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Lanthanide Complexes of Polyacid Ligands derived from 2, 6‐bis(pyrazol‐1‐yl)pyridine, pyrazine, and 6, 6′‐bis(pyrazol‐1‐yl)‐2, 2′‐bipyridine: Synthesis and luminescence properties

Juan Carlos Rodríguez‐Ubis、Rosa Sedano、G. Barroso 等 5 位作者1997-02-10Helvetica Chimica Acta

Abstract The synthesis of three novel pyrazole‐containing complexing acids, N,N,N′,N ′‐{2, 6‐bis[3‐(aminomethyl)pyrazol‐1‐yl]‐4‐methoxypyridine}tetrakis(acetic acid)( 1 ), N,N,N ′, N ′‐{2, 6‐bis[3‐(aminomethyl)pyrazol‐1‐yl]pyrazine}‐tetrakis(acetic acid) ( 2 ), and N,N,N ′, N ′‐{6, 6′‐bis[3‐(aminomethyl)pyrazol‐1‐yl]‐…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Electrical properties of high resistivity 6H–SiC under high temperature/high field stress

G. Gradinaru、T. S. Sudarshan、S. Gradinaru 等 5 位作者1997-02-10Applied Physics Letters

The influence of ambient temperature and applied electric field on the electrical properties of high resistivity (1–30 kΩ cm), semi-insulating (>100 kΩ cm), and insulating (1011–1012 Ω cm) single-crystal 6H–SiC is reported. Current–voltage (I–V) characteristics of lateral metal-semiconductor-metal test structur…

High voltage insulation and dielectric phenomenaSilicon Carbide Semiconductor TechnologiesLightning and Electromagnetic Phenomena

Rheology of “Wet” Polymer Brushes via Brownian Dynamics Simulation: Steady vs Oscillatory Shear

Patrick S. Doyle、Eric S. G. Shaqfeh、Alice P. Gast1997-02-10Physical Review Letters

The rheology of solvent-filled polymer brushes under steady and oscillatory shear is studied by Brownian dynamics simulation. The flow field is solved self-consistently with the polymer dynamics. We find that under steady flow the brushes are shear thinning in both normal forces and shear viscosity. During oscillatory…

Polymer Surface Interaction StudiesSurfactants and Colloidal SystemsBlood properties and coagulation

Dual frequency cholesteric light shutters

Ming Xu、Deng‐Ke Yang1997-02-10Applied Physics Letters

We developed a dual frequency cholesteric light shutter which utilizes a cholesteric liquid crystal; the dielectric anisotropy of the material changes from positive to negative when the frequency of applied voltage is increased. The shutters are switched to the transparent homeotropic texture by low frequency voltages…

Liquid Crystal Research AdvancementsElectrowetting and Microfluidic TechnologiesPhotonic Crystals and Applications

Floppy Modes in Crystalline and Amorphous Silicates

Martin T. Dove、Mark Harris、Alex C. Hannon 等 6 位作者1997-02-10Physical Review Letters

We present the results of comparative inelastic neutron scattering measurements of both amorphous and crystalline silicates. We demonstrate the presence of floppy modes in amorphous silica and potassium disilicate over the energy scale 0--5 meV. A peak is also observed at 5 meV in amorphous silica, which is traditiona…

Phase-change materials and chalcogenidesGlass properties and applicationsHigh-pressure geophysics and materials

Critical Current Suppression in a Superconductor by Injection of Spin-Polarized Carriers from a Ferromagnet

V. A. Vas’ko、V. A. Larkin、P. A. Kraus 等 7 位作者1997-02-10Physical Review Letters

The critical current of a thin film of the high- ${T}_{c}$ superconductor ${\mathrm{DyBa}}_{2}{\mathrm{Cu}}_{3}{\mathrm{O}}_{7}$, when incorporated in a heterostructure in which it is separated from a ferromagnetic underlayer of ${\mathrm{La}}_{2/3}{\mathrm{Sr}}_{1/3}{\mathrm{MnO}}_{3}$ by an undoped ultrathin ${\math…

