Materials Literature
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We present high resolution Ag ${M}_{5}\mathrm{VV}$ and ${M}_{4}\mathrm{VV}$ Auger spectra obtained in coincidence with ${3d}_{5/2}$ and ${3d}_{3/2}$ core photoelectrons, respectively. Auger photoelectron coincidence spectroscopy (APECS) was used to separate these overlapping Auger lines and determine the intrinsic lin…
CO adsorption and oxidation over Au/Al 2 O 3 were studied by infrared (IR) spectroscopy at 150 K. Two types of CO adsorption were found on the support, Al 2 O 3, with the existence of gaseous CO (266 Pa). An additional band of adsorbed CO at 2110 cm -1 was found on Au/Al 2 O 3 at 150 K in the presence of gaseous CO an…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTOne-Dimensional Polymers of Octasubstituted PhthalocyaninesAnthony S. Drager, Rebecca A. P. Zangmeister, Neal R. Armstrong, and David F. O'BrienView Author Information C.S. Marvel Laboratories, Department of Chemistry University of Arizona, Tucson, Arizona 85721 Cite t…
Oxidation of the surface of cross-linked 1,4-polybutadiene provided a hydrophilic substrate that reconstructed against hot water to become more hydrophobic. Subsequent equilibration against water at room temperature returned its original hydrophilicity. These temperature-dependent changes in the relative concentration…
Hyperbranched poly(acrylic acid) and poly( N -isopropylacrylamide) grafts on gold and polyethylene films are good substrates for a new, mild hydrogen-bond-based grafting method. In this chemistry, a hydrogen-bond-donating or -accepting hyperbranched graft couples to a polymeric acceptor or donor in ethanol solution th…
Large deformation, nonlinear stress relaxation behavior was examined in the molten state for two types of ABS polymers, with one type containing well-dispersed rubber particles and the other, agglomerated rubber particles. These different morphologies were accomplished by adjusting the chemical composition of poly(sty…
Orbital ordering, often observed in Mott insulators with orbital degeneracy, is usually supposed to disappear with doping, e.g., in the ferromagnetic metallic phase of manganites. We propose that the orbital ordering of a novel type may exist in such a situation: there may occur an orbital ordering of complex orbitals…
We perform the density-functional and quantum chemical calculations of adsorption of a hydrogen molecule to various kinds of single-walled carbon nanotubes (SWNT's). The potential energy barrier height (PBH) for the dissociative adsorption of a hydrogen molecule onto the outer wall of a nanotube decreases as the tube…
A passive, matched two-time-derivative Lorentz material medium is designed to have its equivalent permittivity and permeability smaller than their values in free space over a large range of frequencies. Superluminal pulse propagation in this medium and consequent superluminal information exchange without a violation i…
We present a study of anisotropy of transport and magnetic properties in La_{1-x}Ca_{x}MnO_{3} (x \approx 1/3) film prepared by pulsed-laser deposition onto a LaAlO_{3} sunstrate. We found a non-monotonic dependence of magnetoresistance (MR) on magnetic field H for both H perpendicular and parallel to the film plane b…
A set of thin GaAs p-type negative electron affinity (NEA) photocathodes have been used to measure the yield of photoemitted electrons at high intensity excitation. The active layer thickness is 100 nm and the p-type doping ranges from 5\times10^{18} cm^{-3} to 5\times10^{19} cm^{-3} for a set of four samples. The res…
We propose a new approach to theoretical description of doped cuprate like $La_{2-x}Sr_{x}CuO_4$ and $YBa_2Cu_3O_{6+x}$, assuming phase separation and treating it as inhomogeneous composite material, containing the dielectric and metallic stripe-like nanoparticles. The formalism of effective medium theory is then appl…
Thin superconducting films of magnesium diboride (MgB2) with Tc \approx 24K were prepared on various oxide substrates by pulsed laser deposition (PLD) followed by an in-situ anneal. A systematic study of the influence of various in-situ annealing parameters shows an optimum temperature of about 600C in a background of…
A fast ion penetrating a solid creates a track of excitations. This can produce displacements seen as an etched track, a process initially used to detect energetic particles but now used to alter materials. From the seminal papers by Fleischer et al. [Phys. Rev. 156, 353 (1967)] to the present [C. Trautmann, S. Klaumu…
Perturbation theory, simulations and scaling arguments predict that there should be no static friction for two weakly interacting flat atomically smooth clean solid surfaces. The absence of static friction results from the fact that the atomic level interfacial potential energy is much weaker than the elastic potentia…
We performed all-electron ab initio self-consistent field Hartree-Fock linear combination of atomic orbital, in which electronic correlation using density functional were included to perform electronic calculations in MgB2 new superconductor. Superconductivity in this compound was correlated with existence of Px,y ban…
Semiconductor ZnS nanowires were synthesized by a direct templating route in an inverted hexagonal liquid crystal formed by oligo(ethylene oxide)oleyl ether amphiphiles, n -hexane, n -hexanol/ i -propanol (2:1), and water. The final product consists of ordered nanowires with a diameter of ca. 5 nm. Most importantly, s…
The singlets $s\ensuremath{-}$ and $d\ensuremath{-},$ and triplet p-wave pairing symmetries in quasi-one-dimensional organic superconductors can be experimentally discriminated by probing the Andreev bound states at the sample edges. These states have the energy in the middle of the superconducting gap and manifest th…
Abstract The benthic boundary layer is the zone of water and sediment immediately adjacent to the bottom of a sea, lake, or river. This zone is a key environment to biologists, geochemists, sedimentologists, and engineers because of very strong gradients of energy, dissolved and solid chemical components, suspended ma…
Texture evolution governs many of the physical, chemical, and mechanical properties of polycrystalline materials, but texture models have only been tested on the macroscopic level, which makes it hard to distinguish between approaches that are conceptually very different. Here, we present a universal method for provid…