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High-pressure synthesis of MgB2 with addition of Ti

T. A. Prikhna、W. Gawalek、Ya. M. Savchuk 等 14 位作者2003-06-01arXiv

The MgB2 - based material high-pressure synthesized at 2 GPa and 800 C for 1 h from Mg and B (taken in the stoichiometry ratio of MgB2) with addition of 2-10 wt% of Ti demonstrated the critical current density (jc) higher than 100 kA/cm^2 at 33 K in 0 T field and at 20 K up to 3 T. At 20 K the critical current density…

SuperconductivityMaterials Science

Involvement of the Reserve Material Poly-β-Hydroxybutyrate inAzospirillum brasilenseStress Endurance and Root Colonization

Daniel E. Kadouri、Édouard Jurkevitch、Yaacov Okon2003-06-01Applied and Environmental Microbiology

When grown under suboptimal conditions, rhizobacteria of the genus Azospirillum produce high levels of poly-beta-hydroxybutyrate (PHB). Azospirillum brasilense strain Sp7 and a phbC (PHB synthase) mutant strain in which PHB production is impaired were evaluated for metabolic versatility, for the ability to endure vari…

Legume Nitrogen Fixing Symbiosisbiodegradable polymer synthesis and propertiesBiofuel production and bioconversion

Fiber Fabry-Perot sensors for detection of partial discharges in power transformers

Bing Yu、Dae Woong Kim、Jiangdong Deng 等 5 位作者2003-06-01Applied Optics

A diaphragm-based interferometric fiberoptic sensor that uses a low-coherence light source was designed and tested for on-line detection of the acoustic waves generated by partial discharges inside high-voltage power transformers. The sensor uses a fused-silica diaphragm and a single-mode optical fiber encapsulated in…

Advanced Fiber Optic SensorsPower Transformer Diagnostics and InsulationHigh voltage insulation and dielectric phenomena

Neovascular targeting therapy: paclitaxel encapsulated in cationic liposomes improves antitumoral efficacy.

M. Schmitt‐Sody、Sebastian Strieth、Senat Krasnici 等 9 位作者2003-06-01PubMed

PURPOSE: Cationic liposomes have been shown to selectively target tumor endothelial cells. Therefore, the encapsulation of antineoplastic drugs into cationic liposomes is a promising tool to improve selective drug delivery by targeting tumor vasculature. It was the aim of our study to evaluate tumor selectivity and an…

RNA Interference and Gene DeliveryNanoplatforms for cancer theranosticsNanoparticle-Based Drug Delivery

Improved crystallographic data for graphite

Jane Y. Howe、Claudia J. Rawn、Linda E. Jones 等 4 位作者2003-06-01Powder Diffraction

Powder diffraction pattern of SP-1 graphite has been obtained using synchrotron X-ray diffraction. Unit cell dimensions were calculated using a least-squares analysis that refined to a |Δ2θ°| of no more than 0.007. A hexagonal cell was determined with a space group of P 6 3 / mmc (194), a =2.4617(2) and c =6.7106 (4)…

X-ray Diffraction in CrystallographyGraphite, nuclear technology, radiation studiesMachine Learning in Materials Science

A Mechanistic Model for Carbon Dioxide Corrosion of Mild Steel in the Presence of Protective Iron Carbonate Films—Part 2: A Numerical Experiment

Srdjan Nešić、Magnus Nordsveen、Rolf Nyborg 等 4 位作者2003-06-01CORROSION

A theoretical carbon dioxide (CO2) corrosion model was used to conduct numerical experiments, which allowed total insight into the underlying physicochemical processes. The focus was on factors influencing protective iron carbonate film formation and the effect that these films have on the CO2 corrosion process. It wa…

CO2 Sequestration and Geologic InteractionsConcrete Corrosion and DurabilityCorrosion Behavior and Inhibition

