Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
The addition of HCN to 4-alkylcyclohexanones 1 to give cyanohydrins 2 is strongly catalyzed by hydroxy-ni trile lyases (HNLs). With PaHNL, from bitter almond, trans-addition occurs almost exclusively, yielding trans-2. With MeHNL, from cassava, cis-addition is preferred to give cis-2. cis-Selectivity is nearly quantit…
Residual mechanical stresses from manufacturing always exist in freshly extruded HV cables. These stresses are not uniformly distributed in the cable insulation bulk material. Five different HV cables were analyzed with respect to residual mechanical stresses and dielectric breakdown strength. Photoelastic measurement…
Three simulation methodologies have been employed to investigate the growth, nucleation, and structure of oxides supported on oxide substrates, these are atom-by-atom deposition, layer-by-layer deposition and finally amorphisation of a structure followed by recrystallisation. The materials which have been investigated…
The outcome of the reaction of the bifunctional reagent p-aminophenol (HO-C6H4-NH2) with the cyclic triphosphazene [N3P3Cl6] is very dependent on the solvent, the temperature, and the proton abstractor. In THF at room temperature with K2CO3 the reaction is very slow and takes place only through the NH2 group to give a…
Experimental results on the propagation of positive streamers along contoured, axially symmetric, polytetrafluoroethylene (PTFE) insulation surfaces are presented. A plane parallel electrode configuration provides a substantially uniform electric field for streamer propagation and a point electrode at the ground plane…
Abstract Hoganite, copper(II) acetate monohydrate, and paceite (pronounced ‘pace-ite’), calcium(II) copper(II) tetraacetate hexahydrate, occur as isolated crystals embedded in ferruginous gossan from the Potosi Pit, Broken Hill, New South Wales, Australia. They are associated with goethite, hematite, quartz, linarite,…
Bioassay-guided fractionation of the ethyl acetate extract of the roots of Dalea scandens (Miller) R. Clausen var. paucifolia led to the isolation of new flavonoids, 2( S)-5'-(-1"',1"'-dimethylallyl)-8-(3",3"-dimethylallyl)-2',4',5,7-tetrahydroxyflavanone, 2( S)-5'-(1"',1"'-dimethylallyl)-8-(3",3"-dimethylallyl)-2'-me…
The relaxation of strain in the ZnS epilayers grown on (100) GaP was investigated with resonant Raman scattering measurement. The single LO phonon resonant Raman shift and the intensity increased but the full width at half maximum decreased with the increasing ZnS epilayer thickness. These were attributed to the relax…
The microphase separation and morphology of symmetric diblock copolymer thin films confined in a slit with neutral or attractive surfaces were studied by the cell dynamic system method (CDS) and Monte Carlo simulation. The size effect, especially in CDS, was carefully investigated indicating that excessively small siz…
Abstract A natural phengite-2 M 1 of composition (K 0.95 Na 0.05 )(Al 0.76 Fe 0.14 Mg 0.10 ) 2 (Si 3.25 Al 0.75 )O 10 (OH 1.96 F 0.04 ) [ a = 5.2173(1) Å, b = 9.0493(2) Å, c = 19.989 (1) Å and β = 95.734(4)°] was studied using in situ high-temperature FTIR. Correlations to structural changes were made using previously…
General behavior principles (GBPs) first introduced in 1976 (H. K. Fauske, the Role of Core-Disruptive Accidents in Design and Licensing of LMFBRs, Nuclear Safety, Vol. 17, No. 5, 550–567, 1976) are applied to assess the core disruptive accident (CDA) outcome for a large (3,500MWt) high power density oxide-fueled sodi…
Monte Carlo computer simulations were used to investigate the interlayer structure of Ca-montmorillonite for hydration levels ranging from the dry clay to a three-layer system. Our model of montmorillonite consists of negative charge sites in both the octahedral and tetrahedral layers. Our results are compared with X-…
Abstract The effect of increasing the concentration of sorghum wax paste on the characteristics of soy protein isolate (SPI) films was investigated. Water vapor permeability (WVP), tensile strength (TS), elongation at break (E), and total soluble matter (TSM) of cast SPI films were determined. Sorghum wax paste extrac…
Die Synthesen zweier neuer Heteropolyanionen des M2X2W20-Typs mit Antimon als Heteroatom werden vorgestellt. Sie wurden durch vollständige Röntgenstrukturanalysen und spektroskopische Analysen charakterisiert. Die Verbindung Na6(NH4)4[Zn2(H2O)6(WO2)2(SbW9O33)2]·36H2O (1) kristallisiert monoklin (P21/n) mit a = 12, 873…
Abstract Scientists are more and more interested in biodegradable materials owing to their environmental advantage. We investigated viscoelastic properties of a newly developed biomaterial made from epoxidized soybean oil (ESO). ESO cross‐linked by triethylene glycol diamine exhibited viscoelastic solid properties. Th…
The aggregation behavior of meso-tetrakis(4-sulfonatophenyl)porphyrin, [ H 2 ( TPPS 4 )] 4- , in the presence of hydrated polyethyleneimine ( PEI ) in aqueous solutions (1.6 < pH < 7.6) has been investigated. The interaction leads to the formation of a variety of pH dependent species, which have been attributed…
Textiles are used in many industrial applications, especially in papermaking. During the pressing of paper, felts are used to recover the water expressed from the wet sheet. To improve this operation, felt structures have to be characterized. X-ray microtomography is a powerful tool for reconstructing the complex orga…
Abstract The adsorption of 13 C-labeled benzene on imogolite has been studied on samples which had been evacuated and then heated to remove water below their decomposition point. After adsorption of labeled benzene, the samples were studied by nuclear magnetic resonance using non-spinning techniques. The results show…
Abstract Two varieties of Zn-smectite were synthesized hydrothermally: sauconite, with an ideal composition of Na 0.4 Zn 3 (Si 3.6 Al 0.4 )O 10 (OH) 2 · n H 2 O; and a Zn equivalent of hectorite, with an ideal composition of Na 0.4 (Li 0.4 Zn 2.6 )Si 4 O 10 (OH) 2 · n H 2 O (referred to here as Zn-hectorite). For comp…
Three new members of the copper/carboxylato/heterocyclic diimine family, namely [Cu(GLYO)(2, 2′-bipy)]2 · nH2O (n = 4 (1) or 6 (2), H2GLYO = glycolic acid, 2, 2′-bipy = 2, 2′-bipyridine) and {[Cu(AcO)2(4, 4′-bipy)] · 3H2O}n (3) (AcO = acetato, 4, 4′-bipy = 4, 4-bipyridine), have been synthesized and characterized by I…