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Orientational Measurements in Polymers Using Vibrational Spectroscopy

B. Jasse、Jack L. Koenig1979-01-01Journal of macromolecular science. Part C, Reviews in macromolecular chemistry and physics/Journal of macromolecular science. Reviews in macromolecular chemistry and physics

The mechanical properties of polymers are strongly influenced not only by the structure of the material but by the magnitude of the molecular orientation. Thus a great deal of interest exists in information about the molecular orientation in samples introduced by drawing or other forming processes. Several techniques…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesSpectroscopy and Chemometric Analyses

Mechanism of action of PVC thermal stabilizers

Jerzy Wypych1979-01-01Journal of Applied Polymer Science

Abstract Based on experimental data, changes of properties of plasticized PVC containing stearates of Ca, Zn, Cd, and Pb stabilizers during thermal degradation are discussed. The mechanism of action of these stabilizers is described in kinetic form.

Polymer Science and PVC

Structure of potassium hexabromostannate(IV) at room temperature

Takuya Higashi、S. Syoyama、K. Osaki1979-01-01Acta Crystallographica Section B

K2SnBr 6 at room temperature, monoclinic, P2~/n, a = 10.621 (2), b = 7.427 (2), c = 7.442 (2) fi~, fl = 90.18 (2) °, D x = 3.825 Mg m -3 for Z = 2. The crystal structure is a distorted KEPtCI 6 structure. The

Crystal Structures and PropertiesOrganometallic Compounds Synthesis and CharacterizationInorganic Chemistry and Materials

Corrosion Resisting Properties of 90/10 Copper–Nickel–Iron Alloy with Particular Reference to Offshore Oil and Gas Applications

Paul Gilbert1979-01-01British Corrosion Journal

Published information on the performance of 90/10 copper-nickel-iron alloy in sea water environments is reviewed, covering the effect of iron content and of different heat treatments, behaviour in quiescent sea water and in polluted sea water, resistance to impingement attack (effect of water velocity), crevice corros…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNon-Destructive Testing Techniques

Photoemission and Auger spectroscopy studies of the interaction of oxygen with zinc

C. R. Brundle、R.I. Bickley1979-01-01Journal of the Chemical Society Faraday Transactions 2 Molecular and Chemical Physics

Photoemission spectroscopy (u.p.s. and X.p.s.) and Auger Spectroscopy (X-ray induced) have been used to study the oxidation of clean evaporated zinc films. At 300 K, two oxygen species coexist throughout the adsorption process. The major species [O(1s) b.e. 530.0 eV] is characteristic of oxide and is considered repres…

Gas Sensing Nanomaterials and SensorsElectron and X-Ray Spectroscopy TechniquesElectronic and Structural Properties of Oxides

Corrosion Behaviour of Cast Nickel Aluminium Bronze in Sea Water

Emrullah Culpan、G. R. F. Rose1979-01-01British Corrosion Journal

AbstractCorrosion trials have been carried out using cast nickel aluminium bronze alloy in the as cast, heat treated and welded states, and the specimens examined using optical and electron optical techniques. It has been shown that selective phase corrosion can occur near the heat affected zone of welded cast nickel…

Aluminum Alloy Microstructure PropertiesNanoporous metals and alloysMetallurgy and Material Science

Recrystallization Textures of Silver, Copper and α‐Brasses With Different Zinc‐Contents as a Function of the Rolling Temperature

Ursula Schmidt、Kurt Lücke1979-01-01Texture Stress and Microstructure

The recrystallization textures of copper and different Cu‐Zn alloys as well as the rolling and recrystallization textures of silver of varying purity were investigated as a function of the rolling temperature. In all cases in which the pure copper type rolling texture was present the cube texture was found as recrysta…

Metallic Glasses and Amorphous AlloysAluminum Alloy Microstructure PropertiesMetallurgy and Material Science

Neutron Irradiation-Induced Defect Structures in Zirconium

A. Jostsons、PM Kelly、RG Blake 等 4 位作者1979-01-01OpenAlex

A transmission electron microscope (TEM) was used to study the neutron irradiation-induced defect structures in zirconium from various sources irradiated to fluences up to 1.3 × 1025 neutrons (n)/m-2 > 0.1 MeV and temperatures in the range 478 to 823 K. Below 673 K the predominant form of damage consists of ⅓ 〈…

Fusion materials and technologiesNuclear Materials and PropertiesNuclear materials and radiation effects

Characterization of pyrimidine-repressible and arginine-repressible carbamyl phosphate synthetases from Bacillus subtilis

Thomas J. Paulus、Robert L. Switzer1979-01-01Journal of Bacteriology

The number and properties of carbamyl phosphate synthetases in Bacillus subtilis have been uncertain because of conflicting genetic results and instability of the enzyme in extracts. The discovery of a previously unrecognized requirement of B. subtilis carbamyl phosphate synthetases for a high concentration of potassi…

Enzyme Structure and FunctionPolyamine Metabolism and ApplicationsBiochemical and Molecular Research

Lois de variations et ordre de grandeur de la conductivité alternative des chalcogénures massifs non cristallins.

