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A Model System for the Thermodynamic Analysis of Reaction‐Induced Phase Separation: Solutions of Polystyrene in Bifunctional Epoxy/Amine Monomers

Ileana A. Zucchi、María J. Galante、Julio Borrajo 等 4 位作者2004-03-01Macromolecular Chemistry and Physics

Abstract Summary: A model system, consisting of a linear polymer dissolved in a bifunctional monomer/co‐monomer solvent, was selected to test the applicability of the Flory‐Huggins (FH) theory in the absence of the usual assumptions present in the analysis of modified thermosetting polymers. Solutions of two almost mo…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesEpoxy Resin Curing Processes

Induced Fit Movements and Metal Cofactor Selectivity of Class II Aldolases

Tina Izard、J. Sygusch2004-03-01Journal of Biological Chemistry

Fructose-1,6-bisphosphate (FBP) aldolase is an essential glycolytic enzyme that reversibly cleaves its ketohexose substrate into triose phosphates. Here we report the crystal structure of a metallo-dependent or class II FBP aldolase from an extreme thermophile, Thermus aquaticus (Taq). The quaternary structure reveals…

Advanced Glycation End Products researchEnzyme Structure and FunctionAldose Reductase and Taurine

Polyelectrolyte Multilayer Films of Different Charge Density Copolymers with Synergistic Nonelectrostatic Interactions Prepared by the Layer-by-Layer Technique

Bjoern Schoeler、Sonja Sharpe、T. Alan Hatton 等 4 位作者2004-03-01Langmuir

Random copolymers composed of diallyldimethylammonium chloride (DADMAC) and acrylamide with varying contents (8-100 mol %) of the cationic DADMAC component were alternated with polyanionic, fully charged poly(styrenesulfonate) to form multilayer thin films. UV-vis spectrophotometry, FTIR spectroscopy, and quartz-cryst…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

Auxosporulation of Licmophora communis (Bacillariophyta) and a review of mating systems and sexual reproduction in araphid pennate diatoms

Victor A. Chepurnov、David G. Mann2004-03-01Phycological Research

SUMMARY The auxosporulation of Licmophora communis is allogamous and dioecious. Pairing between sessile, shortstalked cells of compatible clones is followed by meiosis and gametogenesis, to form two gametes in each gametangium. The behavior of the gametes differs between the gametangia. In the male gametangium, the ga…

Marine and coastal ecosystemsProtist diversity and phylogenyDiatoms and Algae Research

Morphological Control of Nanoporous Films by the Use of Functionalized Cyclodextrins as Porogens

J‐H. Yim、J‐B. Seon、HD Jeong 等 6 位作者2004-03-01Advanced Functional Materials

Abstract Porous cyclic silsesquioxane (CSSQ) thin films containing nanopores (∼ 2 nm) with low dielectric constant ( k < 2.2), have been prepared by using various kinds of cyclodextrin (CD) derivatives as porogenic materials. The pore structure, including average pore size and interconnectivity, can be…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

Formation and Optical Properties of Gold Nanoparticles Synthesized in the Presence of Double-Hydrophilic Block Copolymers

Shu‐Hong Yu、Helmut Cölfen、Yitzhak Mastai2004-03-01Journal of Nanoscience and Nanotechnology

In this article, we present a systematic, controlled synthesis of water-dispersed, polymer-stabilized Au nanoparticles with different sizes by either self-reduction or ultraviolet (UV) irradiation-enhanced reduction in the presence of double hydrophilic block copolymers with different functional patterns. The morpholo…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced Polymer Synthesis and CharacterizationDendrimers and Hyperbranched Polymers

Gaseous Detonation-Driven Fracture of Tubes

Tong Wa Chao2004-03-01OpenAlex

An experimental investigation of fracture response of aluminum 6061-T6 tubes under internal gaseous detonation loading has been carried out. The pressure load, with speeds exceeding 2 km/s, can be characterized as a pressure peak (ranging from 2 to 6 MPa) followed by an expansion wave. The unique combination of this p…

