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Some physicochemical properties of glassy indomethacin.

Eihei Fukuoka、Midori Makita、Shigeo Yamamura1986-01-01Chemical and Pharmaceutical Bulletin

Glassy indomethacin was prepared by cooling the melt, and the glassy state was confirmed by the jump of heat capacity and the anomalous endothermic park (heat capacity maximum) in the differential scanning calorimetry (DSC) curve. The influences of the cooling rate of the melt and the heating rate of the glass formed…

Crystallization and Solubility StudiesThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Clusters: Properties and Formation

A. W. Castleman1986-01-01Annual Review of Physical Chemistry

Machine learning (ML) is transforming all areas of science. The complex and time-consuming calculations in molecular simulations are particularly suitable for an ML revolution and have already been profoundly affected by the application of existing ML ...Read More

Machine Learning in Materials Science

Excimer-laser etching of diamond and hard carbon films by direct writing and optical projection

M. Rothschild、C. Arnone、D. J. Ehrlich1986-01-01Journal of Vacuum Science & Technology B Microelectronics Processing and Phenomena

Excimer-laser patterning of monocrystalline diamond was performed in the direct writing and in the optical projection modes. The etching mechanism employs combined photochemical/thermal transformation of the initial crystal to graphite followed by sublimation or reaction of the transformed solid. In optical projection…

Diamond and Carbon-based Materials ResearchLaser Material Processing TechniquesAdvanced Surface Polishing Techniques

Calcification of subcutaneously implanted type I collagen sponges. Effects of formaldehyde and glutaraldehyde pretreatments.

Robert J. Levy、F J Schoen、Frederick S. Sherman 等 6 位作者1986-01-01PubMed

Although collagen-containing implants are widely used in various surgical applications, there has been relatively little attention paid to the possibility that this type of biomaterial may undergo pathologic calcification which could compromise its function. The present study reports for the first time the calcificati…

Dental Implant Techniques and OutcomesDermatologic Treatments and ResearchCollagen: Extraction and Characterization

The physical origin of negative capacitance

A.K. Jonscher1986-01-01Journal of the Chemical Society Faraday Transactions 2 Molecular and Chemical Physics

The phenomenon of negative capacitance, which has been reported in a variety of situations involving electrolytic as well as electronic systems, does not appear to be understood and some tentative interpretations appear to lack plausibility. It is suggested that the physically correct approach lies in the analysis of…

Ferroelectric and Piezoelectric MaterialsSemiconductor materials and devicesAcoustic Wave Resonator Technologies

Mechanism of hydrolytic degradation of poly(L-lactide) microcapsules: effects of pH, ionic strength and buffer concentration

Kimiko Makino、Hiroyuki Ohshima、Tamotsu Kondo1986-01-01Journal of Microencapsulation

The hydrolytic degradation rate of poly(L-lactide) molecules constituting the microcapsule membrane was estimated at different pH, ionic strength and buffer concentration. Poly(L-lactide) microcapsules were observed to be hydrolytically degraded rapidly in a strongly alkaline solution to lactic acid as the final produ…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionRecycling and Waste Management Techniques

Scanning Electron Microscopy

J. D. Verhoeven1986-01-01Materials Characterization

Abstract Scanning electron microscopy (SEM) has shown various significant improvements since it first became available in 1965. These improvements include enhanced resolution, dependability, ease of operation, and reduction in size and cost. This article provides a detailed account of the instrumentation and principle…

Corrosion Behavior and InhibitionAdvanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy Techniques

Selective removal of electron-accepting p-toluene- and naphthalenesulfonyl protecting groups for amino function via photoinduced donor acceptor ion pairs with electron-donating aromatics

Tatsuo Hamada、Atsushi Nishida、Osamu Yonemitsu1986-01-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSelective removal of electron-accepting p-toluene- and naphthalenesulfonyl protecting groups for amino function via photoinduced donor acceptor ion pairs with electron-donating aromaticsTatsuo. Hamada, Atsushi. Nishida, and Osamu. YonemitsuCite this: J. Am. Chem. Soc. 1986,…

Molecular Sensors and Ion DetectionRadical Photochemical ReactionsCovalent Organic Framework Applications

New selective deposition technology by electron-beam induced surface reaction

Shinji Matsui、Katsumi Mori1986-01-01Journal of Vacuum Science & Technology B Microelectronics Processing and Phenomena

A new selective deposition technology using electron beam induced surface reaction has been demonstrated. Electron beam induced W and Cr patterns were deposited by using WF6, WCl6, and Cr(C6H6)2 as sources, respectively. W and Cr depositions were confirmed by analysis using Auger electron spectroscopy (AES) and x-ray…

Metal and Thin Film MechanicsSemiconductor materials and devicesElectron and X-Ray Spectroscopy Techniques

The calculation of defect parameters in UO2

Robert A. Jackson、A.D. Murray、John H. Harding 等 4 位作者1986-01-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

