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Lattice Site Exclusion Effect on the Double Layer Interaction

Marian Manciu、Eli Ruckenstein2002-06-01Langmuir

A lattice model for an electrolyte solution is proposed, which assumes that the hydrated ion occupies τ i ( i = 1, 2) sites on a water lattice. A lattice site is available to an ion “ i ” only if it is “free” (it is occupied by a water molecule, which does not hydrate an ion) and has also at least (τ i − 1) first-neig…

Theoretical and Computational PhysicsElectrostatics and Colloid InteractionsChemical and Physical Properties of Materials

Computational simulation of the printing of Newtonian liquid from a trapezoidal cavity

Corrina Powell、Savage、J. T. Guthrie2002-06-01International Journal of Numerical Methods for Heat &amp Fluid Flow

A Lagrangian finite element algorithm is described for solving two‐dimensional, time‐dependent free surface fluid flows such as those that occur in industrial printing processes. The algorithm is applied using a problem specific structured meshing strategy, implemented with periodic remeshing to control element distor…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferFluid Dynamics and Thin Films

Temperature Dependence of the Absorption Coefficient in 4H- and 6H-Silicon Carbide at 355 nm Laser Pumping Wavelength

Augustinas Galeckas、Paulius Grivickas、V. Grivickas 等 5 位作者2002-06-01physica status solidi (a)

We report on the absorption coefficient at 355 nm laser wavelength for 4H- and 6H-SiC over a wide temperature range. The measurements were carried out using a depth- and time-resolved free-carrier-absorption technique. The values of the absorption coefficient for the fundamental E ⊥ ĉ and E ‖ ĉ light polarization were…

Silicon Carbide Semiconductor TechnologiesDiamond and Carbon-based Materials ResearchThin-Film Transistor Technologies

Development of the system for qualitative prediction of garments appearance quality

Jelka Geršak2002-06-01International Journal of Clothing Science and Technology

The contribution presented here is the development of the system for qualitative prediction of garment appearance quality. The starting point for designing such a system is a qualitative evaluation of garment appearance quality, based on the study of relation of fabric mechanical properties and achieved quality level…

Dyeing and Modifying Textile FibersTextile materials and evaluationsColor perception and design

Selective attachment of monovalent background electrolyte ions and growth inhibitors to polar steps on sulfates as studied by molecular simulations and AFM observations

Udo Becker、Peter Risthaus、Dirk Bosbach 等 4 位作者2002-06-01Molecular Simulation

Molecular simulations and in situ atomic force microscopy (AFM) experiments are used to demonstrate the influence of the ionic strength of the solution and the mechanism of growth inhibitors on growth and dissolution of barite with some comparative experiments on celestite. Growth and dissolution rates, as determined…

Calcium Carbonate Crystallization and InhibitionMinerals Flotation and Separation TechniquesChemical and Physical Properties in Aqueous Solutions

Glass-ceramic materials as sealants for SOFC applications

T. Schwickert、R. Sievering、P. Geasee 等 4 位作者2002-06-01Materialwissenschaft und Werkstofftechnik

At Forschungszentrum Jülich, glass-ceramic materials from the BaO-CaO-Al2O3-SiO2-system are used to join high temperature fuel cell stacks. Requirements for the sealant and characterisation of the glasses are shown in this paper. Characterisation is done in three steps: determination of glass properties, characterisat…

Advanced ceramic materials synthesisAdvancements in Solid Oxide Fuel CellsCatalysis and Oxidation Reactions

BSAC standardized disc susceptibility testing method

J. M. Andrews2002-06-01Journal of Antimicrobial Chemotherapy

J Antimicrob Chemother2001; 48: Suppl. S1, 43–57 In Table V the lower breakpoint for cefoperazone of 1 mg/L has been used to allow the detection of extended-spectrum β-lactamases. In Table VII the ATCC reference strain was incorrectly given as ATCC 25932; this should have read ATCC 25923. In Tables VII and VIII the ch…

Nuclear Materials and PropertiesPolymer-Based Agricultural EnhancementsEngineering Applied Research

The effects of measuring technique and sample preparation on the breakdown strength of polyethylene

I. L. Hosier、A. S. Vaughan、S.G. Swingler2002-06-01IEEE Transactions on Dielectrics and Electrical Insulation

The effects of specimen thickness, testing conditions and preparation technique on the measured ramp-breakdown strength of 2 polyethylene systems have been investigated. The obtained data have been found to be highly reproducible, enabling results under different test conditions to be correlated with one another. In a…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesHigh voltage insulation and dielectric phenomena

The dislocations contrast factors of cubic crystals in the Zener constant range between zero and unity

I. C. Dragomir、T. Ungár2002-06-01Powder Diffraction

Diffraction peak profiles broaden due to the smallness of crystallites and the presence of lattice defects. Strain broadening of powders of polycrystalline materials is often anisotropic in terms of the hkl indices. This kind of strain anisotropy has been shown to be well interpreted assuming dislocations as one of th…

Crystal Structures and PropertiesNuclear materials and radiation effectsX-ray Diffraction in Crystallography

Enzymatic degradations of copolymers of L-lactide with cyclic carbonates

Chikara Tsutsumi、Katsuhiko Nakagawa、Hiroyuki Shirahama 等 4 位作者2002-06-01Macromolecular Bioscience

Syntheses and biodegradation of random copolymers of L-lactide (L-LA) with trimethylene carbonate (TMC), 1,1-dimethyltrimethylene carbonate (1,1-DTMC) and 2,2-dimethyltrimethylene carbonate (2,2-DTMC) were investigated at various monomer ratios using SmMe(C5Me5)2THF as an initiator at 80 °C for 24 h in toluene. Enzyma…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionCarbon dioxide utilization in catalysis

