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Spatially correlated nuclei: How the Johnson-Mehl-Avrami-Kolmogorov formula is modified in the case of simultaneous nucleation

M. Tomellini、M. Fanfoni、Manuela Volpe2000-11-01Physical review. B, Condensed matter

We present a theoretical investigation about the role played by spatial correlation among nuclei in the kinetics of first-order phase transitions. From the cluster expansion of the distribution functions in terms of the m-dots correlation functions, we obtain the equation which describes the kinetics in case of simult…

Polymer crystallization and propertiesMaterial Dynamics and Propertiesnanoparticles nucleation surface interactions

Effect of Atmosphere on Weight Loss in Sintered Silicon Carbide during Heat Treatment

Takayuki Nagano、Kenji Kaneko、Guodong Zhan 等 4 位作者2000-11-01Journal of the American Ceramic Society

Heat treatment was performed on β‐SiC with different sintering additives in the temperature range 1873–2073 K, in both argon and nitrogen‐gas atmospheres. In the case of the specimens heat‐treated at 2073 K in argon, the weight loss was more than the total weight of the sintering additives, except for B,C‐doped β‐SiC.…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Double exchange and the cause of ferromagnetism in doped manganites

Guo‐meng Zhao2000-11-01Physical review. B, Condensed matter

The coexistence of ferromagnetism and metallic conduction in doped manganites has long been explained by a double exchange model (ferromagnetic Kondo-lattice model) in which the ferromagnetic exchange arises from the carrier hopping. We evaluate the zero-temperature spin stiffness $D(0)$ and the Curie temperature ${T}…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Neutron diffraction of hole polaron ordering inLa1−xSrxMnO3(x≃18)

Y. Yamada、Jun Suzuki、Kenichi Oikawa 等 5 位作者2000-11-01Physical review. B, Condensed matter

The polaron-ordered structure of ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Sr}}_{x}{\mathrm{MnO}}_{3} (x\ensuremath{\cong}\frac{1}{8})$ has been reinvestigated to verify the previously proposed models. We found satellite reflections on the ${(0,k,l)}_{\mathrm{ortho}}$ and ${(1,k,l)}_{\mathrm{ortho}}$ reciprocal planes…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Surface-Enhanced Resonance Raman Scattering and Near-Infrared Fourier Transform Raman Scattering as in Situ Probes of Ink Jet Dyes Printed on Paper

C. Rodger、Geoffrey Dent、J. H. Watkinson 等 4 位作者2000-11-01Applied Spectroscopy

The characterization of ink jet dyes and inks printed onto paper surfaces is of importance for the development of ink jet ink formulations and for use in forensic science. Raman spectroscopy is an effective and informative probe for this purpose if problems associated with fluorescence are overcome. A comparison is ma…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy Techniques in Biomedical and Chemical ResearchIdentification and Quantification in Food

Superconductivity, Antiferromagnetism, and Phase Diagram of a Series of Organic Conductors: λ-(BETS)2FexGa1-xBryCl4-y

Hisashi Tanaka、H. Kobayashi、A. Kobayashi 等 4 位作者2000-11-01Advanced Materials

Organic conductors based on the bis(ethylenedithio)tetraselenafulvalene(BETS) are of interest because they display not only superconducting and magnetic transitions but also, as recently reported, unprecedented superconductor to insulator transitions. Here is presented the electrical and magnetic properties for two se…

Perovskite Materials and ApplicationsOrganic and Molecular Conductors ResearchInorganic Fluorides and Related Compounds

Photochromism of Diarylethenes Having Isopropyl Groups at the Reactive Carbons. Thermal Cycloreversion of the Closed-Ring Isomers

Seiya Kobatake、Kingo Uchida、Eriko Tsuchida 等 4 位作者2000-11-01Chemistry Letters

Abstract Diarylperfluorocyclopentenes having 2-isopropyl-5-phenylthiophene and 2-isopropyl-1-benzothiophene aryl groups underwent thermally reversible photochromism in solution. The photogenerated colored closed-ring isomers returned to the initial colorless open-ring isomers above 60 °C. The activation energies of th…

Photochromic and Fluorescence ChemistryPhotoreceptor and optogenetics researchPolydiacetylene-based materials and applications

Catalytic Behavior of Au Core / Pd Shell Bimetallic Nanoparticles on Silica Prepared by Sonochemical and Sol–Gel Processes

Kenji Okitsu、M. Murakami、Shuji Tanabe 等 4 位作者2000-11-01Chemistry Letters

Abstract A unique catalyst, Au core and Pd shell bimetallic nanoparticles immobilized on porous silica exhibiting a considerable high activity for the hydrogenation of cyclohexene, was prepared via two steps composed of the sonochemical reduction method and the sol–gel process under a low temperature condition.

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsNanomaterials for catalytic reactions

Functionalized diphenylchlorins and bacteriochlorins: their synthesis and bioconjugation for targeted photodynamic therapy and tumour cell imaging

Jonathan Sutton、Nelson Fernández、Ross W. Boyle2000-11-01Journal of Porphyrins and Phthalocyanines

A range of 5,15-diphenylporphyrins with symmetric and unsymmetric substitution patterns were subjected to osmium tetroxide-mediated dihydroxylations. The resulting chlorins and bacteriochlorins present an important group of compounds for studying structure-activity relationships of photodynamic sensitizers. The regios…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesHeme Oxygenase-1 and Carbon Monoxide

Defect formation and structural alternation in modified SiO2 glasses by irradiation with F2 laser or ArF excimer laser

Yoshiaki Ikuta、Shinya Kikugawa、Masahiro Hirano 等 4 位作者2000-11-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