Iron-based superconductors researchMagnetic and transport properties of perovskites and related materialsPhysics of Superconductivity and Magnetism

Large Magnetic Entropy Change in Perovskite-Type Manganese Oxides

Z.B. Guo、Yikun Du、Jinsong Zhu 等 6 位作者1997-02-10OpenAlex

Magnetic entropy change larger than that of gadolinium has been observed in polycrystalline of ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Ca}}_{x}{\mathrm{MnO}}_{3}$ ( $x\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}0.2$ and 0.33) perovskite-type manganese oxide. The large magnetic entropy change produced by the a…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsAdvanced Thermoelectric Materials and Devices

Random Telegraph Signal in the Photoluminescence Intensity of a Single Quantum Dot

Al. L. Éfros、Matthew S. Rosen1997-02-10OpenAlex

We propose a model in which the time dependence of the photoluminescence intensity of a single nanosize quantum dot under cw excitation conditions shows a sequence of ``on'' and ``off'' periods similar to a random telegraph signal. In our model the off periods are the times when the dot is ionized and the luminescence…

Quantum Dots Synthesis And PropertiesAdvanced Semiconductor Detectors and MaterialsSemiconductor Quantum Structures and Devices

Targeted Disruption of Decorin Leads to Abnormal Collagen Fibril Morphology and Skin Fragility

Keith G. Danielson、Hélène Baribault、David Holmes 等 6 位作者1997-02-10OpenAlex

Decorin is a member of the expanding group of widely distributed small leucine-rich proteoglycans that are expected to play important functions in tissue assembly. We report that mice harboring a targeted disruption of the decorin gene are viable but have fragile skin with markedly reduced tensile strength. Ultrastruc…

Collagen: Extraction and CharacterizationProteoglycans and glycosaminoglycans researchSkin and Cellular Biology Research

Prediction of new sp2 and sp2/sp3 hollow carbon crystals

G. Benedek、Luciano Colombo、Sabrina Gaito 等 5 位作者1997-02-08The Journal of Chemical Physics

Among the hypothetical forms of fully covalent carbon lattices with either graphite-like sp2 or mixed sp2/sp3 bonding we investigated the possibility of monocrystals with a hollow structure. We have calculated the structural, elastic and electronic properties of two prototypical face–centered cubic lattices C20 and C2…

Boron and Carbon Nanomaterials ResearchCarbon Nanotubes in CompositesGraphene research and applications

Nematics of linear assemblies in two dimensions

Paul van der Schoot1997-02-08The Journal of Chemical Physics

A density functional theory is presented describing the isotropic-nematic transition in dispersions of self-assembled linear objects in two dimensions. It is shown that the transition is second order. The auto-correlation function of order parameter fluctuations is also calculated on both sides of the transition point…

Nonlinear Dynamics and Pattern FormationLiquid Crystal Research AdvancementsMaterial Dynamics and Properties

Block copolymer microstructures in the intermediate-segregation regime

M. W. Matsen、Frank S. Bates1997-02-08OpenAlex

A detailed examination of the intermediate-segregation regime of diblock copolymer melts is presented using the incompressible Gaussian chain model and self-consistent field theory (SCFT). We find that the competition between interfacial tension and chain stretching used to describe behavior in the strong-segregation…

Advanced Polymer Synthesis and CharacterizationBlock Copolymer Self-AssemblyRheology and Fluid Dynamics Studies

An epoxy‐terminated structural adhesive. II. Curing, adhesive strength, and flammability characteristics

Santi N. Ghosh、Sukumar Maiti1997-02-07Journal of Applied Polymer Science

Curing characteristics and the curing schedule of an epoxy-terminated polymer (ETP) were investigated using diaminodiphenyl ether (DADPE), diaminodiphenyl sulfone (DADPS), diaminodiphenyl methane (DADPM), and the hardener of a commercial epoxy, two-pack Araldite (Ciba-Geigy), as curing agents. The adhesive strength of…

Synthesis and properties of polymersEpoxy Resin Curing ProcessesFlame retardant materials and properties

<title>Holographic recording in amorphous semiconductor films</title>

Andris Ozols、Nina Nordman、Olli Salminen 等 4 位作者1997-02-06Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

The present state of the real time holographic recording in amorphous semiconductor films is reviewed including mechanisms, parameters, properties and applications. Effects of the coherent, incoherent and relaxational self- enhancement as well as the influence of the film structure relaxation are considered. Quasi-per…

Phase-change materials and chalcogenidesLiquid Crystal Research AdvancementsPhotorefractive and Nonlinear Optics

<title>X-ray absorption spectroscopy study of the local environment around tungsten and molybdenum ions in tungsten-phosphate and molybdenum-phosphate glasses</title>

Alexei Kuzmin、J. Purāns1997-02-06Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

X-ray absorption spectroscopy (XAS) was used to study the local environment around tungsten and molybdenum ions in BaO-P<SUB>2</SUB>O<SUB>5</SUB>-WO<SUB>3</SUB> and CaO-P<SUB>2</SUB>O<SUB>5</SUB>-MoO<SUB>3</SUB> glasses having different composition of WO<SUB>3</SUB> and MoO<SUB>3</SUB> oxides. The W L<SUB>1,3</SUB> an…

Crystal Structures and PropertiesLuminescence Properties of Advanced MaterialsGlass properties and applications

<title>Nature of fundamental absorption edge of WO<formula><inf><roman>3</roman></inf></formula></title>

Jānis Kleperis、J. Zubkans、A. Lūsis1997-02-06Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

The fundamental absorption edge of amorphous, polycrystalline and crystalline tungsten trioxide (WO<SUB>3</SUB>) thin films obtained by different techniques (thermal evaporation, rf plasma sputtering, chemical gas transport) was investigated. Special attention was paid to correct measurements of absorption values of a…

Surface Roughness and Optical MeasurementsLaser Material Processing TechniquesTransition Metal Oxide Nanomaterials

Structural, electronic, and dynamical properties of amorphous gallium arsenide: a comparison between two topological models

Normand Mousseau、Laurent J. Lewis1997-02-06arXiv

We present a detailed study of the effect of local chemical ordering on the structural, electronic, and dynamical properties of amorphous gallium arsenide. Using the recently-proposed ``activation-relaxation technique'' and empirical potentials, we have constructed two 216-atom tetrahedral continuous random networks w…

Materials Science

Adlayer core-level shifts of random metal overlayers on transition-metal substrates

M. V. Ganduglia-Pirovano、J. Kudrnovsky、M. Scheffler1997-02-05arXiv

We calculate the difference of the ionization energies of a core-electron of a surface alloy, i.e., a B-atom in a A_(1-x) B_x overlayer on a fcc-B(001)-substrate, and a core-electron of the clean fcc-B(001) surface using density-functional-theory. We analyze the initial-state contributions and the screening effects in…

Materials Science

Surface relaxation and ferromagnetism of Rh(001)

Jun-Hyung Cho、Matthias Scheffler1997-02-05arXiv

The significant discrepancy between first-principles calculations and experimental analyses for the relaxation of the (001) surface of rhodium has been a puzzle for some years. In this paper we present density functional theory calculations using the local-density approximation and the generalized gradient approximati…

Materials Science

Optical Response of Grating-Coupler-Induced Intersubband Resonances: The Role of Wood's Anomalies

L. Wendler、T. Kraft、M. Hartung 等 8 位作者1997-02-05arXiv

Grating-coupler-induced collective intersubband transitions in a quasi-two-dimensional electron system are investigated both experimentally and theoretically. Far-infrared transmission experiments are performed on samples containing a quasi-two-dimensional electron gas quantum-confined in a parabolic quantum well. For…

Materials ScienceMesoscale and Nanoscale Physics