Fatigue and fracture mechanicsHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Electrical properties of polymer nanocomposites based upon organophilic layered silicates

Carsten Zilg、Dirk Kaempfer、Ralf Thomann 等 5 位作者2004-03-01OpenAlex

An investigation on space charge and conduction properties of electrical-insulating polymer nanocomposites is presented. Space charge, conduction current and electric strength measurements were performed. Different poling field were considered, in order to derive the space charge accumulation characteristics and infer…

Advanced Sensor and Energy Harvesting MaterialsHigh voltage insulation and dielectric phenomenaDielectric materials and actuators

The electrical conduction in polyimide nanocomposites

Yang Cao、Patricia Irwin2004-03-01OpenAlex

The electrical properties of polyimide based nanocomposites were fully investigated by isothermal steady-state current, dielectric spectroscopy, and thermally stimulated current measurements. The effect of nano fillers on the dielectric properties was evaluated via the interfacial polarization as well as the electrica…

Polymer Nanocomposites and PropertiesHigh voltage insulation and dielectric phenomenaDielectric materials and actuators

On Alternative Thermal Methods for Discerning the Miscibility in Blends of Isotactic Polystyrene and Poly(cyclohexyl methacrylate) with Closely‐Spaced Glass Transitions

Li‐Ling Chang、Eamor M. Woo、Chih‐Pei Chiang2004-03-01Macromolecular Chemistry and Physics

Abstract Summary: Thermal characterizations were performed to further discern the miscibility and qualitative interactions in blends of isotactic polystyrene (iPS) and poly(cyclohexyl methacrylate) (PCHMA). A method based on the enthalpy relaxation of the blends was used to overcome the difficulty or ambiguity in reso…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Helium Removal and Recycling

D. Reiter、S. Wiesen2004-03-01Fusion Science & Technology

Removal of helium, the ash from the D-T-fusion reaction, from a burning plasma flame, is one of the critical issues for future thermonuclear burning plasma. Even in plasmas driven by additional heating to large Q-values this is a severe problem. Recombination of fuel and ash ions at plasma exposed surfaces, re-emissio…

Magnetic confinement fusion researchFusion materials and technologies

Microstructural modifications in uniaxially hot‐drawn polycyclohexylene terephthalate films

M. Kattan、Éric Dargent、J. Grenet2004-03-01Polymer Engineering and Science

Abstract Semi‐aromatic thermoplastic polycyclohexylene terephthalate (PCT), initially wholly amorphous, was uniaxially drawn to study microstructural modifications as the appearance of the strain‐induced (S.I.) crystalline phase. Polyethylene terephthalate (PET) and poly(ethylene glycol‐co‐cyclohexane‐1,4‐dimethanol t…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Syntheses and Crystal Structures of New Quaternary Ag-Containing Group 5 Chalcogenides: KAg2MVSe4 and K3Ag3MV2S8 (MV = Nb, Ta)

Wen‐Tong Chen、Hongwei Ma、Guo‐Cong Guo 等 7 位作者2004-03-01Bulletin of the Chemical Society of Japan

Abstract Four new quaternary Ag-containing group 5 chalcogenides, KAg2NbSe4 (1), KAg2TaSe4 (2), K3Ag3Nb2S8 (3), and K3Ag3Ta2S8 (4), have been prepared through the use of molten alkali metal polychalcogenides as reactive fluxes and structurally characterized by single-crystal X-ray diffraction techniques. The layer-typ…

Crystal Structures and PropertiesIron-based superconductors researchSolid-state spectroscopy and crystallography

INTEREST OF A COMPOUND YARN TO IMPROVE FABRIC PERFORMANCE

Manuela Ferreira、Serge Bourbigot、Xavier Flambard 等 5 位作者2004-03-01Autex Research Journal

