Materials Literature
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The synthesis of a novel fluoroionophore, 5-p-[[4-(10',15',20'-triphenyl-5'-porphinato) phenyloxyl]-1-butyloxyl]phenyl-10,15,20-triphenylporphine (DTPP), and its application for preparation of a Hg(II)-sensitive optical fiber chemical sensor are described. The response of the sensor is based on the fluorescence quench…
The retraction energy of a multiwalled carbon nanotube with an extruded core causes the core to oscillate with respect to its fully retracted position where the van der Waals potential energy is minimized. This phenomenon, together with the available nanotechnology, leads to the creation of nanomechanical systems of o…
L'action inhibitrice du 2-aminothiophénol (ATP) et du 2-aminophényl disulfure (APDS) sur la corrosion du fer dans HCl 1 M est étudiée par détermination de perte de masse et par analyse des courbes de polarisation potentiodynamique. Ces deux composés (ATP, APDS) réduisent la vitesse de corrosion du fer; cependant, l'AP…
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” opt…
Abstract The structure and thermal properties of polyamide‐1010 (PA1010), treated at 250°C for 30 min under pressures of 0.7–2.5 GPa, were studied with wide‐angle X‐ray diffraction (WAXD), infrared (IR), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). Crystals were formed when the pressu…
Computations, mostly at the RHF level, have been performed on La3+ and Y3+ model complexes of the widely used DOTA ligand [DOTA = 1,4,7,10-tetraaza-1,4,7,10-tetrakis(carboxymethyl)cyclododecane] for the purpose of identifying properties of the transition states of geometrical isomer interconversions, which have been t…
Electrochemical homopolymerization of metanillic acid has been achieved for the first time using a 4:1 acetonitrile-water mixture to get 100% sulfonated polyaniline which is soluble in both organic and aqueous solvents, electrically conducting, and is n-dopable.
Aluminum tetracarboxyphthalocyanine is adsorbed onto silanized silica particles at different dye to particle ratios. Diffuse reflectance spectra are measured and the equilibrium between dye monomers and aggregates is studied. Between 4.0 × 10−8 and 2.0 × 10−6 mol of dye g−1 of support, a simple dimerization equilibriu…
Porous alumina was fabricated by anodization in sulfuric acid and oxalic acid, where a laser dye, rhodamine 6G (RG6), and another luminescent organic molecule 8-hydroxyquinoline aluminum (Alq 3 ) were impregnated. The morphology determined by atomic force microscopy shows that the size of the pores is about 10-15 nm f…
This article reports the first work on the use of silica supported dendritic chiral auxiliaries for the enantioselective addition of diethylzinc to benzaldehyde: the control of dendrimer propagation on the silica surface is of prime importance to obtain enhanced conversion, selectivity, and enantioselectivity.
Abstract This article presents the tensile properties and morphological characteristics of binary blends of the high‐density polyethylene (HDPE) and a linear low‐density polyethylene (LLDPE). Two constituents were melt blended in a single‐screw extruder. Injection‐molded specimens were evaluated for their mechanical p…
Abstract Glyoxal and glutaraldehyde behave very differently for improving wet strength of paper. It is found that glyoxal is very efficient for improving temporary wet strength of paper without the presence of a catalyst and exposure to elevated temperatures. When a metal salt, such as Zn(NO 3 ) 2 , is used as a catal…
Tin ion-exchanged montmorillonite catalyzed the ring-opening polymerization of δ-valerolactone in a solvent free system. The polymerization proceeded in a living manner, giving rise to poly(δ-valerolactone)s with controlled molecular weights. Aluminium and iron ion-exchanged montmorillonites were also effective for th…
The reliability of the approximations commonly adopted in the calculation of static optical (hyper) polarizabilities is tested against exact results obtained for an interesting toy-model. The model accounts for the principal features of typical nonlinear organic materials with mobile electrons strongly coupled to mole…
We extend the Ericksen–Leslie theory for nematic liquid crystals to account for the presence of disclinations. To achieve this, we use Gurtin's theory of configurational forces and obtain an evolution equation in which the resultant of the Eshelby stress at a disclination is proportional to the velocity of the disclin…
Spermine-bridged gem-disubstituted cyclotriphosphazatrienes have been synthesised by two routes. In one route a spermine-bridged cyclophosphazene 2 reacted with monofunctional nucleophiles known to favour gem disubstitution in cyclophosphazene rings (e.g.tert-butylamine) to give 3b, or to favour formation of spiro-der…
A novel ESR-silent polyoxomolybdate Na(21)([Na(5)(H(2)O)(14)][Mo(46)O(134)(OH)(10)(mu-CH(3)COO)(4)]).CH(3)COONa.approximately equal to 90H(2)O (3) was simply synthesized in high yield by reducing an acidified aqueous solution of Na(2)MoO(4).2H(2)O and CH(3)COONa.3H(2)O. The structure of 3 is constructed by a 46-member…
In this paper the microscopic dynamics of methyl side groups in polyisoprene is studied by means of inelastic neutron scattering. By combining time-of-flight and backscattering technique a range of four decades can be obtained (0.2 ps–2 ns). The two experimental results were combined in the time domain by using an inv…
Azulene reacts with paraformaldehyde in the presence of florisil to give excellent yields of calix[4]azulene.
We have studied the optical absorptions of a series of point defects in SiO2 by means of time-dependent density functional response theory (TD-DFT). The structure of the defects has been described with cluster models and atomic orbital basis functions. For each center the lowest singlet→singlet and singlet→triplet (fo…