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Dynamics of spin-state interconversion and cooperativity for ferric spin-crossover complexes in the solid state. 5. Variable-temperature spectroscopic, magnetic, and single-crystal x-ray structural characterizations of the spin-state and order-disorder transformations of a Schiff base complex

Mark D. Timken、Charles E. Strouse、S. Michael Soltis 等 7 位作者1986-02-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDynamics of spin-state interconversion and cooperativity for ferric spin-crossover complexes in the solid state. 5. Variable-temperature spectroscopic, magnetic, and single-crystal x-ray structural characterizations of the spin-state and order-disorder transformations of a S…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Superplastic deformation characteristics of microduplex Ti–6Al–4V alloy

M. T. Cope、N. Ridley1986-02-01Materials Science and Technology

A study has been made of the superplastic tensile behaviour of a microduplex Ti–6AI–4V alloy in the temperature range 760–940°C. Maximum superplastic elongations were obtained for a temperature of 880°C at which the volume fraction of β–phase was approximately 0·4. At temperatures below about 850°C, the main microstru…

Microstructure and mechanical propertiesOrthopaedic implants and arthroplastyTitanium Alloys Microstructure and Properties

Structure, stability, and bonding in cyclodiphosphazene and cyclotriphosphazene

Georges Trinquier1986-02-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructure, stability, and bonding in cyclodiphosphazene and cyclotriphosphazeneGeorges. TrinquierCite this: J. Am. Chem. Soc. 1986, 108, 4, 568–577Publication Date (Print):February 1, 1986Publication History Published online1 May 2002Published inissue 1 February 1986https://…

Synthesis and characterization of novel inorganic/organometallic compoundsFlame retardant materials and propertiesThermal and Kinetic Analysis

Method for variation of grain size in studies of gas-solid reactions involving calcium oxide

Robert H. Borgwardt、Nancy F. Roache、Kevin R. Bruce1986-02-01Industrial & Engineering Chemistry Fundamentals

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMethod for variation of grain size in studies of gas-solid reactions involving calcium oxideRobert H. Borgwardt, Nancy F. Roache, and Kevin R. BruceCite this: Ind. Eng. Chem. Fundamen. 1986, 25, 1, 165–169Publication Date (Print):February 1, 1986Publication History Published…

Crystallization and Solubility StudiesThermal and Kinetic AnalysisCyclone Separators and Fluid Dynamics

Experimental criterion for the crystallization regime in polymer crystals grown from dilute solution: Possible limitation due to fractionation

J. J. Point、M.‐Ch. Colet、M. Dosière1986-02-01Journal of Polymer Science Part B Polymer Physics

Abstract By integration of equations previously derived by Frank, the growth rate of polymer crystals is shown to be dependent on their size, provided that the persistence length L p or the kinetic length L k = (2 g / i ) 1/2 are significantly larger than the primary nucleus. A new method of decorating the fold surfac…

Polymer crystallization and propertiesEffects and risks of endocrine disrupting chemicalsRheology and Fluid Dynamics Studies

IR transition moment directions in matrix-isolated dimethylsilylene and 1-methylsilene

Gerhard Raabe、Hrvoj Vančik、Robert West 等 4 位作者1986-02-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIR transition moment directions in matrix-isolated dimethylsilylene and 1-methylsileneGerhard. Raabe, H. Vancik, Robert. West, and Josef. MichlCite this: J. Am. Chem. Soc. 1986, 108, 4, 671–677Publication Date (Print):February 1, 1986Publication History Published online1 May…

Inorganic and Organometallic ChemistrySolid-state spectroscopy and crystallographyChemical Thermodynamics and Molecular Structure

Heating in crystalline solids due to rapid deformation

J. Philip Miller、Charles S. Coffey、V. F. DeVost1986-02-01Journal of Applied Physics

We present experimental evidence that during rapid deformation of at least some crystalline and polymeric solids heat is generated at unexpectedly high temperatures beginning essentially at the moment deformation begins. The heat was observed by fast infrared sensors. Both the initial infrared emissions and the appare…

High-Velocity Impact and Material BehaviorFire effects on concrete materialsMaterial Properties and Failure Mechanisms

Quadruple reentrance (nematic-smectic-Ad-nematic-smectic-Ad-nematic-smectic-A1) from the frustrated spin-gas model of liquid crystals

Joseph O. Indekeu、A. Nihat Berker1986-02-01Physical Review A

The microscopic ``spin-gas'' model reproduces and physically explains the sequence of liquid-crystal phases, nematic--smectic-${A}_{d}$--nematic--smectic-${A}_{d}$ --nematic--smectic-${A}_{1}$, which was observed with decreasing temperature in recent experiments. The microscopic frustration inherent to smectic structu…

Liquid Crystal Research AdvancementsTheoretical and Computational PhysicsNonlinear Dynamics and Pattern Formation

Dislocation and void segregation in copper during neutron irradiation

B.N. Singh、T. Leffers、A. Horsewell1986-02-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

High-purity (99·999%) and fully annealed copper specimens have been irradiated in the DR-3 reactor at Ris⊘ to doses of 1 × 1022 and 5 × 1022 neutrons (fast)m−2 (2 × 10−3 dpa and 1 × 10−2 dpa, respectively); the irradiation experiments were carried out at 250°C. The irradiated specimens were examined by transmission el…

Microstructure and mechanical propertiesFusion materials and technologiesNuclear Materials and Properties

Power distribution techniques for VLSI circuits

W.S. Song、L.A. Glasser1986-02-01IEEE Journal of Solid-State Circuits

The onchip power distribution problem for highly scaled technologies is investigated. Metal migration and line resistance problems as well as ways to optimize multilayer metal technology for low resistance, low current density, and maximum wirability are also investigated. Fundamental lower limits and the limiting fac…

