Materials Literature
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It is shown that the softening of the acoustic mode and the ensuing ferroelastic phase transition are due to the linear-quadratic interaction between the symmetric and antisymmetric deformations, which is presently neglected in the literature. An expression is obtained which can be used to predict the phase transition…
Self-assembly of preformed aluminosilicate nanoclusters in the presence of templating micella provides a route to strongly acidic, hydrothermally stable mesoporous aluminosilicates with ordered hexagonal structures (MAS-5). Results show that the materials are similar to Beta zeolite and are highly active for the catal…
Changes in crystal structure of ettringite on dehydration in normal atmosphere have been re-examined by means of thermogravimetry, X-ray diffraction, and 27Al nuclear magnetic resonance spectroscopy. Synthetic ettringite crystals were heated at various temperatures up to 200°C for durations of up to 7 h. The ettringit…
The crystallization of a eutectic Pb-Sn melt is investigated under nonuniform conditions in vacuum, in air, and in water. It is found that the structure of the solid-state systems formed depends on the cooling conditions. A structural inhomogeneity in volume and a correlation between the microstructure and the coordin…
Abstract Reversible nitrogen absorption and desorption cycle of CeFe7 and Ce2Fe17 was performed by heating in NH3 or N2 for nitrogenation and in H2 for denitrogenation. The nitrogen absorption and desorption rates for CeFe7 were faster than that for Ce2Fe17 owing to the high diffusion rate of nitrogen for CeFe7, resul…
The effect of palm oil fatty acid (POFA) and stearic acid on dynamic properties, curing characteristics and mechanical properties of natural rubber (SMR L) and epoxidized natural rubber (ENR 50) was investigated in the concentration range of 1 to 7 phr. Results indicate that scorch time, t 2 , cure time, t 90 and maxi…
The properties of a new domain structure, the equilibrium hexagonal lattice of spiral domains in ferrimagnetic films with perpendicular anisotropy were experimentally studied. The intervals of the bias fields and temperatures under which the lattice can be formed are determined. Temperature and field intervals of spir…
A time-dependent gas-phase isovolumetric desorption technique has been used to assess the isotope effects in the diffusive transport parameters of hydrogen in an 8% CrWVTa reduced activation martensitic steel in the temperature range of 423–892 K and driving pressures from 4 × 104–105 Pa. The experiments have been run…
Two new occurrences of anduoite, (Ru,Os)As2, a rare platinum-group mineral (PGM), are reported from chromitites, one from the Kapitanov deposit, Ukrainian Shield, Ukraine, and the other from the Maja e Sukes deposit, Tropoja ophiolitic massif, Albania. At Kapitanov, anduoite occurs as discrete, homogeneous, euhedral c…
Streszcz. ang.
The kinetics of thermal shrinkage of poly(ethylene terephthalate) films have been characterized and related to various parameters of the stretching process. Amorphous orientation functions and levels of crystallinity have been found to be of major importance to the shrinkage process. As film extension ratios increase,…
We present a detailed magnetothermal study of Pr0.7Ca0.3MnO3, a perovskite manganite in which an insulator-metal transition can be driven by magnetic field but also by pressure, visible light, X-rays or high currents. We find that the field-induced transition is associated with a large release of energy which accounts…
The energies of unoccupied and occupied orbitals were used as the correlation parameters between the electronic and adsorptive properties of organic molecules. A model describing the chemisorption of organic compounds on CaCO 3 involving two types of interaction, i.e. two-electron, donor–acceptor interaction HOMO(adso…
Two very useful, versatile reactions applicable to the synthesis of TTF-type electron donors are presented: the one-pot preparation of 1,3-dichalcogenole-2-chalcogenones from readily available terminal alkynes and the ready formation of heterocyclic rings fused on TTF by transalkylation on a chalcogen atom. These reac…
Measurements of elastic waves brought by a pulse of simulated corona discharge in an oil immersed pole transformer and a model tank filled with oil were performed in order to identify the location of insulation deterioration, using an acoustic emission (AE) technique. The detected AE signals were analyzed by means of…
Natural rubber (NR)/Linear low density polyethylene (LLDPE) blends were prepared using an internal mixer at 150°C and a rotor speed of 55 rpm. The tensile strength, tensile modulus and hardness increase with increasing LLDPE content whereas elongation at break and mass swell show decreasing trend. With 30/70 (W/W) NR/…
We study non-equilibrium velocity fluctuations in a model for the sedimentation of non-Brownian particles experiencing long-range hydrodynamic interactions. The complex behavior of these fluctuations, the outcome of the collective dynamics of the particles, exhibits many of the features observed in sedimentation exper…
In this paper we show the possibility of regulating the dose of the anchoring energy under the control of the incident light. Using a dye-doped nematic sample where it was previously demonstrated the effect of light-induced anchoring, we measured the threshold for the Fred-ericksz transition for different irradiation…
Some of the basic mechanical characteristics such as tensile, bending, shear, compression, and surface properties of cotton knitted fabrics after a durable flame‐retardant finishing, were studied by the objective‐evaluation method developed by Kawabata and Niva using the KES‐F system. In addition, properties such as b…
Abstract High‐performance surfactants have been developed for the preparation of water‐in‐oil high internal phase emulsions (HIPE), particularly for the preparation of polymerized HIPE foams. High‐efficiency surfactants with poly(butylene oxide)/poly(ethylene oxide) (BO/EO) block copolymer backbones have been develope…