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Investigations on the stability of thiol stabilized semiconductor nanoparticles

Herwig Döllefeld、Kathrin Hoppe、Joanna Kolny‐Olesiak 等 6 位作者2002-01-01Physical Chemistry Chemical Physics

Various analytical methods like analytical ultracentrifugation, UV–vis absorption spectroscopy, NMR spectroscopy, and powder X-ray diffraction have been applied to study the stability of thiol stabilized semiconductor nanoparticles. Reduced particle sizes were found in solution at low concentrations. Most probably the…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Grafting sulfobetaine monomer onto the segmented poly(ether-urethane) surface to improve hemocompatibility

Y. L. Yuan、F. Ai、J. Zhang 等 6 位作者2002-01-01Journal of Biomaterials Science Polymer Edition

Polyurethanes are widely used as blood-contacting biomaterials, due to their good biocompatibility and mechanical properties. Nevertheless, their blood compatibility is still not adequate for more demanding applications. Surface modification is an effective way to improve the hemocompatibility for biomaterials. The pu…

Orthopaedic implants and arthroplastyElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Crash-worthiness assessment of thin-walled structures with the high-strength steel sheet

Hoon Huh、Woo-Jong Kang2002-01-01International Journal of Vehicle Design

The crashworthiness of thin-walled structures has been investigated for the high-strength steel 60TRIP and 60C as well as the low-carbon steel by both experiments and numerical simulation. Crush tests have been carried out for square tubes of various heights in order to observe the crush behaviour, the reaction force…

Cellular and Composite StructuresHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Preparation of cross-linked biocompatible poly(2-methacryloyloxyethyl phosphorylcholine) gel and its strange swelling behavior in water/ethanol mixture

Yoshihiro Kiritoshi、Kazuhíko Ishihara2002-01-01Journal of Biomaterials Science Polymer Edition

Functional cross-linked poly(2-methacryloyloxyethyl phosphorylcholine(MPC)) gels were prepared with various cross-linkers by conventional radical polymerization in aqueous media. The poly(MPC) gels swelled in water and have a large degree of swelling compared with that of poly(2-hydroxyethyl methacrylate). The swellin…

Hydrogels: synthesis, properties, applicationsElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Preparation and photo-physical characterisation of nanocomposites obtained by intercalation and co-intercalation of organic chromophores into hydrotalcite-like compounds

Gian Gaetano Aloisi、Umberto Costantino、Fausto Elisei 等 6 位作者2002-01-01Journal of Materials Chemistry

Several chromophores with donor–acceptor properties and containing a carboxylic or sulfonic group [coumarin-3-carboxylic acid (3-CCA), 9-anthracenecarboxylic acid (9-ACA), 4-benzoylbenzoic acid (4-BBA) and 2-naphthalenesulfonic acid (2-NSA)] have been intercalated into Mg–Al hydrotalcite-like compounds, both via anion…

Mesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and ApplicationsSilicone and Siloxane Chemistry

Synthesis of Siliceous Hollow Spheres with Ultra Large Mesopore Wall Structures by Reverse Emulsion Templating

Chengzhong Yu、Bozhi Tian、Jie Fan 等 5 位作者2002-01-01Chemistry Letters

Abstract By using reverse emulsion templating, siliceous hollow spheres with ultra large mesopore wall structures (∼50 nm in pore diameter, ∼200 nm in wall thickness) have been synthesized with a high surface area (674 m2/g) and pore volume (1.25 cm3/g).