Defect parameters are calculated for a wide range of defects in UO2. In addition to internal energies, entropies of formation have been calculated for some defects. Enthalpies are obtained for comparison with experimental data, where available. Defect processes studied include intrinsic defects, cation substitution, i…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesThermodynamic and Structural Properties of Metals and Alloys

Photophysics, photochemistry, kinetics, and mechanism of the photochromism of 6'-nitroindolinospiropyran

Christian Lenoble、Ralph S. Becker1986-01-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotophysics, photochemistry, kinetics, and mechanism of the photochromism of 6'-nitroindolinospiropyranChristian Lenoble and Ralph S. BeckerCite this: J. Phys. Chem. 1986, 90, 1, 62–65Publication Date (Print):January 1, 1986Publication History Published online1 May 2002Publ…

Photochromic and Fluorescence ChemistryPhotoreceptor and optogenetics researchbioluminescence and chemiluminescence research

Preparation of a novel, soluble copper phthalocyanine with crown ether moieties

Ali R. Koray、Vefa Ahsen、Özer Bekâroĝlu1986-01-01Journal of the Chemical Society Chemical Communications

A novel, soluble copper phthalocyanine containing four benzo-15-crown-5 moieties was synthesized and characterized by elemental analysis, i.r. and u.v. spectroscopy, and its alkali cation-complexing capability and selectivity studied.

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsOrganic Chemistry Cycloaddition Reactions

Thermal expansion behavior of various aromatic polyimides

Shunichi Numata、Shuuichi Oohara、Koji Fujisaki 等 5 位作者1986-01-01Journal of Applied Polymer Science

Abstract The thermal expansion behavior for various aromatic polymides was investigated. Usally polymers, including polyimides, have high thermal expansion coefficients (3–6 × 10 −5 K −1 ), compared with metals and ceramics. However, there are some polyimides which have very low thermal expansion coefficients below 1…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersTribology and Wear Analysis

Structural transitions in epitaxial overlayers

Robijn Bruinsma、Andrew Zangwill1986-01-01Journal de physique

We present a theory of epitaxial growth appropriate to overlayer materials that can adopt a bulk metastable crystal structure with a lattice constant significantly different from that of the stable ground state structure, as is common for metal epitaxy. This requires a generalization of the traditional Frank and van d…

Microstructure and mechanical propertiesSolidification and crystal growth phenomenananoparticles nucleation surface interactions

Novel photocatalysts, ion-exchanged K4Nb6O17, with a layer structure

Kazunari Domen、Akihiko Kudo、Mutsumi Shibata 等 6 位作者1986-01-01Journal of the Chemical Society Chemical Communications

Proton-exchanged K4Nb6O17 showed high activity for H2 evolution from aqueous methanol solution without any assistance from other materials such as noble metals.

Polyoxometalates: Synthesis and ApplicationsLayered Double Hydroxides Synthesis and ApplicationsInorganic Chemistry and Materials

Upward creep of a wetting fluid : a scaling analysis

Jean‐François Joanny、P. G. de Gennes1986-01-01Journal de physique

A Van der Waals fluid, climbing from a reservoir along a vertical wall, should display a remarkable cascade of events : i) A macroscopic meniscus is set up in a short time t1 and reaches the classical altitude hc∼ 1 mm. ii) A dynamic precursor film appears at a time t2 ∼ 10-2 s. The tip of the « tongue» advances fast…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesAdvanced Thermodynamics and Statistical Mechanics

Properties of II–VI semiconductors associated with moving dislocations

Yu. A. Osip’yan、Victor F. Petrenko、A. V. Zaretskii 等 4 位作者1986-01-01Advances In Physics

Moving dislocations in II–VI semiconductors carry a large electric charge. This charge is not in thermal equilibrium, but is due to the sweeping up of electrons from point defects. Its movement produces a dislocation current during plastic deformation, and conversely, the application of an external field changes the f…

ZnO doping and propertiesElectronic and Structural Properties of OxidesSurface and Thin Film Phenomena

Effect of Shear Stress on Sintering

M. N. Rahaman、Lutgard C. De Jonghe、RH Brook1986-01-01Journal of the American Ceramic Society

The effect of small uniaxial stresses on the sintering of CdO powder compacts was studied using a loading dilatometer. Compacts of two different green densities were sintered at 1123 K and subjected to stresses between 0 and 0.25 MPa. Densification and creep occur simultaneously, and the effects of these two processes…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Enhanced photoredox chemistry in quantized semiconductor colloids

Jovan M. Nedeljković、M. T. Nenadović、O. I. Mićić 等 4 位作者1986-01-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEnhanced photoredox chemistry in quantized semiconductor colloidsJ. M. Nedeljkovic, M. T. Nenadovic, O. I. Micic, and A. J. NozikCite this: J. Phys. Chem. 1986, 90, 1, 12–13Publication Date (Print):January 1, 1986Publication History Published online1 May 2002Published inissu…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesMolecular Junctions and Nanostructures