X. Le Cleac’h1979-01-01Journal de physique

L'étude de la conductivité alternative σ(ω) des chalcogénures massifs non cristallins (Se, As2S3, As2Se 3, (As2Te3)1-xGex, Se 1-xGex) a été effectuée dans de grands domaines de fréquence (1 kHz-35 GHz) et de température (100-300 K). Deux effets de contact, l'un observable aux basses fréquences et l'autre au-dessus de…

Glass properties and applicationsCrystal Structures and PropertiesPhase-change materials and chalcogenides

Wide-angle X-ray scattering study of structural parameters in non-crystalline polymers

R. Lovell、Geoffrey R. Mitchell、Alan H. Windle1979-01-01Faraday Discussions of the Chemical Society

The paper presents an analysis of WAXS (wide-angle X-ray scattering) data which aids an understanding of the structure of non-crystalline polymers. Experimental results are compared with calculations of scattering from possible models. Evidence is presented which supports the view that the chains in molten PE do not l…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Absorption of hydrogen by titanium–cobalt and titanium–nickel intermetallic alloys. Part 1.—Experimental results

Robert Burch、Nigel B. Mason1979-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

Pressure–composition–temperature relationships are presented for the titanium–cobalt + hydrogen and the titanium–nickel + hydrogen systems for the ranges 10 kPa to 2 MPa and 325 to 600 K. The TiCo + H system exhibits three distinct two-phase regions, whereas the TiNi + H system contains no two-phase regions in this ra…

Advanced Chemical Physics StudiesHydrogen Storage and MaterialsNuclear Materials and Properties

Metallurgy of galvanized coatings

J. Mackowiak、N. R. Short1979-01-01International Metals Reviews

In this review the authors cover both the scientific and practical aspects of the metallurgy of galvanized coatings. They begin the review by considering the current iron—zinc equilibrium phase diagram; special emphasis is placed on the correlation between the actual phases found in galvanized coatings and those which…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityMaterial Properties and Failure Mechanisms

Mechanical properties and structure of extremely strainhardened copper

S. Erbel1979-01-01Metals Technology

Specimens of 99·9 %purity copper were deformed initially by torsion up to €=200. Their mechanical properties were determined from tensile tests. The extreme values of mechanical properties were observed in a range of strain €=3−200. Changes in microstructure reflecting the mechanicalproperties of the specimens were in…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsPowder Metallurgy Techniques and Materials

Rapid reversible fission of a C–H bond in a metal complex: X-ray crystal structure of [RhHCl(Bu t 2 PCH 2 CH 2 CHCH 2 CH 2 PBu t 2 )]

Christopher Crocker、R. John Errington、Walter S. McDonald 等 6 位作者1979-01-01Journal of the Chemical Society Chemical Communications

The occurrence and stereochemistry of a rapid reversible C–H fission in [[graphic omitted]But2)] is established by n.m.r. spectroscopy, including triple resonance INDOR, and by X-ray crystallography.

Magnetism in coordination complexesFluorine in Organic ChemistryAdvanced NMR Techniques and Applications

Determination of Self‐Concentration Quenching Mechanisms of Rare Earth Luminescence from Intensity Measurements on Powdered Phosphor Screens

Lyuji Ozawa1979-01-01Journal of The Electrochemical Society

It has been demonstrated that self‐concentration quenching mechanisms can be determined from luminescence intensity measurements as a function of activator concentration if the excitation of a powdered phosphor screen is made with the directly and weakly absorbed radiation.

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator Technologies

Dendrite growth in eutectic alloys: the coupled zone

W. Kurz、David J. Fisher1979-01-01International Metals Reviews

Casting alloys of eutectic composition are of great practical importance. Good microstructural control of these alloys is essential in obtaining the required properties in the cast state. Primary phases present in a eutectic matrix may have either a beneficial or a detrimental effect on these properties. Therefore, th…

Aluminum Alloy Microstructure PropertiesHigh Temperature Alloys and CreepSolidification and crystal growth phenomena

Isothermal growth, thickening and melting of poly(ethylene oxide) single crystals in the bulk. Part 4.—Dependence of pathological crystal habits on temperature and thermal history

André J. Kovacs、C. Straupé1979-01-01Faraday Discussions of the Chemical Society

Characteristic features of isothermal growth, thickening and melting behaviour of melt grown single crystals of low molecular weight poly(ethylene oxide) fractions are described and discussed in terms of their relevance to basic concepts of polymer crystal growth. In the narrow temperature interval where transition fr…

Polymer crystallization and propertiesRheology and Fluid Dynamics Studies

Optics of cholesteric liquid crystals

V. A. Belyakov、В. Е. Дмитриенко、V.P. Orlov1979-01-01Uspekhi Fizicheskih Nauk

УСПЕХИ ФИЗИЧЕСКИХ Η Λ У К 535.44 ОПТИКА ХОЛЕСТЕРИЧЕСКИХ ЖИДКИХ КРИСТАЛЛОВ В. А. Беляков, В, Е. Дмитриеико, В. П. Орлов СОДЕРЖАНИЕ 1. Введение 221 2. Кинематическое рассмотрение 224 а) Сечение рассеяния (225).б) Поляризационные характеристики (226).3. Случай нормального падения 227 а) Собственные волны (227).б) Решение…

Liquid Crystal Research Advancements