Abstract The market for protective clothing is growing in many fields, including flame resistance clothing, cut-resistance gloves and so on. High-performance fibres such as aramides are known to be flameproof and resistant to mechanical impacts, but they are sensitive to UV.The purpose of this study was to produce com…

Textile materials and evaluations

Photo‐aligned anisotropic optical thin films

Hubert Seiberle、C. Benecke、Thomas Bachels2004-03-01Journal of the Society for Information Display

Abstract— Photo‐alignment of anisotropic optical thin films enables realization of novel optical elements, which were not feasible up until now. Photo‐aligned anisotropic thin films can be applied to rigid or flexible substrates, which may be flat or curved. The optical performance of such films can be tailored to app…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsSemiconductor Lasers and Optical Devices

Recementation of Crushed Ortstein by Blueberry Leaf Extract

C. J. Bronick、D. L. Mokma、Hui Li 等 4 位作者2004-03-01Soil Science Society of America Journal

Cementing of sand grains by organo‐Al and organo‐Fe complexes is thought to be a gradual process and takes at least a few thousand years. The resulting ortstein inhibits root penetration. Blueberries ( Vaccinium corymbosum L.) in isolated regions of blueberry fields in Michigan experience reduced growth that has been…

Clay minerals and soil interactionsPolymer-Based Agricultural EnhancementsSoil Management and Crop Yield

Magnetic Field Analysis of Iron-Core Reactor Coils by the Finite-Volume Method

Jun Zou、Jiansheng Yuan、Xi Ma 等 6 位作者2004-03-01IEEE Transactions on Magnetics

An accurate evaluation of the magnetic field of the iron-core reactor coils by the finite-volume method (FVM) is presented. The linear and quadratic interpolation scheme of FVM is developed. The numerical results are compared with those obtained by the finite-element method. Good agreement is obtained. The main advant…

Fusion materials and technologiesMagnetic Properties and ApplicationsSuperconducting Materials and Applications

Effect of molecular weight on brittle‐to‐ductile transition temperature of polyetherimide

Mark A. Sanner、Gurulingamurthy Haralur、Andy May2004-03-01Journal of Applied Polymer Science

Abstract The fracture and yield strength of polyetherimide was evaluated over a temperature range of 23 to 140°C for materials with number‐average ( M n ) and weight‐average molecular weight ( M w ) ranging from 15.6 to 22.8 and 36.6 to 52.3 kg/mol, respectively. The brittle‐to‐ductile transition temperature, where an…

Polymer crystallization and propertiesNatural Fiber Reinforced CompositesInjection Molding Process and Properties

Optical investigations of the effect of gradual substitution NH4 → Cs on the ferroelastic phase transition in a CsLiSO4 crystal

S. V. Mel’nikova、V. A. Grankina2004-03-01Physics of the Solid State

Crystals of Cs x (NH 4 ) 1− x LiSO 4 (0.39≤ x ≤1.0) solid solutions are grown and investigated using polarized light microscopy and measurements of the birefringence in the temperature range 100–530 K. The ( x - T ) phase diagram of the Cs x (NH 4 ) 1− x LiSO 4 solid solutions is constructed. It is demonstrated that,…

Nonlinear Optical Materials ResearchSolid-state spectroscopy and crystallographyOptical and Acousto-Optic Technologies

Modification of polystyrene by reactive extrusion with peroxide and trimethylolpropane triacrylate

Byung Kyu Kim、Kyung Ho Shon、Han Mo Jeong2004-03-01Journal of Applied Polymer Science

Abstract Polystyrene (PS) was modified by reactive extrusion with trimethylolpropane triacrylate (TMPTA) and dicumyl peroxide (DCP). The coupling reaction caused by TMPTA increased the molecular weight of PS, and this coupling reaction was enhanced in the presence of DCP at high TMPTA/DCP ratio. The rheological proper…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties