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This article describes work carried out in UKAEA laboratories to examine the possibility of using protective coatings on cadmium plate—such as that used to protect mild steel—in order to prevent or minimise corrosion due to hostile organic vapours. The degree of attack by vapours of acetic, formic, butyric and propion…
In FeTiO 3 , CoTiO 3 and NiTiO 3 the dominant magnetic exchange interactions are held to be of super-superexchange type, using two oxygens or one oxygen and one diamagnetic Ti 4+ ion between the pairs of paramagnetic cations. In order to explain the antiferromagnetic ordering of manganese spins in the same layer in Mn…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAnalysis of Mixtures of Hydroxyl Compounds Using Differential Reaction Rates.Friso. Willeboordse and F. E. CritchfieldCite this: Anal. Chem. 1964, 36, 12, 2270–2274Publication Date (Print):November 1, 1964Publication History Published online1 May 2002Published inissue 1 Nove…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPyrolytic Conversion of 7,7-Dichloronorcarane to CycloheptatrieneG. C. RobinsonCite this: J. Org. Chem. 1964, 29, 11, 3433–3434Publication Date (Print):November 1, 1964Publication History Published online1 May 2002Published inissue 1 November 1964https://pubs.acs.org/doi/10.…
Abstract The thermal degradation in oxygen of a number of fluorine‐containing polymers has been studied by using a weight loss technique. The relative thermal stabilities of the different polymers have been determined and, where possible, the overall activation energy and frequency factors for their breakdown. The res…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Crystal Structure of Strontium Bromide MonohydrateMaurice Dyke and Ronald L. SassCite this: J. Phys. Chem. 1964, 68, 11, 3259–3262Publication Date (Print):November 1, 1964Publication History Published online1 May 2002Published inissue 1 November 1964https://pubs.acs.org/…
Abstract Further studies on the thermal degradation of POPG‐TDI polymer have been carried out. It has been shown that at temperatures of ∼200°C., the predominant degradation process involves random scission of the urethane linkages to give substantial amounts of isocyanate and hydroxyl. Kinetic data suggests that the…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHexachlorotungstate(V) CompoundsR. N. Dickinson, Susan E. Feil, F. N. Collier, W. W. Horner, Sally M. Horner, and S. Y. TyreeCite this: Inorg. Chem. 1964, 3, 11, 1600–1603Publication Date (Print):November 1, 1964Publication History Published online1 May 2002Published inissue…
Lithium ferrite, an inverse spinel with an order-disorder transition at about 800°C, has been grown in the ordered state. The narrowest ferromagnetic resonance linewidth yet observed in a spinel has resulted from the growth of single crystals of lithium ferrite in the ordered state. Details of the growth conditions, m…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Crystal and Molecular Structure of Tetra-n-butylammonium-copper(III) Bis(maleonitrile dithiolate) and the Geometry of the Monovalent Copper(III) Bis(maleonitrile dithiolate) IonJ. D. Forrester, Allan Zalkin, and David H. TempletonCite this: Inorg. Chem. 1964, 3, 11, 1507…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSecondary Nucleation from Aqueous SolutionT. P. Melia and W. P. MoffittCite this: Ind. Eng. Chem. Fundamen. 1964, 3, 4, 313–317Publication Date (Print):November 1, 1964Publication History Published online1 May 2002Published inissue 1 November 1964https://pubs.acs.org/doi/10.…
Abstract The thermal degradation in vacuum of a number of fluorine‐containing polymers has been studied by using a weight loss technique. The relative thermal stabilities of the different polymers have been determined and where possible the overall activation energy and frequency factors for their breakdown. The metho…
Dielectric measurements and direct‐transmission electron microscopy were used to analyze the phase separation and alteration in sodium borosilicate glasses. Metal impregnation of the glasses after leaching was particularly useful in observing the topology of separated phases whose characteristic dimensions are about 1…
Abstract Polymetaphosphate and polyethylene glycol in aqueous solution are excluded completely from rayon fibers. Determinations of nonsolvent water (δ) with these reference substances give the same value which can be used as a measure of the true swelling. The polymers can, however, penetrate into porous areas presen…
An exact solution is obtained for the axisymmetric vibrations of orthotropic cylinders by the application of the Frobenius series method. Numerical results are given for the two orthotropic materials barytes and topaz.
Dislocations have been observed and characterized in polyethylene single crystals by means of moiré patterns produced by superimposed lamellas. Analysis of the dislocations by dark and bright field electron microscopy has revealed that they are partial (imperfect) dislocations. The partials were shown to involve termi…
Results are presented from a theoretical and experimental program to investigate the damage that would be inflicted upon a missile, satellite, or space vehicle by a hypervelocity particle. Most of the work has been directed toward thin shield impacts. The problem is treated theoretically by examining the wave motion i…
The kinetics of spherulite growth of TMPS has been measured as a function of the fusion conditions (time of melting and fusion temperature) for different crystallization temperatures. The influence of fusion conditions on nucleation is described. The rates of spherulite growth (G) have been measured through the maximu…
A theory is presented for the thermodynamic mixing properties of certain charge-unsymmetrical fused salt mixtures of the type (P+—Qz+)X—. The analysis is based upon the work of Reiss, Katz, and Kleppa who showed that for charge-symmetrical molten-salt mixtures many of the thermodynamic properties of mixing could be un…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA Surface Tension Study of the Interaction of Dimethyldodecylamine Oxide with Potassium Dodecanesulfonate in Dilute Aqueous SolutionMilton J. Rosen, David Friedman, and Michael GrossCite this: J. Phys. Chem. 1964, 68, 11, 3219–3225Publication Date (Print):November 1, 1964Pub…