The formation and restoration of defects by F2 laser irradiation with high laser fluence were investigated for modified silica glasses, and the results were compared with those by ArF excimer laser irradiation. F2 laser irradiation induced oxygen deficient centers (ODCs) and E′ centers via one-photon-absorption proces…

Glass properties and applicationsLaser Material Processing TechniquesBuilding materials and conservation

High-Speed Fracture of Elastomers: Part I

G. J. Lake、C. Lawrence、A. G. Thomas2000-11-01Rubber Chemistry and Technology

Abstract The fracture behavior of elastomers has been studied in the high speed region immediately above a transition region where a change in the nature of the fracture surface occurs. A video camera operating at up to 6000 frames/s was used to follow the progress of failure. The test pieces employed were of the pure…

Mechanical Behavior of CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Tiling the plane with noncongruent toric focal conic domains

Christophe Blanc、M. Kléman2000-11-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

This paper deals with regular arrays of macroscopic defects (focal conic domains) observed when a slab of lamellar phase is sandwiched between two substrates imposing different orientational anchorings. We report, in particular, detailed observations of the texture of a lyotropic lamellar phase in contact with a glass…

Liquid Crystal Research AdvancementsAdvanced Materials and MechanicsQuasicrystal Structures and Properties

Macropore Formation on Medium Doped p-Type Silicon

S. Lust、C. L�vy-Cl�ment2000-11-01physica status solidi (a)

Macropore formation on medium doped p-type silicon with a doping density as high as [Na] = 1017 cm—3(ρ= 0.2 Ωcm) was observed for the first time. As this occurs only in presence of N,N-dimethylformamide and dimethylsulfoxide, it is assumed that the nature of the organic solvent plays an important role in the dissoluti…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Dimer liquid crystals with bent mesogenic units

Antonius T. M. Marcelis、Arie Koudijs、Ernst J. R. Sudhölter2000-11-01Liquid Crystals

Three series of dimer liquid crystals containing an aromatic and a cholesteryl mesogenic unit were synthesized and investigated The compounds within the series differ in the length of the spacer connecting the mesogenic groups. Two of the three series contain an aromatic mesogenic group that is connected to the spacer…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesPlant Reproductive Biology

Synthesis of aromatic polybenzoxazoles by silylation method and their thermal and mechanical properties

Yoshio Imai、Kazuo Itoya、Masa‐aki Kakimoto2000-11-01Macromolecular Chemistry and Physics

Various aromatic polybenzoxazole (PBO) films were prepared through the two-step silylation method by low-temperature solution polycondensation of trimethylsilyl-substituted bis(o-aminophenol)s with aromatic dicarboxylic acid chlorides yielding precursor poly(o-trimethylsiloxy-amide)s, followed by thermal cyclocondensa…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Direct Analysis of Intraparticle Mass Transfer in Silica Gel Using Single-Microparticle Injection and Microabsorption Methods

Kiyoharu Nakatani、Tomomi Sekine2000-11-01Langmuir

Sorption and desorption processes of cationic dyes occurring in single silica gel microparticles in an aqueous solution were kinetically studied by microcapillary manipulation/injection and microabsorption methods. The sorption and desorption rates of rhodamine 6G were limited by diffusion of the dye in the particle i…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPhotonic Crystals and Applications

Distribution of benthic diatoms in the littoral zone of the Gulf of Riga, the Baltic Sea

Sirje Vilbaste、Kristina Sundbäck、Claes Nilsson 等 4 位作者2000-11-01European Journal of Phycology

The composition (% relative abundance) of the benthic diatom community was studied in the littoral zone (0–5 m) of the NW and E coasts of the brackish, non-tidal Gulf of Riga, in the Baltic Sea. The samples were collected concomitantly with measurements of sediment primary productivity and chlorophyll a during three c…

Marine and coastal ecosystemsMarine Biology and Ecology ResearchDiatoms and Algae Research

Evaluation of three methods for the measurement of crystallinity of pet resins, preforms, and bottles

Z. Bashir、I. Al‐Aloush、I. Al‐Raqibah 等 4 位作者2000-11-01Polymer Engineering and Science

Abstract The control of crystallization is important at all processing stages of the PET bottle industry, from the manufacture of bottle resins to the fabrication of preforms and bottles. In this work, we sought to evaluate critically three methods of crystallinity measurement. We have used density, Differential Scann…

Polymer crystallization and propertiesAdditive Manufacturing and 3D Printing TechnologiesTextile materials and evaluations

Coagulation Method of Aqueous Concentrated Alumina Suspensions by Thermal Decomposition of Hydroxyaluminum Diacetate

Richard Laucournet、Cécile Pagnoux、Thierry Chartier 等 4 位作者2000-11-01Journal of the American Ceramic Society

Consolidation of aqueous concentrated suspensions was used to shape alumina green bodies because it enabled us to obtain complex‐shape components with accurate sizes. A high state of alumina particle dispersion was achieved by using (HO) 2 C 6 H 2 (SO 3 Na) 2 (Tiron), which allowed us to obtain stable alumina suspensi…

Advanced ceramic materials synthesisMagnesium Oxide Properties and ApplicationsElectrophoretic Deposition in Materials Science

Diffusion Photovoltage in Porous Semiconductors and Dielectrics

V. Yu. Timoshenko、Volodimyr V. Duzhko、Th. Dittrich2000-11-01physica status solidi (a)

Strong retardation of photovoltage transients has been observed in porous materials (meso- and nanoporous Si, sintered networks of TiO2 nanoparticles, porous Al oxide) excited by short laser pulse. It has been shown that the photovoltage is mainly determined by the slow carriers diffusion with different diffusion coef…

Silicon and Solar Cell TechnologiesSilicon Nanostructures and PhotoluminescenceIon-surface interactions and analysis