Extrusion of polystyrene nanocomposite foams with supercritical CO2

Xiangmin Han、Changchun Zeng、L. James Lee 等 5 位作者2003-06-01Polymer Engineering and Science

Abstract Intercalated and exfoliated polystyrene/nano‐clay composites were prepared by mechanical blending and in situ polymerization respectively. The composites were then foamed by using CO 2 as the foaming agent in an extrusion foaming process. The resulting foam structure is compared with that of pure polystyrene…

Polymer Foaming and CompositesCarbon dioxide utilization in catalysisPolymer composites and self-healing

Introduction to Conventional Transmission Electron Microscopy

Marc De Graef2003-06-01Materials Today

This 2003 book covers the fundamentals of conventional transmission electron microscopy (CTEM) as applied to crystalline solids. Emphasis is on the experimental and computational methods used to quantify and analyze CTEM observations. A supplementary website containing interactive modules and free Fortran source code…

Electron and X-Ray Spectroscopy Techniques

Imaging the near field

S. Anantha Ramakrishna、J. B. Pendry、M. C. K. Wiltshire 等 4 位作者2003-06-01Journal of Modern Optics

In an earlier paper we introduced the concept of the perfect lens which focuses both near and far electromagnetic fields, hence attaining perfect resolution. Here we consider refinements of the original prescription designed to overcome the limitations of imperfect materials. In particular we show that a multilayer st…

Metamaterials and Metasurfaces ApplicationsThermal Radiation and Cooling TechnologiesNear-Field Optical Microscopy

Bis(μ-oxo)dicopper in Cu-ZSM-5 and Its Role in the Decomposition of NO: A Combined in Situ XAFS, UV−Vis−Near-IR, and Kinetic Study

Marijke H. Groothaert、Jeroen A. van Bokhoven、Andrea A. Battiston 等 5 位作者2003-06-01OpenAlex

In situ XAFS combined with UV-vis-near-IR spectroscopy are used to identify the active site in copper-loaded ZSM-5 responsible for the catalytic decomposition of NO. Cu-ZSM-5 was probed with in situ XAFS (i) after O(2) activation and (ii) while catalyzing the direct decomposition of NO into N(2) and O(2). A careful R-…

Catalytic Processes in Materials ScienceAdvanced Nanomaterials in CatalysisNanocluster Synthesis and Applications

Supercooled and Glassy Water

Pablo G. Debenedetti、H. Eugene Stanley2003-06-01OpenAlex

Cold, noncrystalline states play an important role in understanding the physics of liquid water. From recent experimental and theoretical investigations, a coherent interpretation of water’s properties is beginning to emerge.

Material Dynamics and PropertiesPhase Equilibria and ThermodynamicsThermodynamic properties of mixtures

Calcium carbonate in biomineralisation and biomimetic chemistry

Fiona C. Meldrum2003-06-01OpenAlex

Nature is adept at controlling mineralisation processes to produce single crystals and polycrystalline and amorphous structures with remarkable morphologies and mechanical properties. Calcium carbonate is one of the most common biominerals, and as such has received considerable attention, both in terms of research int…

Calcium Carbonate Crystallization and InhibitionDiatoms and Algae ResearchCephalopods and Marine Biology

Medical applications of shape memory alloys

Luciano Machado、Marcelo A. Savi2003-06-01OpenAlex

Shape memory alloys (SMA) are materials that have the ability to return to a former shape when subjected to an appropriate thermomechanical procedure. Pseudoelastic and shape memory effects are some of the behaviors presented by these alloys. The unique properties concerning these alloys have encouraged many investiga…

Shape Memory Alloy Transformations

Glassy dynamics of kinetically constrained models

F. Ritort、P. Sollich2003-06-01OpenAlex

We review the use of kinetically constrained models (KCMs) for the study of dynamics in glassy systems. The characteristic feature of KCMs is that they have trivial, often non-interacting, equilibrium behaviour but interesting slow dynamics due to restrictions on the allowed transitions between configurations. The bas…