Mesoporous Materials and CatalysisPickering emulsions and particle stabilizationCovalent Organic Framework Applications

Lattice dynamic investigation of Raman and infrared wavenumbers at the zone center of orthorhombic RFeO3 (R = Tb, Dy, Ho, Er, Tm) perovskites

Himanshu Gupta、Manoj K. Singh、Lokender Tiwari2002-01-01Journal of Raman Spectroscopy

Abstract A short‐range force constant model was applied for the first time to investigate the phonons in RFeO 3 ( R = Tb , Dy, Ho, Er, Tm) perovskites in the orthorhombic phase. The calculations with the 12 stretching and three bending force constants provide good agreement for the observed Raman and infrared wavenumb…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsSolid-state spectroscopy and crystallography

Strain Gradient Elasticity for Antiplane Shear Cracks: A Hypersingular Integrodifferential Equation Approach

Albert Fannjiang、Gláucio H. Paulino、Youn-Sha Chan2002-01-01SIAM Journal on Applied Mathematics

We consider Casal's strain gradient elasticity with two material lengths $\ell,{\ell}'$ associated with volumetric and surface energies, respectively. For a Mode III finite crack we formulate a hypersingular integrodifferential equation for the crack slope supplemented with the natural crack-tip conditions. The full-f…

Composite Structure Analysis and OptimizationNumerical methods in engineeringNonlocal and gradient elasticity in micro/nano structures

Comparison of the Lifshitz–van der Waals/acid–base and contact angle hysteresis approaches for determination of solid surface free energy

Henryk Radelczuk、Lucyna Hołysz、Emil Chibowski2002-01-01Journal of Adhesion Science and Technology

Total surface free energy, γS TOT, for several solids (glass, PMMA, duralumin, steel and cadmium) was calculated from the surface free energy components: apolar Lifshitz–van der Waals, γS LW, and acid–base electron–donor, γS -, and electron–acceptor, γS +. Using van Oss and coworkers' approach (Lifshitz–van der Waals/…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

Cerium(III) Inhibition of Corrosion-Driven Organic Coating Delamination Studied Using a Scanning Kelvin Probe Technique

G. Williams、H. N. McMurray、David Worsley2002-01-01Journal of The Electrochemical Society

The scanning Kelvin probe is used to study the influence of trivalent cerium cations ( Ce 3 + ) on the kinetics and mechanism of corrosion-driven delamination processes affecting polyvinyl butyral (PVB) coatings adherent to the intact zinc surface of hot dip galvanized steel. Placing aerated aqueous sodium chloride on…

Corrosion Behavior and InhibitionAnalytical Chemistry and SensorsConcrete Corrosion and Durability

Mechanical Properties, Water Vapor Permeabilities and Solubilities of Highly Carboxymethylated Starch‐Based Edible Films

K.W. Kim、Cheul Jong Ko、H.J. Park2002-01-01Journal of Food Science

ABSTRACT: Tensile strength (TS), elongation (E), water vapor permeabilities (WVP) and solubilities were determined for highly carboxymethylated starch (HCMS)‐based edible films plasticized with sorbitol (S), xylitol (X), mannitol (M) and glycerol (G). TS and E of HCMS‐based film increased as the concentration of plast…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Combined wavelet transform and regression technique for secondary current compensation of current transformers

F. Li、Y. Li、R.K. Aggarwal2002-01-01IEE Proceedings - Generation Transmission and Distribution

A technique is proposed to effectively and efficiently compensate for secondary current of current transformers, particularly in the presence of remanent flux. The technique first utilises the wavelet transform to accurately distinguish the distorted section from the healthy section of a secondary current waveform. Se…

Power Quality and HarmonicsMagnetic Properties and ApplicationsAdvanced Electrical Measurement Techniques

Effects of Acetan on Production of Bacterial Cellulose by Acetobacter xylinum

Takehiko Ishida、Yasushi Sugano、Tomonori Nakai 等 4 位作者2002-01-01Bioscience Biotechnology and Biochemistry

Acetan is a water-soluble polysaccharide produced by a bacterial cellulose (BC) producer, Acetobacter xylinum. An acetan-nonproducing mutant, EP1, was generated from wild-type A. xylinum BPR2001 by the disruption of aceA, which may act to catalyze the first step of the acetan biosynthetic pathway in this bacterium. EP…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesPolysaccharides and Plant Cell Walls

Self-assembled molecular films of tetraamino metal (Co, Cu, Fe) phthalocyanines on gold and silver. Electrochemical and spectroscopic characterization

M. P. Somashekarappa、J. Keshavayya、S. Sampath2002-01-01Pure and Applied Chemistry

Abstract The formation of molecular films of 2,9,16,23-tetraamino metal phthalocyanines [TAM(II)Pc; M (II) = Co, Cu, and TAM(III)Pc; M = Fe] by spontaneous adsorption on gold and silver surfaces is described. The properties of these films have been investigated by cyclic voltammetry, impedance, and FT-Raman spectrosco…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresElectrochemical Analysis and Applications

Corrosion Control Using Polyelectrolyte Multilayers

Tarek R. Farhat、Joseph B. Schlenoff2002-01-01Electrochemical and Solid-State Letters

The corrosion of stainless steel under anodic conditions in salt solutions was strongly suppressed by an ultrathin layer of polyelectrolyte complex, applied using the layer-by-layer deposition method. Voltammetric scans over a wide potential region, as well as constant potential measurements in the metastable pitting…

Polymer Surface Interaction StudiesMolecular Junctions and NanostructuresDendrimers and Hyperbranched Polymers

Chemical synthesis of molybdenum disulfide nanoparticles in an organic solution

Dominique Duphil、Stéphane Bastide、Claude Lévy‐Clément2002-01-01Journal of Materials Chemistry

Molybdenum disulfide, MoS2, nanoparticles can be synthesized either at high temperature as mono- and polycrystalline materials or at low temperature using various (electro)chemical routes. In the work presented, MoS2 nanoparticles were obtained using a low temperature (140 °C) method via a chemical solution reaction r…

2D Materials and ApplicationsCatalysis and Hydrodesulfurization StudiesMXene and MAX Phase Materials

Inhibition of Corrosion-Related Reduction Processes via Chromium Monolayer Formation

William J. Clark、Richard L. McCreery2002-01-01Journal of The Electrochemical Society

The oxygen reduction reaction (ORR) was examined on copper, platinum, and glassy carbon electrodes, with regard to its inhibition by exposure of the electrode to chromate ion in NaCl solution. All three electrode materials exhibited a mass transport limited current for the ORR at sufficiently negative potentials, but…

Corrosion Behavior and InhibitionElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Modeling of coalescence in polymer blends

SuPing Lyu、Frank S. Bates、Christopher W. Macosko2002-01-01AIChE Journal

Abstract Coalescence in polymer blends was modeled by combining population dynamics with three coalescence theories: Smoluchowski, trajectory, and film drainage. Modeling results are compared with our previous coalescence experiments on polystyrene/high density polyethylene blends. Comparison of the Smoluchowski theor…

Polymer crystallization and propertiesMicroplastics and Plastic PollutionRheology and Fluid Dynamics Studies

The Crystal Chemistry of Beryllium

F. C. Hawthorne、D. M.C. Huminicki2002-01-01Reviews in Mineralogy and Geochemistry

Research Article| January 01, 2002 The Crystal Chemistry of Beryllium Frank C. Hawthorne; Frank C. Hawthorne Department of Geological Sciences, University of Manitoba, Winnipeg, Manitoba, Canada R3T 2N2, frank_hawthorne@umanitoba.ca Search for other works by this author on: GSW Google Scholar Danielle M.C. Huminicki D…

Crystal Structures and PropertiesIron-based superconductors researchMineralogy and Gemology Studies

Development of magnetic refrigerator for room temperature application

Naoki Hirano2002-01-01AIP conference proceedings

This paper describes experimental results of a magnetic refrigerator operated at room temperature. Spheres of Gadolinium, 2.2 kg in weight and 0.3 mm in diameter, are used as a magnetic working material. The magnetic materials were divided into two vessels and reciprocated between high and zero magnetic fields. High m…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Thermodynamics and Statistical Mechanics