolization. A solvent evaporation technique was utilized to obtain microspheres in which methylene chloride, distilled water and polyvinyl alcohol were used as the sol…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesTissue Engineering and Regenerative Medicine

Annealing effects on the internal bias field in ferroelectric PZT thin films with self-polarization

Shan Sun、Yongmei Wang、Paul Fuierer 等 4 位作者1999-07-01Integrated ferroelectrics

Asymmetric switching properties were measured and quantified in sol-gel derived PZT thin films. The hysteresis asymmetry is attributed to the presence of an internal bias field that has been correlated with the self-polarization during fabrication. Annealing the sample under a remanent polarization with the polarity o…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Generation of pretilt angle in NLCs and EO characteristics of a photo-aligned TN-LCD with oblique non-polarized UV light irradiation on a polyimide surface

Dae‐Shik Seo、Jeong‐Min Han1999-07-01Liquid Crystals

We have investigated the generation of pretilt angle for a nematic liquid crystal (NLC) alignment in cells with oblique non-polarized ultraviolet (UV) light irradiation on polyimide (PI) surfaces. It was found that monodomain alignment of the NLC is obtained with an incident angle of 70 degrees and 75 degrees on the P…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsAdvanced Materials and Mechanics

Welding of High-Performance Thermoplastic Composites

R. Rudolf、Peter Mitschang、M. Neitzel 等 4 位作者1999-07-01Polymers and Polymer Composites

In previous investigations, vibration welding, which is suitable for the mass production of small and simple shaped parts, was adjusted to the characteristics of thermoplastic composites. However, because of the small batches in thermoplastic composites manufacturing, especially in today's aircraft industry, there is…

Material Properties and ApplicationsAdvancements in Materials EngineeringPolymer Science and Applications

Growth and characterization of epitaxial films of tungsten-doped vanadium oxides on sapphire (110) by reactive magnetron sputtering

Ping Jin、Masato Tazawa、M. Ikeyama 等 8 位作者1999-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Epitaxial films of W-doped vanadium oxides including W–V2O3, W–VO2 and W–V2O5 were deposited on sapphire (110) by reactive magnetron sputtering of a V–W (1.6 at. % W) alloy target in a range of oxygen partial flows. The deposited films were characterized by x-ray diffraction (XRD), Rutherford backscattering spectromet…

ZnO doping and propertiesTransition Metal Oxide NanomaterialsGa2O3 and related materials

Effect of the Steam‐Methane Ratio on Reactions Occurring on Ni/Yttria‐Stabilized Zirconia Cermet Anodes Used in Solid‐Oxide Fuel Cells

Manabu Ihara、Chiaki Yokoyama、Abulet Abudula 等 6 位作者1999-07-01Journal of The Electrochemical Society

Power‐generation experiments of solid‐oxide fuel cells with Ni/yttria‐stabilized zirconia cermet anodes were carried out by changing the water‐to‐methane ratio in the fuel. To separate the electrochemical reactions occuring on the three‐phase boundary of the anode from the steam‐reforming reactions, premixed gases cor…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

High temperature platinum etching using Ti mask layer

Hyoun-Woo Kim、Byong-Sun Ju、B.Y. Nam 等 8 位作者1999-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Platinum is a strong candidate for an electrode material of the high dielectric capacitors in highly integrated dynamic random access memory devices. However, it is extremely difficult to etch the fine patterns of Pt due to an inherently low etch slope. This characteristic comes from the physical sputtering nature of…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

Annealing of copper electrodeposits

C. H. Seah、S. Mridha、Lisa Chan1999-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

The properties of electroplated copper film have been investigated as a function of annealing temperatures together with the diffusion barrier performance. Electroplated copper films on copper and tungsten seed materials were annealed from 300 to 700 °C in N2 atmosphere for grain growth study. The average grain size o…

Metal and Thin Film MechanicsElectrodeposition and Electroless CoatingsCopper Interconnects and Reliability

Photoemission spectroscopy analysis of ZnO:Ga films for display applications

Eric Forsythe、Yongli Gao、L. G. Provost 等 4 位作者1999-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

We report the physical properties of ZnO:Ga-based films prepared by metalorganic chemical vapor deposition (MOCVD) using ultraviolet and x-ray photoemission spectroscopy (UPS and XPS). In addition, the surface characteristics of the films are modified with a series of cleaning and etching steps. The films were produce…

ZnO doping and propertiesGa2O3 and related materials

Poly(Trimethylene Phthalates or Naphthalate) and Copolymers: New Opportunities in Film and Packaging Applications

Charles Hwo、Tom Forschner、Rohan Lowtan 等 5 位作者1999-07-01Journal of Plastic Film & Sheeting

Poly(trimethylene phthalates or naphthalate) and copolymers are aromatic polyesters made by polycondensation of 1,3-propanediol (PDO) and terephthalic acid (PTT), isophthalic acid (PTI) or naphthalic acid (PTN) and/or with comonomers (isophthalic acid, 1,4-butanediol, etc.). This presentation describes the chemistry a…

Polymer crystallization and properties

RAYLEIGH-BENARD CONVECTION IN LIMITED DOMAINS: PART 2 - TRANSITION TO CHAOS

Fulvio Stella Edoardo Bucchignani1999-07-01Numerical Heat Transfer Part A Applications

Transitions to chaos in three-dimensional limited aspect ratio boxes, filled with an incompressible fluid and heated from below, have been examined by direct numerical simulation as the Rayleigh number is varied. Two different problems have been considered: the first is related to a domain 3.5 x 1 x 2.1 filled with wa…

Fluid Dynamics and Turbulent FlowsSolidification and crystal growth phenomenaNonlinear Dynamics and Pattern Formation

Optically encoded second-harmonic generation in germanosilicate glass by a femtosecond laser

Jinhai Si、Kenji Kitaoka、Jianrong Qiu 等 5 位作者1999-07-01Optics Letters

Second-harmonic generation in germanosilicate glasses was encoded by coherent superposition of the 810-nm fundamental and the 405-nm second-harmonic light of a femtosecond laser. The difference spectra between the absorption spectra of the glasses before and after preparation were measured. An evident correlation betw…

Glass properties and applicationsPhotorefractive and Nonlinear OpticsPhotochemistry and Electron Transfer Studies

Study of hydrogenated diamond-like carbon films using x-ray reflectivity

Qing Zhang、S. F. Yoon、Rusli Rusli 等 6 位作者1999-07-01Journal of Applied Physics

X-ray reflectivity under grazing incidence conditions is a powerful technique to study thin film density, surface roughness, and the multilayer structure without destroying the samples. In this article, we, using x-ray reflectivity technique, have studied the effects of bias voltage and deposition pressure on the mass…

Metal and Thin Film MechanicsHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research