Material Dynamics and PropertiesTheoretical and Computational PhysicsAdvanced Physical and Chemical Molecular Interactions

Exposure to Carbon Nanotube Material: Assessment of Nanotube Cytotoxicity using Human Keratinocyte Cells

Anna A. Shvedova、Vincent Castranova、Elena R. Kisin 等 8 位作者2003-06-01OpenAlex

Carbon nanotubes are new members of carbon allotropes similar to fullerenes and graphite. Because of their unique electrical, mechanical, and thermal properties, carbon nanotubes are important for novel applications in the electronics, aerospace, and computer industries. Exposure to graphite and carbon materials has b…

Carcinogens and Genotoxicity AssessmentCarbon Nanotubes in CompositesNanoparticles: synthesis and applications

Proton NMR Characterization of Room-Temperature Aging after Modest Thermal Cycling in Isotactic Polypropylenes

David L. VanderHart、Chad R. Snyder2003-05-31Macromolecules

A proton NMR method, based on simple Bloch-decay spectra in the solid state, is presented that enables one to follow, with excellent sensitivity, structural changes associated with aging in semicrystalline polymers whose T g is well below the aging temperature. The method is demonstrated for two representative isotact…

Polymer crystallization and propertiesAdvanced NMR Techniques and ApplicationsNMR spectroscopy and applications

Two isomorphous complexes: dichloro[phthalocyaninato(2–)]tin(IV) and dichloro[phthalocyaninato(2–)]germanium(IV)

Jan Janczak、Ryszard Kubiak2003-05-31Acta Crystallographica Section C Crystal Structure Communications

Isomorphous triclinic forms of dichloro[phthalocyaninato(2-)]tin(IV), [Sn(C(32)H(16)N(8))Cl(2)], and dichloro[phthalocyaninato(2-)]germanium(IV), [Sn(C(32)H(16)N(8))Cl(2)], and a monoclinic form of the latter have been obtained from the reaction of pure tin and germanium powder, respectively, with phthalonitrile under…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsMagnetism in coordination complexes

Effect of the Polycation Nature on the Structure of Layer-by-Layer Electrostatically Self-Assembled Multilayers of Polyphenol Oxidase

Erica Forzani、Manuel López Teijelo、Francisco Carlos Nart 等 5 位作者2003-05-31Biomacromolecules

Self-assembled multilayers comprised of alternate layers of polyphenol oxidase (PPO) and poly(allylamine) (PAH) or PPO and poly(diallyldimethylamine) (PDDA), deposited on a 3-mercaptopropanesulfonic acid (MPS)-modified gold surface, were studied "in-situ" (under water) by means of ellipsometry and quartz crystal micro…

Polymer Surface Interaction StudiesMolecular Junctions and NanostructuresSurfactants and Colloidal Systems

Polyphosphate Flame Retardants with Increased Heat Resistance

B. Cichy、D. Łuczkowska、M. Nowak 等 4 位作者2003-05-31Industrial & Engineering Chemistry Research

A review of methods for producing and using condensed melamine phosphates as flame retardants, and analysis of our own investigations on production of melamine polyphosphate, are presented. Physicochemical properties of obtained products are given including thermal properties (DTA, TG, and DSC). Effectiveness of actio…

Material Properties and ApplicationsEnvironmental and Industrial SafetyFlame retardant materials and properties

Wetting Characteristics of Plasma-Modified Porous Polyethylene

George W. Greene、George C. Yao、Rina Tannenbaum2003-05-31Langmuir

This paper examines the wetting characteristics of porous polyethylene surfaces modified by exposure to reactive oxygen glow discharge gas plasma, through the direct measurement of the wicking properties of the modified material. It is well-known that oxygen plasma can be used to chemically alter the surface of polyet…

Advanced Sensor and Energy Harvesting MaterialsPlasma Applications and DiagnosticsSurface Modification and Superhydrophobicity