Materials Literature
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The crystal structure and the magnetic properties of the compound [Cu(μ-oxalato-O,O‘)(H2O)(4-aminopyridine)2]n, the first transition metal extended structure that exhibits a bridging oxalate anion in a 1,1‘-cis-bidentate coordination mode, are reported.
ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTSpiropyran Derivative of an Elastin-like Bioelastic Polymer: Photoresponsive Molecular Machine to Convert Sunlight into Mechanical WorkM. Alonso, V. Reboto, L. Guiscardo, A. San Martín, and J. C. Rodríguez-CabelloView Author Informa…
The surface species formed from the adsorption of 1,3-butadiene and 1-butene on Mo 2 N/γ-Al 2 O 3 catalyst have been characterized by in situ FT-IR spectroscopy with an attempt to get insight into the selective hydrogenation of 1,3-butadiene on transition metal nitride catalysts. 1,3-Butadiene adsorption on the Mo 2 N…
When dissolved in aqueous solution, α-lactose, whether originally in the anhydrous or the monohydrated form, readily undergoes mutarotation to yield the β isomer. At equilibrium, which is reached in 6.5 h at 292 K and more rapidly with increasing temperatures, the latter is present to the extent of ca. 60% w/w. At sat…
We report observation of inverted phases consisting of spheres and/or cylinders of the majority fraction block in a poly(styrene- b -butadiene- b -styrene) (SBS) triblock copolymer by solvent-induced order−disorder phase transition (ODT). The SBS sample has a molecular weight of 140K Da and a polystyrene (PS) weight f…
The present paper is devoted to the study of original trinuclear (CuII, LnIII, CuII) complexes (Ln = La, Ce, Gd). They derive from the polydentate ligands H2Li (i = 1, 3, 4) represented in Figure 1. The crystal and molecular structures of two complexes have been determined at room temperature. The (Cu, Gd, Cu) complex…
We show that the luminescence from CdSe quantum dot monolayers can be strongly influenced by the interaction of water molecules adsorbed on the surface. Light-induced alterations in the surface states following adsorption of water, results in quasi-reversible luminescence changes in the quantum dot. The excitonic QY i…
Carbon nanofibers (diameter range, 3–100 nm; length range, 0.1–1000 µm) have been known for a long time as a nuisance that often emerges during catalytic conversion of carbon-containing gases. The recent outburst of interest in these graphitic materials originates from their potential for unique applications as well a…
ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTPolyimide Thin Films Produced by Direct Solid-State Polymerization of an Amino Anhydride MonomerTimothy P. Bender and Zhi Yuan WangView Author Information Department of Chemistry, Carleton University, 1125 Colonel By Drive, Ottawa,…
The influences that both electron energy and density of a plasma bear on thin film formation are examined in the case of iodine-doped polyaniline polymerization. The plasma was produced by means of 13.5-MHz radiofrequency–generated glow discharges in low-pressure (ca. 10−2 mbar) air between electrodes. Four representa…
A series of cyclic metalloporphyrin trimers containing one Ru(II)-CO porphyrin center are synthesized. A stepwise convergent route is used to synthesize Ru(CO)Zn(2)2.Py3T, where tripyridyltriazine (Py3T) templates the formation of the trimer and forces the CO group to the outside of the cavity. Three mixed-metal trime…
Pseudomonas sp. 61-3 produces a blend of poly(3-hydroxybutyrate) [P(3HB)] homopolymer and poly(3-hydroxybutyrate-co-3-hydroxyalkanoates) [P(3HB-co-3HA)] random copolymer consisting of monomeric units of 4-12 carbon atoms from sugars. The phaG(Ps) gene encoding (R)-3-hydroxyacyl-acyl carrier protein coenzyme A transfer…
A "spin diverse" S = 3/2 ground-state complex, NN-SQCuTpCum,Me, has been prepared. The three S = 1/2 spin carriers are nitronyl nitroxide (NN), o-semiquinone (o-SQ), and cupric ion. The solid-state structure of the ZnII derivative, NN-SQZnTpCum,Me (C56H69BN8O4Zn), was determined: monoclinic, P2(1)/c, a = 12.5781(12) A…
Higher plants represent a rich source of new molecules with pharmacological properties, which are lead compounds for the development of new drugs. During the last decades, the renewed interest in investigating natural products has led to the advent of several important drugs, such as the anticancer substances vinblast…
Treatment of cis-[W(N2)2(PMe2Ph)4] (5) with an equilibrium mixture of trans-[RuCl(eta 2-H2)(dppp)2]X (3) with pKa = 4.4 and [RuCl(dppp)2]X (4) [X = PF6, BF4, or OTf; dppp = 1,3-bis(diphenylphosphino)propane] containing 10 equiv of the Ru atom based on tungsten in benzene-dichloroethane at 55 degrees C for 24 h under 1…
A shape memory alloy (SMA) spring actuator for an active catheter was fabricated by the heat treatment of wound SMA wire on a mandrel. In order to evaluate the characteristics of the fabricated SMA spring actuator, four types of tests were performed, as follows: isothermal loading and unloading, measurement of shape r…
The structural and thermal behavior of all members of the homologous series of neodymium(III) alkanoates, ranging from neodymium(III) butyrate to neodymium(III) eicosanoate are described. Neodymium(III) butyrate monohydrate, Nd(C3H7COO)3.H2O crystallizes in space group P1 (No. 2), Z = 2. The lattice parameters are a =…
The capability of periodic structures to act as filters for traveling waves is used to control the longitudinal wave propagation in rods. Shape memory inserts placed periodically along the rods act as sources of impedance mismatch with tunable characteristics. Such characteristics are attributed to the unique behavior…
The numerical simulation analyses were performed on the buckling and postbuckling behavior of laminated composite shells with embedded shape memory alloy (SMA) wires. These analyses using ABAQUS code were conducted to investigate the effect of embedded SMA wires on the characteristics of buckling and postbuckling caus…
Ag/Fe/Ag and Cr/Fe/Cr trilayers with a single $25 nm$ thick ferromagnetic layer exhibit giant magnetoresistance (GMR) type behavior. The resistance decreases for parallel and transversal magnetic field alignements with a Langevin-type magnetic field dependence up to B=12 T. The phenomenon is explained by a granular in…