Materials Literature
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Estimates for the thickness of the interface between poly (2,6-dimethyl-1,4-phenylene oxide) (PPO) and copolymers of styrene–acrylonitrile (SAN) and styrene–maleic anhydride (SMA) based on the theory of Helfand and Tagami are compared to neutron reflectivity (NR) measurements. Good agreement is found between the NR me…
Drape is a unique property that allows a fabric to be bent in more than one direction with double curvature. For many years, textile researchers studied this attribute in order to evaluate the drape quality and improve the drape appearance of garments. However, fabric drape can be more realistically investigated by co…
No presente trabalho, foi estudada a extração de substâncias húmicas (SH) de horizontes A de dois solos do Rio Grande do Sul (Latossolo Roxo (LR), e Brunizém vértico (B)) e de um lodo orgânico (LO), oriundo da fabricação de celulose, empregando-se dois métodos: (1) as SH foram extraídas com solução de NaOH 0,5 mol L-1…
Abstract The field of molecular based magnetism is an active area of research directed toward the design of new magnetic materials. The idea is to introduce molecular strategies in magneto‐chemistry. This can open completely new synthetic routes to materials with previously unknown physical properties. Spin carriers u…
Amorphous films of syndiotactic polystyrene were crystallized in dichloromethane, to obtain samples in the clathrate δ form; successively the samples were either annealed at temperatures below the glass transition temperature (Tg) or extracted with acetone. The samples obtained show, in the X-ray analysis, crystalline…
This paper presents a review of Electric Double Layered Magnetic Fluids (EDL-MF) based on spinel ferrite type [(M1-x+2Fex+3)]A [(Fe2-x+3 Mx+2)]BO4-2, with M(II) = Mn, Co, Ni, Cu and Zn. The chemical synthesis of the nanoparticles using hydrothermal techniques and their complete peptization in an aqueous medium results…
Variation of the number of crosslinks in polyvinylethylene (PVE) networks has a marked effect on the ${T}_{g}$-normalized temperature dependence (``fragility'') of the segmental relaxation times, even though the local chemical environment of virtually all repeat units is unchanged. Since the heat-capacity increment at…
To model the processes of cavitation inception, noise and damage, it is necessary to generate a model of the cavitation event rate which can then be coupled with the consequences of the individual events to produce a complete synthesis of the phenomenon. In this paper we describe recent efforts to connect the observed…
Silicon dioxide films were deposited in a parallel-plate electrode RF plasma-enhanced chemical vapor deposition (PECVD) system using hydrogen-free tetraisocyanatesilane (TICS) and oxygen. The deposition parameters were varied systematically, and the films were characterized by measuring infrared spectra, density, etch…
The thermal degradation behaviour of polymers and copolymers containing acrylic and methacrylic acid salt units has received much less attention than that devoted to the corresponding ester polymers from these acids. Whether present in a homopolymer or copolymer chain, however, these ionic salt units can have a major…
We propose a mechanism for breaking tilted nematic anchorings using an electric field normal to the plates. This breaking is a discontinuous first-order transition, unlike the known second-order breaking of planar anchorings. The elastic coupling of the tilted orientations on both plates is used to initialize the firs…
The three‐dimensional microstructural development of silicon nitride ceramics that exhibit superplastic elongation (up to ɛ = 1.34) was analyzed using a stereological analysis method. According to the microstructural change from randomly oriented grains to aligned grains along the tensile direction, the average orient…
All articles of this category A convergent synthesis of 1 → 3 C -branched polyamide dendrons was developed providing a facile access to defined monodisperse dendritic building blocks. dendritic building block - convergent synthesis
Embryonic and larval expression patterns of the sericin-1 gene and its presumed transcription factor, SGF-3/POU-M1, in the silk gland were analyzed by in situ hybridization and immunohistochemistry. The sericin-1 transcripts were first detected at embryonic stage 26 in an increasing gradient pattern in the middle and…
Like other diatoms, living cells of Chaetoceros decipiens Cleve expand lengthwise before they divide. During prophase, the nucleolus disappears in about 30 s. The spindle is very small but anaphase chromosome separation can be seen. Following rapid cleavage, the protoplasts contract, plasmolyzing slightly and transfor…
The early literature of catecholate complexes of Ni(II) is explained with regard to both high-spin octahedral and low-spin square-planar complexes. The former contain coordinated solvent, while the latter do not. The syntheses of the paramagnetic (S = 1; &mgr;(eff) = 2.93 &mgr;(B) at 300 K) octahedral Ni(II) complex N…
Cationic polymerization of isobutyl vinyl ether (IBVE) with acetic acid (CH3COOH)/tin tetrahalide (SnX4: X = Cl, Br, I) initiating systems in toluene solvent at 0°C was investigated, and the reaction conditions for living polymerization of IBVE with the new initiating systems were established. Among these tin tetrahal…
Abstract PEEK/carbon fiber composites were prepared by a modified diaphragm forming machine under vacuum. The study of the degree of crystallinity versus the differential scanning calorimetry (DSC) heating rate indicated that 50°C/min was an optimal heating rate to suppress the reorganization of the specimens crystall…
Molecule-based materials can exhibit a variety of technologically useful cooperative properties not associated with individual molecules, such as ferromagnetism, superconductivity, and ferroelectricity. Selected examples are used to illustrate the fact that, although in general the molecular structure differs in only…
Macrocyclic compounds constitute a potential class of corrosion inhibitors. In an attempt to develop effective corrosion inhibitors we have synthesized four macrocyclic compounds by condensing o‐ethylene diamine and o‐phenylene diamine with ethylacetoacetate and succinic acid; Their inhibiting action was evaluated on…