Semiconductor materials and devices3D IC and TSV technologiesCopper Interconnects and Reliability

Cloning, overproduction, and purification of the B2 subunit of ribonucleoside-diphosphate reductase

Scott P. Salowe、J. Stubbe1986-02-01Journal of Bacteriology

The nrdB gene, which encodes the B2 subunit of Escherichia coli ribonucleotide reductase (EC 1.17.4.1), was cloned into multicopy plasmid pSPS2. This vector, which contains the pL promoter of bacteriophage lambda and the tetracycline resistance gene of pBR322, was transformed into a lysogenic host with a thermolabile…

Microbial Natural Products and BiosynthesisRNA and protein synthesis mechanismsEnzyme Structure and Function

Preparation and Sintering of Homogeneous Silicon Nitride Green Compacts

T. M. Shaw、B. A. Pethica1986-02-01Journal of the American Ceramic Society

Interactions between silicon nitride particles and hydroxide precipitates were investigated using electrophoresis measurements. Conditions under which stable suspensions of silicon nitride particles and flocculation and heteroflocculation of silicon nitride/hydroxide mixtures occur were Identified. On the basis of the…

Concrete and Cement Materials ResearchAdvanced ceramic materials synthesisMagnesium Oxide Properties and Applications

The growth of large single crystals of lysozyme

Mitsuo Ataka、Shōji Tanaka1986-02-01Biopolymers

Abstract If protein single crystals larger than those suitable for x‐ray analysis are obtained, various spectroscopic, thermal, mechanical, and electrical measurements become possible. To understand the factors governing the crystal size, tetragonal lysozyme crystals were grown in batches at 15°C from solutions of dif…

Protein Structure and DynamicsEnzyme Structure and FunctionCrystallization and Solubility Studies

Formation of band textures in hydroxypropylcellulose liquid crystals

Patrick Navard1986-02-01Journal of Polymer Science Part B Polymer Physics

Abstract Upon shearing, some polymeric liquid crystals develop a particular texture, called “band texture,” consisting of fine equidistant black lines as viewed between crossed polarizers. In mesomorphic hydroxypropylcellulose–water solutions, these bands are due to relaxation of the shear. The band texture appears af…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsAdvanced Materials and Mechanics

Isothermal–isobaric computer simulations of melting and crystallization of a Lennard-Jones system

Shūichi Nosé、Fumiko Yonezawa1986-02-01The Journal of Chemical Physics

By means of constant-temperature, constant-pressure molecular dynamics techniques, we simulate the melting and crystallization processes of a model system composed of 864 Lennard-Jones (LJ) particles under periodic boundary conditions. On heating an fcc crystal of LJ particles, it is ascertained that melting takes pla…

Phase Equilibria and ThermodynamicsMaterial Dynamics and Propertiesnanoparticles nucleation surface interactions

Crystal structure and optical lattice vibrations of SbSBr crystals

作者信息未提供1986-02-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract The study of infrared reflection spectra of SbSBr crystals necessitated redetermination of its structure and revision of its description, along the lines of the isostructural compounds BiSCl, BiSBr and SbSeI. The cell constants are: a = 8.2424(6), b = 9.7556(4), c = 3.9680(2) Å, Z = 4; space group Pnam . The…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyOptical and Acousto-Optic Technologies

Topotactic Growth of β‐Alumina on α‐Alumina

David W. Susnitzky、C. B. Carter1986-02-01Journal of the American Ceramic Society

Thin foils of polycrystalline α‐alumina were reacted with a potassium‐rich vapor at ≤900°C. Potassium β‐alumina formed along α‐alumina grain boundaries and protruded from holes in the foils. Conventional transmission electron microscopy was used to analyze the α‐alumina/β‐alumina phase boundary for possible orientatio…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisMicrowave Dielectric Ceramics Synthesis

Thermochemistry and Structure of Low Pressure Chemically Vapor Deposited and Bulk SiO2 ‐ P 2 O 5 and SiO2 ‐ GeO2 Glasses

Maria Huffman、Alexandra Navrotsky、F. Pintchovski1986-02-01Journal of The Electrochemical Society

Heterogeneously (film) and homogeneously low pressure chemically vapor deposited (“snow”) SiO 2 ‐ P 2 O 5 and SiO 2 ‐ GeO 2 glass samples have been prepared at various temperatures. Bulk glass samples have also been made by melting the oxides. High temperature transposed drop and solution calorimetry have provided the…

Luminescence Properties of Advanced MaterialsAdvanced ceramic materials synthesisGlass properties and applications

Twin‐Related Tetragonal Variants in Yttria Partially Stabilized Zirconia

Nobuo Ishizawa、Atsushi Saiki、Takeshi Yagi 等 5 位作者1986-02-01Journal of the American Ceramic Society

Crystals of yttria partially stabilized zirconia were grown by the arc‐image floating‐zone technique and studied by transmission electron microscopy. Crystals annealed at 1700°C consist of tetragonal precipitates and a cubic matrix. The platelike domains in a precipitate are twin‐related tetragonal variants stacked al…

Advanced ceramic materials synthesisZeolite Catalysis and SynthesisNuclear materials and radiation effects

Vacancy loop formation in hydrogen-ion-implanted alpha-iron

F.R. Wan、S. Ohnuki、H. Takahashi 等 5 位作者1986-02-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

To investigate the behaviour of hydrogen in irradiated iron at high temperature, electron-irradiation and defect analysis have been carried out in a high-voltage electron microscope after H+−ion implantation. After the implantation, visible interstitial-type loops were formed at room temperature. However, in iron impl…

Fusion materials and technologiesHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties