Materials Literature
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This paper focuses attention on the intrazeolite anchoring of ruthenium carbonyl clusters and their catalytic performances. The synthesis involves the adsorption of metal carbonyl species or metal ion exchange into zeolite cages followed by reductive carbonylation under a mixed CO and H 2 atmosphere. The characterizat…
ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTSynthesis of Soluble Fluorinated Vinyl Ether Copolymers by Ionic Addition of Fluoroolefins to Poly(vinyl alcohol)Andrew E. Feiring and Edward R. WonchobaView Author Information DuPont Central Research & Development, Experimental Station, P.O. Box 80328, Wilmington, Delaware 198…
The magnetization of Ni_{1-x}Mo_{x} single crystals with x=4,6,8 and 10 % by weight have been measured at 4.2K using a vibrating sample magnetometer and a Superconducting Quantum Interference Device (SQUID). The magnetization of the alloy at these low concentrations and at 0 K have been theoretically determined by usi…
The well-known and general “compressibility theorem” for pure substances relates κT =−(∂ ln V/∂p)N,T to a spatial integral involving the pair correlation function g(2). The isochoric inherent structure formalism for condensed phases separates g(2) into two fundamentally distinct contributions: a generally anharmonic v…
The exact mean-field phase behavior of the Semenov–Vasilenko model for rod-coil diblock copolymers is studied by applying self-consistent field techniques. The behavior depends on three quantities: the rod/coil immiscibility χN, the coil volume fraction f, and the ratio ν of the characteristic coil to rod dimensions.…
The electron transport coefficients, the drift velocity W , the product of the gas number density and the longitudinal diffusion coefficient and the ratio of the longitudinal diffusion coefficient to the electron mobility of electrons were measured in pure oxygen over the range 1.7-350 Td and in two oxygen-argon mixtu…
Solid phase epitaxial growth of ion beam-amorphized α-quartz has been studied by means of Rutherford backscattering spectrometry in channeling geometry. α-quartz single crystals were irradiated with Cs+ and Xe+ ions and annealed in air or in vacuum at 500–900 °C. Complete epitaxial regrowth has been observed in the Cs…
Fatigue phenomena occurring in Pb(ZrxTi1−x)O3 ferroelectric thin-film capacitors (FECAP) with Pt electrodes are studied by means of conduction measurements in the cold-field-emission (tunneling) regime. We have determined that conduction in virgin FECAPs is controlled by tunneling at temperatures 100–140 K and electri…
Based upon kinetic Monte Carlo simulations of crystallization in a simple polymer model we present a new picture of the mechanism by which the thickness of lamellar polymer crystals is constrained to a value close to the minimum thermodynamically stable thickness. This description contrasts with those given by the two…
Non-dipolar effects in the angular distribution of core level photoemission are shown to have a substantial influence on the interpretation of x-ray standing wavefield determinations of surface adsorption structures when the x-ray absorption is monitored by photoemission, even at photon energies below 3 keV. Results f…
We observed the emission of correlated electron pairs from the valence band of solids following the absorption of single photons in the vacuum ultraviolet range. Applying a time-of-flight technique, we measured the energy distributions of correlated electron pairs emitted from clean Cu(001) and Ni(001) crystals. Signi…
We demonstrate that a staggered parametric ac driving term can support stable progressive motion of a soliton in a Toda lattice with friction, while an unstaggered drivng force cannot. A physical context of the model is that of a chain of anharmonically coupled particles adsorbed on a solid surface of a finite size. T…
Nano-crystalline diamond is prepared with a unique method in which a graphite target is etched by a high-power pulsed laser in water. Transmission electron microscopy (TEM) and high resolution electron microscopy (HREM) indicate nano-crystalline diamond is obtained, having a hexagonal lattice or cubic lattice.
Triethoxysilane HSi(OEt)3 was used as coupling agent to graft a poly(organophosphazene) (POPZ) containing allylic functions to the surface of poly(vinyl alcohol) or poly(ethylene-co-vinyl alcohol) films. Hydrolyzed HSi(OEt)3, which contained both inorganic (Si–OH) and organic (Si–H) reactivities, acted at the interfac…
The preparation of a novel triaryl phosphine oxide thermoset polymer containing the perfluorocyclobutane linkage is described. The synthetic methodology involves the formation of a Grignard reagent from 4-bromotrifluorovinyloxybenzene and reaction with phosphorous trichloride to form the triaryl phosphine trifluorovin…
Composites were made from rubberwood in the form of fibers (RWF) and powder (RWP) and high-density polyethylene (HDPE). The RWP–HDPE composites showed higher tensile strength than those of the fibers. The inferior properties of the RWF-filled composites were believed to be attributed to the agglomeration of the fibers…
The isothermal and nonisothermal crystallization kinetics of nonnucleated and nucleated isotactic polypropylene (iPP) were investigated by DSC and a polarized light microscope with a hot stage. Dibenzylidene sorbitol (DBS) was used as a nucleating agent. It was found that the crystallization rate increased with the ad…
A new type of bamboo fiber-reinforced polypropylene (PP) composite was prepared and its mechanical properties were tested. To enhance the adhesion between the bamboo fiber and the polypropylene matrix, maleic anhydride-grafted polypropylene (MAPP) was prepared and used as a compatibilizer for the composite. The maleic…
Selective formation of trans-nitrochlorins 16-19, cyclopropylchlorins 14, 15, and 20-23, or functionalized trans-chlorins 5-13 by reaction of 2-nitro-5,10,15,20-tetraphenylporphyrin 1 with "active" methylene compounds such as malonates or malononitrile in the presence of base has been achieved. Reaction control is acc…
Highly porous matrices of poly-L-lactide (PL) and polyglycolide (PG), 24, 50, or 95 mg/cc in the form of 10 x 10 x 3 mm wafers, were implanted subcutaneously (two per rat) in the flanks of 8-12-week-old female Lewis rats (n = 120). Matrices were harvested, two rats per week, for 15 weeks and examined histologically. A…