Ab Initio Calculations of Pristine and Doped Zirconia Σ5 (310)/[001] Tilt Grain Boundaries

Zugang Mao、Susan B. Sinnott、Elizabeth C. Dickey2002-06-01Journal of the American Ceramic Society

The structure of the cubic‐ZrO 2 symmetrical tilt Σ5 (310)/[001] grain boundary is examined using density functional theory within the local density and pseudopotential approximations. Several pristine stoichiometric grain‐boundary structures are investigated and compared with Z‐contrast scanning transmission electron…

Advancements in Solid Oxide Fuel CellsHigh-pressure geophysics and materialsElectronic and Structural Properties of Oxides

Precyclic-Loading-Induced Stress Corrosion Cracking of Pipeline Steels in a Near-Neutral-pH Soil Environment

Sheng-Hui Wang、W. Chen、Fraser King 等 5 位作者2002-06-01CORROSION

Two pipeline steels of different grades were used to study the effect of cyclic loading prior to corrosion exposure upon the initiation of stress corrosion cracks in a near-neutral-pH soil environment. A cyclic loading scheme was constructed based on pressure fluctuation data collected on operating pipeline systems. T…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsMaterial Properties and Failure Mechanisms

Contrasting clay mineral assemblages in British Lower Palaeozoic slate belts: the influence of geotectonic setting

R. J. Merriman2002-06-01Clay Minerals

Abstract Regional differences in clay mineralogy are found in British Lower Palaeozoic slate belts formed during Caledonian terrane amalgamation. Extensional basins in Wales, the northern Lake District and the Isle of Man are characterized by a greater diversity of species in clay mineral assemblages. Slates that evol…

Geological and Geochemical AnalysisClay minerals and soil interactionsTherapeutic Uses of Natural Elements

Structural properties and mechanical behavior of injection molded composites of polypropylene and sisal fiber

Xiaolin Xie、Robert K.Y. Li、S. C. Tjong 等 4 位作者2002-06-01Polymer Composites

Abstract Composites based on isotactic polypropylene (PP) and sisal fiber (SF) were prepared by melt mixing and injection molding. The melt mixing characteristics, thermal properties, morphology, crystalline structure, and mechanical behavior of the PP/SF composites were systematically investigated. The results show t…

Polymer crystallization and propertiesNatural Fiber Reinforced CompositesTribology and Wear Analysis

A dipole model for the cross-slip of screw dislocations in fcc metals

L. M. Brown2002-06-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

Abstract An attempt is made to reconcile observations and theories of cross-slip with recent models of cyclic plasticity and the fatigue endurance limit of crystals. According to this view, the stress required to separate two screw dislocations of opposite signs, which are just on the point of mutual annihilation by c…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsFusion materials and technologies

Role of water in the catalytic cycle of E. coli dihydrofolate reductase

Paul J. Shrimpton、Rudolf K. Allemann2002-06-01Protein Science

Dihydrofolate reductase (DHFR) catalyzes the nicotinamide adenine dinucleotide phosphate (NADPH)-dependent reduction of 7,8-dihydrofolate (H2F) to 5,6,7,8-tetrahydrofolate (H4F). Because of the absence of any ionizable group in the vicinity of N5 of dihydrofolate it has been proposed that N5 could be protonated direct…

Enzyme Structure and FunctionPorphyrin Metabolism and DisordersBiochemical and Molecular Research

Body scanning

Lashawnda Mckinnon、Cynthia L. Istook2002-06-01Journal of Fashion Marketing and Management

Describes research designed to examine the effects of subject positioning on the accuracy of body scan data. A body measurement system developed by the Textile Clothing Technology Corporation was used to acquire two scans from each of 72 subjects. The subjects were instructed to continue to breathe normally and stand…

Textile materials and evaluations

Structural characterization of the new polymorphic mesophases formed by bent-core molecules

Alexey Eremin、I. Wirth、Siegmar Diele 等 10 位作者2002-06-01Liquid Crystals

A new achiral banana-shaped five-ring 2-methylresorcinol derivative fluorinated on the outer rings has been synthesized. This compound exhibits four antiferroelectric smectic phases characteristic for bent-core molecules (B2, B′2, B″2, B5). In addition, a highly viscous solid-like phase has been detected which also sh…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Thiacrown Ether Substituted Styryl Dyes: Synthesis, Complex Formation and Multiphotochromic Properties

Оlga А. Fedorova、Yu. V. Fedorov、A.I. Vedernikov 等 10 位作者2002-06-01The Journal of Physical Chemistry A

Syntheses of two series of new styryl dyes incorporating thiacrown ether moieties (CSDs 3a − e, 4a − e ) are described. 1 H NMR and UV−vis measurements show that these compounds exhibit a strong preference for formation of complexes with heavy metal ions. Polarographic measurements allow conversion of relative complex…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence Chemistry

Inhibition of unwanted proteolysis during sample preparation: Evaluation of its efficiency in challenge experiments

Lila Castellanos‐Serra、Dalila Paz‐Lago2002-06-01Electrophoresis

Measures to counteract proteolysis during sample preparation are widely used; among them, protein extraction at a basic pH (Tris pH 11.0), sample boiling in sodium dodecyl sulfate (SDS), extraction in denaturing lysis solutions and the use of proteinase inhibitors combined with some of these approaches. Here, we teste…

Advanced Proteomics Techniques and ApplicationsPolymer Surface Interaction StudiesBlood properties and coagulation